摘要
Flexiblethin-filmsupercapacitorswithhighspecificcapacitancearehighlydesirableformodernwearableormicro-sizedelectricalandelectronicapplications.Inthiscontribution,Ni-Cohydroxides(NCH)nanosheetsweredepositedontopofNi-Cualloy(NCA)nanowirearraysformingafreestandingthin-filmcompositeelectrodewithhierarchicalstructureforsupercapacitors.Duringelectrochemicalcycling,thedissolutionofCuintoCuionswillcreatemoreactivesitesonNCA,andtheredepositedcopperoxidecanbecoatedontoNCH,givingrisetosubstantialincreaseinspecificcapacitancewithcycling.Meanwhile,NCAandNCHhaveexcellentconductivity,thusleadingtoexcellentrateperformance.Thisflexiblethin-filmelectrodedeliversanultrahighinitialspecificcapacitanceof0.63F·cm~(-2)(or781.3F·cm~(-3)).Duringcharge-dischargecycles,thespecificcapacitancecanincreaseupto1.18F·cm~(-2)(or1475F·cm~(-3))alongwiththe'self-etching'process.Theelectrodepresentsabetterspecificcapacitanceandratecapabilitycomparedwithpreviouslyreportedflexiblethin-filmelectrode,andthisnoveldesignofetchingtechniquemayexpandtootherbinaryorternarymaterials.
出版日期
2017年09月19日（中国期刊网平台首次上网日期，不代表论文的发表时间）
