Microcalorimetric Study on the Oscillating System of Two-phase Reaction of Aqueous Acid with Primary Amine in Chloroform

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摘要 Ithasbeenfoundthatthetwo-phasereactionsofaqueousHCl,HOAcorH3PO4withprimaryamineN1923inchloroformareosiclatingreactions.Theirpower-timecurvesweremeasuredbythetitrationmicrocalorimetricmethod,andtheinductionperiod(tin).Thefirstoscillatingperiod(tp.1)andthesecondoscillatingperiod(tp.2)weredetermined.Theapparentactivatingparametersandtheordersoftheoscillatingsystemswerecalculatedandthefollowingrelationshipswereestablished:fortheoscillatingsystemofhydrochloricacid.
机构地区 不详
出处 《中国化学:英文版》 2003年1期
出版日期 2003年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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