First assessment of Li2O–Bi2O3 ceramic oxides for high temperature carbon dioxide capture

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摘要 ThecapacitytocaptureCO2wasdeterminedinseveralstoichiometriccompositionsintheLi2O–Bi2O3system.Thecompounds(Li7BiO6,Li5BiO5,Li3BiO4andLiBiO2phases)weresynthesizedviasolid-statereactionandcharacterizedbyX-raydiffraction,scanningelectronmicroscopyandN2adsorptiontechniques.Thesampleswereheat-treatedattemperaturesfrom40to750°CundertheCO2atmospheretoevaluatethecarbonateformation,whichisindicativeofthecapacityofCO2capture.Moreover,Li7BiO6showsanexcellentCO2capturecapacityof7.1mmol/g,whichisconsiderablyhigherthanthoseofotherpreviouslyreportedceramics.Li7BiO6isabletoreactwithCO2from240°Ctoapproximately660°CshowingahighkineticreactionevenatCO2partialpressurevaluesaslowas0.05.
机构地区 不详
出处 《能源化学:英文版》 2016年5期
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出版日期 2016年05月15日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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