摘要
Nanoscalemullitepowderweresynthesizedviasolgel-SCFDandmiddletemperaturetreatmentbyusingAIP(aluminum-isopropoxde)andTEOS(tetraethylorthosilicate)asstartingmaterials.Bothofthebinaryaerogelofalumina-silicaandcalcinednanoscalematerialswereinvestigatedbyusingTG-DSC(thermogravimetry-differentialscanningcalorimeter),TEM(transmissionelectronmicroscope),XRD(X-Raydiffractometer)andspecificsurfaceareaandporosimetry.TG-DSCindicatedtheremovalofmostofthevolatiles,i.e.15.98%uptoabout700℃,andintheDSCcurve,existenceoftwoexothermicpeakatabout445℃and1015℃maybeduetothecrystallizationofSi-O-Al-Oindiphasicgelsandmullitizationandasmallendothermicpeakatabout805℃indicatedthedecompositionofstructuralwatermolecules.OnthecolligationoftheresultsofTG-DSC,XRDandTEM,thebeginningtemperatureofmullitizationinAl2O3-SiO2aerogelsystemcanbeconfirmedatabout1015℃.XRDresultsalsoshowedtheformationofmulliteattherange1100-1200℃.TEMandsurfaceareaandporosimetryresultsshowedthatthenanosizedmullitewerecalcinatedat1100and1200℃exhibitedsize30nmand50nm,specificsurfacearea138.91m^2/gand95.81m^2/g.
出版日期
2003年04月14日（中国期刊网平台首次上网日期，不代表论文的发表时间）
