简介：Twonewdicyanamidecoordinationpolymers,{Mn(dmpz)[N(CN)2]2}2(1)and{Cu(dmpz)[N(CN)2]2}2(2)(dmpz=3,5-dimethylpyrazole),weresynthesizedandcharacterizedbysinglecrystalX-raydiffractionanalysisandIRspectroscopy.In1and2themetalionshavetwodifferentcoordinationmodes,whereoneiscoordinatedtofourdicyanamideanionsandtwomonodentatedmpzmoleculestoformaslightlydistortedoctahedralgeometry,whiletheotheradoptsoctahedralgeometry,surroundedbyfournitrileNatomsandtwoamideNatomsofthedicyanamideanions.Bothcomplexescontaintwoalternatingchainsthatareparalleltoeachother.
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![Two New Dicyanamide Coordination Polymers with Alternating Parallel Chains： {Mn（dmpz）[N（CN）<b style='color:red'>2</b>]<b style='color:red'>2</b>}<b style='color:red'>2</b> and {Cu（dmpz）[N（CN）<b style='color:red'>2</b>]<b style='color:red'>2</b>}<b style='color:red'>2</b>](/image/thesis0 "Two New Dicyanamide Coordination Polymers with Alternating Parallel Chains： {Mn（dmpz）[N（CN）<b style='color:red'>2</b>]<b style='color:red'>2</b>}<b style='color:red'>2</b> and {Cu（dmpz）[N（CN）<b style='color:red'>2</b>]<b style='color:red'>2</b>}<b style='color:red'>2</b>")