简介:二新奇的灰更少添加剂-benzothiazole衍生物包含硼和氯,OBC和BBC,被综合。在在油菜籽的添加剂上油的不同集体比率(RO)的OBC和BBC的tribological表演在一台四球的机器上被检验。油样品润滑的更低的钢球的穿的表面借助于扫描电子显微镜学(SEM)被分析。测试结果显示出那OBC,BBC在底有好溶解度上油,并且能有效地增加基础油的带负担的能力。包含1.5m%BBC的油样品的最大的非抓住负担是1117N,它2.3倍于基础油的。OBC和BBC能改进禁止性能和基础油的热稳定性的反穿和腐蚀,谁的起始的分解温度在350°C上面。然而,在不同集中的OBC和BBC能增加基础油的磨擦系数。油润滑的钢球的SEM形态学取样包含1.5m%添加剂似乎比形成的基础油,和疤的更一致、光滑是很浅的。
简介:TheresultsofcommercialapplicationoftwotypesofC_8aromaticsisomerizationcatalystsunderdifferentfeedconditionswerecomparedtogainaninsightinthetechno-economicalbasisforselectingpropertechnologicalrouteattheplant.Thecomparisonrevealsdifferencesineveryaspectoffeedconsumption,unitcapacity,productoutput,productdistribution,andunitprocessparametersdependinguponwhichcatalysttypeisadoptedbytheintegratedPXcomplex.Thetypeofaromaticsisomerizationcatalysthasitsinfluenceontheplantscale,theconstructioncost,theprocessunitcapacityandtheproductcost,withthemagnitudeofitsimpactvaryingwithchangingfeedconditions.
简介:ThemoleculartransformationsofcarboxylicacidsinheavyacidicSLcrudebeforeandaftertrueboilingpointdistillationwereexaminedbyultra-highresolutionnegative-ionelectrosprayionization(ESI)Fouriertransformioncyclotronresonancemassspectrometry(FT-ICRMS).Theacidclass(heteroatomnumber),type(znumbers)andcarbonnumberdistributionswerepositivelycharacterized.Itwasfoundoutthatthetotalacidnumber(TAN)ofSLcrudedecreasedaftertrueboilingpointdistillation,andtheabundanceofO2classinmassspectrawasalsofoundtobereducedfrom67.6%to34.5%inSLTBPmixedcrudeasmeasuredbyMSspectra,indicatingtoapotentialcarboxylicaciddecomposition.However,itwasinterestingthatthecarboxylicacidstypedistributioninbothoilswasalmostthesamealthoughtheirrelativeabundanceinSLTBPmixedcrudeturnedtobemuchlower,suggestingthatvariouspetroleumcarboxylicacidtypeshavethesimilarthermaldecompositionreactionbehavior.Furthermore,foreachO2typeofacidsinSLTBPmixedcrude,theabundanceofcarboxylicacidswithcarbonnumberhigherthan35wasreducedgreatly,especiallyforthosewithcarbonnumberhigherthan60,themasspeaksofwhichwerenearlytotallyremoved,indicatingthatthelargecarboxylicacidmoleculesinheavyfractionsdecomposedmoresignificantlybecauseoflongerheatingtimeduringthetrueboilingpointdistillationprocess.Asaresult,thereductionofTANmaybecausedbythethermaldecompositionofcarboxylicacidsespeciallythosewithhighcarbonnumber,suggestingthatquickdistillationormuchlowerpressureisrequiredtoavoidthethermaldecomposition.