简介:<正>NaYzeolitewasmodifiedthroughdealuminationwithoxalicacid,andtheHYzeolitewasobtainedbycalcinationofthemodifiedNaYzeolite.Thezeolitemoldingprocesswascarriedoutatambienttemperature(25℃),andtheinfluenceofsolid/fuelmassratioandadsorptivedesulfurizationtimeontheHYzeolitewereinvestigatedthroughtestsonstaticselectiveadsorptivedesulfurizationofFCCgasolinecontainingorganicsulfurcompounds(withaScontent=135ppm).ThesulfurcontentandsulphidetypesintheFCCgasolinewereanalyzedbyaGC2010sulfuranalyzerandaGC-SCDchromatograph.ThetestresultsshowedthatthemoldedHYzeolitewasbetterthantheunmoldedHYzeolite.AtastaticadsorptivedesulfurizationtimeonthemoldedHYzeoliteequatingto6hours,asolid/fuelmassratioof1:3,thesulfurcontentofFCCgasolinewasdecreasedto30ppm,andthedesulfurizationratewasequalto78%.WhenthebreakthroughpointofthemoldedHYwasequalto50ppm,themoldedHYzeolitewascapableofadsorbing4.86mgofsulfurpergramofadsorbent.AndtheregenerationrateofmoldedHYzeolitewasequalto98%.
简介:TheapplicationofXzeoliteintheareasforproducingpara-xylenebyadsorptiveseparation,N2/O2separation,etc.,wasreviewed,andtheframeworkSiO2/Al2O3molarratio,thecationsandthewatercontentofXzeolitesignificantlyaffecteditsselectivityandcapacity.Astheactivecomponentofpara-xyleneadsorbent,theXzeolitewithaframeworkSiO2/Al2O3molarratioof2.2-2.4coupledwithcationsofBa^2+andK^+,aswellasawatercontentof4.0%-5.0%exhibitedhigherpara-xyleneselectivity.ForN2/O2separation,higherN2capacityandN2/O2separationfactorwereachievedwhentheXzeolitehadaframeworkSiO2/Al2O3molarratioof2.0coupledwithLi^+cations.TheintroductionofanothercationinXzeolitecouldfurtherincreasetheN2/O2separationfactor,whiletheadsorptionofwater,however,couldleadtoaremarkabledecreaseofN2capacity.Besides,theXzeolitecouldbeusedinadsorptiveseparationofhighlypureHeandselectiveadsorptionofCO2,CO,CH4,N2,Ar,andH2.