简介:ThephaseandmorphologytransformationduringthehydrothermaltreatingprocessofY2O3wasevaluatedwithX-raydiffcrcnce(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),particlesizeandspecificsurfaceareadetermination.TheresultsshowedthatthecubicY2O3didnottransferintohexagonalY(OH)3inpurewater.Therefore,purehexagonalY(OH)3withnanotubeandmicrorodmorphologieswereobtainedbyhydrothermaltreatingY2O3at150℃for12hin15mlof2mol/LNaOHsolutionwithandwith-outPVAorPEGItwassuggestedthatthecharacteristicpreferentialgrowthofY(OH)3wasattributedtothestructureanisotropyofhexahedronY(OH)3.TheadditionofPVAorPEGcouldpromotetheformingprocessofnanotubesbyselectiveadsorptionondifferentcrystalplanes,whichalteredthegrowthratealongdifferentdirectionsandresultedinthediffusionlimitofconstructingionsinthecentertopofrods.Finally,Y(OH)3:EuandY2O3:Eunanotubeswerealsosynthesizedbyusingthismethod,andtheirphotoluminescencepropertieswereevaluated.
简介:Inthepasttenyearstheeomplementarytristimulusspeetrophotometryll],eTs,hasseenitsdiverseappli-eations{2一61thoughmostresearehesremaininrelativelysimpesystems,andlessworkhasbeeninvolvinkinetiereaetions.AnattemPthasbeenmadeontheinvestigationofsomecomPlieatedsystemseontainingrareearthsandmeta一acetylchloroPhosPhonaz
简介:
简介:Whitebody-color(Y,Gd)BxV1-xO4-x:Eu3+phosphorswerepreparedbycoprecipitationreaction.UnderVUVexcitationat147nm,theredemissioncolorimetricpurityof(Y,Gd)BxV1-xO4-x:Eu3+phosphorismuchbetterthanthatofcommercialPDP(plasmadisplaypanels)phosphor(Y,Gd)BO3:Eu3+.Butitsrelativeemissionintensityisonlyabout90%ofthecommercialphosphor.
简介:StudyonMorphologyofSurfaceofLargeAreaYBCOThinFilmsonZr(Y)O2SubstrateWangRuikun(王瑞坤),SunLihong(孙丽虹),LiuHongfei(刘鸿飞)WangXiaopi?..
简介:Thenanosizedparticlematerialsofdoped-TiO2withY2O3werepreparedbymeansofsol-geltechniqueforuseinelectrorheological(ER)fluids,andtheircrystalstructuresweremeasuredbyX-raydiffraction(XRD)analysis.TocomparewiththepureTiO2,adistinctenhancementintheshearstressunderdcelectricfieldwasfoundbyusingsuchmaterials.Thiscanbeexplainedbytheincreaseofthedielectriclossanddielectricconstantatlowfrequency.TheeffectsofthecrystalstructureoftheparticlesonthedielectricpropertyandERperformanceofmaterialswereinvestigated.
简介:Redphosphor(Y,Gd)BO3:Eu3+withgrainshape,smallsize,non-agglomerate,highcrystallinityandgoodphotoluminescence(PL)intensitywaspreparedbyacomplexmethodthattheprecursorofthephosphorwaspreparedbyco-precipitationmethodandthephosphorwaspreparedbycombustionmethod.TheSEMphotosandthephotoluminescencespectrumexcitedunderVUVshowthatthemorphologyandluminescentpropertiesofthisphosphoraresatisfiedwhenanappropriateamountofureawasadoptedasthecombustionagentinthepreparationprocedure.
简介:TheelectrodeprocessofY3+iononmolybdenumandnickelelectrodeshasbeenstudiedbycyclicvoltammetryandchronopotentiometryintheYCl3-NaCl-KClmelt.Theoverallchargetransferprocessisatwo-stepreaction:Y3++e=Y2+;Y2++2e=Y.YttriumreducedonthenickelelectrodecanformaseriesofNi-Yalloys.X-raydiffractionanalysiswasemployedtodeterminethealloycompositionsformedunderdifferentcon-ditions.
简介:VariousaffectingfactorsanddegradationmechanismwerestudiedonultrasonicdegradationofmethylorangeadoptingY2O3dopinganataseTiO2catalystpreparedinlaboratory.Intheexperiment,theUV-VISspectrophotometerwasusedtofollowandinspectthedegradationprocessofmethylorange.TheresultsindicatethattheultrasonicdegradationratiosofmethylorangeinthepresenceofanataseTiO2catalystaremuchbetterthanthosewithoutcatalyst.Moreover,thecatalyticperformanceofY2O3dopinganataseTiO2catalystisobviouslyhigherthanthatofanataseTiO2catalystwithoutdoping.TheoptimalconditionswereadoptedinthisworkandthedegradationandCODeliminationratioofmethylorangegotto98%and99.0%in90min,respectively.
简介:EffectofCe-Mg-Si(lightRE)andY-Mg-Si(heavyRE)nodulizersonthemicrostructuresandmechanicalpropertiesofheavysectionductileironwasinvestigatedtodevelopthematerialofspent-nuclear-fuelcontainers.Twoas-castsweretreatedbythesamequalitypercentageoflightREandheavyRE,respectively.Fourpositionswerechosentostandfordifferentsolidificationcoolingratesofspecimens.Thetensilestrength,elongationandimpacttoughnessofspecimenstreatedbyheavyREwereallhigherthanthoseofthespecimenstreatedbylightRE.Withthedecreaseofcoolingrate,themechanicalpropertiesoftwospecimensdecreased,andthefracturemorphologychangedfromductilefracturetobrittlefracture.TheimprovingeffectofmechanicalpropertiesbetweenheavyREandlightREwasobviousduetothebetteranti-degradationpropertyofheavyRE.Whilethesolidificationprocesslastedformorethan250min,theimprovingeffectwasnotobviousduetoseriousspheroidalizationdecaying.
简介:TheZrO2-Al2O3ceramiccompositeswerepreparedbyappropriatetechniqueswithcommercialZrO2andAl2O3powdersasrawmaterialsandY2O3asstabilizer.TheresultsindicatethatwiththeintroductionofAl2O3intotheZrO2matrixwherethequantityofadditiveY2O3is3.5%(molefraction),thegrowthofZrO2grainsisefficientlyinhibited,whichhelpstheZrO2grainsexistinametastabletetragonalmanner;thushigherstrengthandtoughnessareacquired.Whenthecontentofaluminais20%(massfraction),thebendingstrengthandfracturetoughnessofthecompositesare676.7MPaand10MPa·m1/2respectively,themechanicalbehaviorsareclosetothosepreparedwithZrO2andAl2O3powderssynthesizedthroughwetchemicalapproach.Themechanicalbehaviorsofthecompositesarewellimprovedowingtothedispersiontougheningofaluminagrainsandphasetransformationtougheningofzirconiagrains.
简介:文章研究了对Mg-9Gd-4Y-0.6Zr合金在时效过程中的微观组织。在225℃时效初期硬度缓慢上升,之后硬度急剧上升,24h出现了明显的时效硬化峰,然后硬度开始下降。微观结构的分析结果表明,在初期(2h)产生了大量弥散分布的具有DO19结构的β″,而在峰值时(24h)出现具有bco的β′,在持续时效(384h)时出现亚稳相β1,而在后来的长时间时效(1000h)时出现既在原位转变的平衡相β。
简介:AseriesofSm~(3+)dopedY_2MoO_6werepreparedthroughhightemperaturesolidstatereactiontechnique.Theirphasestructures,morphologiesandluminescencepropertieswereinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andphotoluminescencespectrometry.ThemostintenseabsorptionofY_2MoO_6hostoccurredat367nm.EnergytransferfromhostlatticetoSm~(3+)ionscouldbeobserved,andtheschematicdiagramofenergytransferwasconstructed.ThecriticalenergytransferdistanceandenergytransfermechanismbetweenSm~(3+)ionswerediscussedindetail.Consideringthehighcolorpurityandappropriateemissionintensity,Sm~(3+)dopedY_2MoO_6couldbeapromisingphosphorundernearultravioletlightexcitation.
简介:Semi-solidAl2Y/AZ91magnesiummatrixcompositesslurrywaspreparedbyultrasonicvibration,effectofultrasonicvibrationtemperatureandtimeonmicrostructureofsemi-solidslurrywasinvestigated.Theresultsshowedthatwiththeultrasonicvibrationtemperaturedecreasingthesolidvolumefractionofsemi-solidslurryincreased.Thebestultrasonicvibrationtemperaturewas600oC.Withtheincreaseofultrasonicvibrationtime,theaveragegraindiameterofprimaryа-Mgparticlesdecreasedfirstly,thenincreased,theaverageshapefactorincreasedgraduallyanddecreasedslightlyafter90s,andafewrosettedendriteswereobservedafter120s.Thebestsemi-solidslurrywithaveragegraindiameterof75μmandshapefactorof0.7weregainedafterthemeltwastreatedbyultrasonicvibrationforabout60satnearliquidustemperature(600oC).Atlast,themicrostructureevolutionmechanismofsemi-solidmagnesiummatrixcompositesslurrywasanalyzedbythetheoriesofthermodynamicsandkinetics.
简介:Er~(3+)andLa~(3+)codopedY_2O_3nanocrystallinepowdersweresynthesizedbygelcombustionmethodandcharacterizedwiththermalanalysis,X-raydiffraction(XRD),transmissionelectronmicroscopy(TEM),high-resolutionTEM(HRTEM)techniquesandfluorescencespectroscopy.Afterbeingcalcinedat1200oC,the(Y_(1–x)La_x)_2O_3:Er~(3+)powderswereconfirmedtobecubicY_2O_3phasewiththecrystallinegrainsizeintherangeof20–40nm.TheEr~(3+)emissionat1.53μmfromthe~4I_(13/2)→~4I_(15/2)transitionwasobserved,whichwasfoundtobeenhancedbyintroducingLa~(3+)ions.SuchenhancementcouldbeattributedtotheadjustmentofEr~(3+)ions'localenvironmentbythecodopingofLa~(3+)ions,leadingtotheincreasedgroundstateabsorptioncrosssectionofEr~(3+)ions.
简介:(Y,Gd)BxV1-xO4-x:Eu3+phosphorswerepreparedbysolidstatereaction.Theredemissioncolorpurityof(Y,Gd)BxV1-xO4-x:Eu3+phosphorismuchbetterthanthatoftherecentwidely-usedcommercialredemittingphosphor(Y,Gd)BO3:Eu3+anditsrelativeemissionintensityis84%ofthecommercialphosphor(Y,Gd)BO3:Eu3+.Itisexpectedthat(Y,Gd)BxV1-xO4:Eu3+phosphorwillbeapromisingcandidateforPDP(plasmadisplaypanels)application.