简介:Theneedformoreactiveandhydrothermallystablefluidcatalyticcracking(FCC)catalyststocombattheeffectofmetalcontaminantshasledtoanincreaseindemandforrareearthoxides.RareearthoxidesenhancecatalystactivityandpreventthelossofacidsitesduringtheFCCunitoperation,especiallywhenheavyresiduewithhighmetalcontentisusedasfeed.Inthispaper,areviewwascarriedouttoshowtheeffectsofrareearthelementsonthestructure,activity,andstabilityofFCCcatalysts.Also,theuseofrareearthelementsasvanadiumtrapswasanalyzedinconjunctionwiththemechanismofcatalystdeactivationbyvanadium.TheobjectivewastoelucidatetheinteractionofvanadiumspecieswiththezeolitecomponentoftheFCCcatalystsandtheroleofrareearthelementsincounteringthedeleteriouseffectsofvanadiumontheFCCcatalysts.
简介:ApplicationoftheEu3+IonforSiteSymmetryDeterminationBinnemansK,Gorller-WalrandC(UniversityofLeuven,DepartmentofChemistry,Co?..
简介:有色金属的分类很多,大约有80多种,大致按其比重、价格、在地壳中的储量及分布情况和被人们发现与使用情况的早晚等分为五大类。(1)重有色金属;指比重大于4.5的有色金属。包括铜,镍,锢,铅,锌,锑,汞,镉和铋。(2)轻有色金属;指比重小于4.5的有色金属。包括铝,镁,钙、钾、锶和钡。(3)贵金属;指在地壳中含量少,开采和提取都比较困难,对氧和其它试剂稳定,价格比一般金属贵的有色金属。包括金、银。和铂族元素。一般比重都较大,熔点较高在916—3000度,有很好的化学稳定性、优良的抗氧化性及耐腐蚀性。(4)半金属;一般指硅、硒、碲、砷和硼五种元素。其物理化学性质介于金属和非金属之间。如砷是非金属,但它能传热和导电。
简介:Nd:钇铝柘榴石先锋粉末被同类的降水,和Nd综合:钇铝柘榴石透明陶艺被真空sintering为5h在1700°C作好准备。陶器的材料被轻发射度和地排放枪环境扫描显微镜描绘。用统计和立方米科学理论,学习在在轻发射度和立体声之间的量的关系上被执行在三维的欧几里德几何学的空格的逻辑参数。这被发现Nd的发射度:有在厚度的1公里的钇铝柘榴石分别地在可见、在红外线附近的波长是大约45%和58%。发射度线性地与增加相等的范围直径增加并且当相等的范围直径是20μm时,到达单个水晶的理论价值。有每统一谷物和分离谷物的体积增加吝啬的特定的区域的发射度减少,和有增加的发射度减少在Nd意味着谷物的免费距离:钇铝柘榴石陶艺。
简介:AnovelTb(III)ternarycomplexTb(p-BBA)_3MAAwassynthesizedwith4-benzoylbenzoicacid(p-BBA)andmethacrylicacid(MAA)asligands.ThecomplexwascharacterizedbyIR,UV-visible,thermogravimetricanalysisandfluorescencespectroscopy.Monitoredat544nm,thecomplexdisplayedwideandstrongexcitationbandat300–400nm,whichmatchedwellwiththe365nm-emittingUVchip.Thecomplexexhibitedexcellentgreenemissionat544nm(~5D_4→~7F_5transitionofTb~(3+))underanexcitationat365nm.Besides,thecomplexshowedhighthermalstability.Itsintramolecularenergytransferprocesswasfurtherdiscussed.Furthermore,thecomplexalsohadhigherfluorescencelifetime(1.38ms)andhigherquantumyield(0.372).Finally,electroluminescentpropertiesindicatedthatwhenusedtofabricateLEDwith365nmUVchip(powerefficiencyis18.6lm/W),thecomplexremaineditsfavorableopticalperformance.TheseresultsimpliedthatTb(p-BBA)_3MAAcouldbeusedasagreenphosphorforNUV-basedwhiteLED.