简介:为了明确团聚现象及表面性质对ZnS纳米材料发光性质的影响,采用SiO2对ZnS材料进行了表面修饰,并对ZnS及ZnS/SiO2复合材料的光学性质进行对比研究。采用吸收光谱分析了包覆前后光吸收性质的差异,发现SiO2包覆后ZnS纳米材料的带边由333nm红移至360nm。为了研究ZnS纳米材料与ZnS/SiO2纳米复合材料的光发射性质,分别对含纳米材料的水溶液样品及粉末样品的发光光谱进行了采集。对比研究的结果表明,SiO2包覆后ZnS纳米材料在蓝紫光区的发光得到了明显增强。以氙灯作为激发光源所获得荧光光谱显示ZnS/SiO2粉末样品发光的积分强度增大为原来的17.5倍,但相同条件下针对溶液样品的测试结果显示其发光强度只增大了1.1倍,这种增强可用SiO2的存在抑制了ZnS纳米粒子间的团聚来解释,且这一推断由325nm紫外激光激发下获得的光致发光数据进行了验证。
简介:Variousagriculturalcropresiduesincludingcornstover,corncob,andsorghumstalkwithamoisturecontentof75wt%weresubjectedtoalongpretreatment(12-60h)withsupercriticalCO2(scCO2),atlowtemperature(50-80℃)andapressureof17.5-25.0Mpa.Thesugaryieldsfromtheenzymatichydrolysis(EH)ofthepretreatedsampleswereasmuchasthree-tofourfoldgreaterthanthoseaffordedbytherawmaterials.However,whenpretreatmentwasconductedwithinashorttime(e.g.0.5h),aspreviouslyreportedintheliterature,onlyaslightincreaseintheEHsugaryieldswasobserved.TheproposedscCO2pretreatmentmechanismdemonstratedtheroleofmoistureinthesystem.Wetting,softening,andswellingwereobservedtomainlyaffectthelignocellulosewhenasuitableamountofwaterwasadded.Finally,thesampleswereanalysedbyX-raydiffractionandscanningelectronmicroscopy,beforeandafterpretreatment,toinvestigatethechangesinthemicroscopicstructureofthebiomass.
简介:Anovelgas-phaseelectrocatalyticcellcontainingalow-temperatureprotonexchangemembrane(PEM)wasdevelopedtoelectrochemicallyconvertCO2intoorganiccompounds.TwodifferentCu-basedcathodecatalysts(CuandCu-C)werepreparedbyphysicalvapordepositionmethod(sputtering)andsubsequentlyemployedforthegas-phaseelectroreductionofCO2atdifferenttemperatures(70-90℃).ThepreparedelectrodesCuandCu-CwerecharacterizedbyX-raydiffraction(XRD),X-rayphotoemissionspectroscopy(XPS)andscanningelectronmicroscopy(SEM).Asrevealed,CuispartiallyoxidizedonthesurfaceofthesamplesandtheCuandCu-Ccathodiccatalystswerecomprisedofaporous,continuous,andhomogeneousfilmwithnanocrystallineCuwithagrainsizeof16and8nm,respectively.Theinfluenceoftheappliedcurrentandtemperatureontheelectro-catalyticactivityandselectivityofthesematerialswasinvestigated.Amongthetwoinvestigatedelectrodes,thepureCucatalystfilmshowedthehighestCO2specificelectrocatalyticreductionratesandhigherselectivitytomethanolformationcomparedtotheCu-Celectrode,whichwasattributedtothehigherparticlesizeoftheformerandlowerCuO/Curatio.Theobtainedresultsshowpotentialinterestforthepossibleuseofelectrical「enewableenergyforthetransformationofCO2intovaluableproductsusinglowmetalloadingCubasedelectrodes(0.5mgCucm2)preparedbysputtering.
简介:Inthiswork,MoOxpromotedIr/SiO2catalystswerepreparedandusedfortheselectivehydrogenolysisoftetrahydrofurfurylalcohol(THFA)to1,5-pentanediolinacontinuousflowreactor.Theeffectsofdifferentnoblemetals(Ir,Pt,Pd,Ru,Rh),supportsandIrcontentswerescreened.Amongtheinvestigatedcatalysts,4wt%Ir-MoOx/SiO2withaMo/Iratomicratioof0.13exhibitedthebestcatalyticperformance.ThesynergybetweenIrparticlesandthepartiallyreducedisolatedMoOxspeciesattachedonthemisessentialfortheexcellentcatalyticperformanceofIr-MoOx/SiO2.ThecatalystexhibitedabetterhydrogenolysisefficiencyofTHFAwiththeselectivityof1,5-pentanediolof65%–74%ataconversionofTHFAof70%–75%whentheinitialTHFAconcentrationisrangingfrom20wt%and40wt%.AndhighersystempressurewasalsoinfavoroftheconversionofTHFA.Duringastabilitytest,theconversionofTHFAand1,5-pentanediolyieldoverIr-MoOx/SiO2decreasedwithreactiontime,whichcanbeexplainedbytheleachingofMospeciesduringthereaction.
简介:Catalyticpropertiesofthemetal-organicframeworkCr-MIL-101insolvent-freecycloadditionofCO2toepoxidestoproducecycliccarbonatesusingtetrabutylammoniumbromideasco-catalysthavebeenexploredundermildreactionconditions(8barCO2,25C).Styreneandpropylenecarbonateswereformedwithhighyields(95%and82%,respectively).CatalyticperformanceofCr-MIL-101wascomparedwithotherMOFs:Fe-MIL-101,Zn-MOF-5andHKUST-1.Thecatalyticpropertiesofdifferentquaternaryammoniumbromides,Cr-MIL-101aswellasPW12/Cr-MIL-101compositematerialhavebeenassessedinoxidativecarboxylationofstyreneinthepresenceofbothtert-butylhydroperoxideandH2O2asoxidantsat8100barCO2and2580Cwithselectivitytostyrenecarbonateupto44%at57%substrateconversion.
简介:Throughournewly-developed'chemicalvapordepositionintegratedprocess(CVD-IP)'usingcarbondioxide(CO2)astherawmaterialandonlycarbonsourceintroduced,CO2couldbecatalyticallyactivatedandconvertedtoanewsolid-formproduct,i.e.,carbonnanotubes(CO2-derived)ataquitehighyield(thesingle-passcarbonyieldinthesolid-formcarbon-productproducedfromCO2catalyticcaptureandconversionwasmorethan30%atasingle-passcarbon-base).Forcomparison,whenonlypurecarbondioxidewasintroducedusingtheconventionalCVDmethodwithoutintegratedprocess,nosolid-formcarbon-materialproductcouldbeformed.IntheadditionofsaturatedsteamatroomtemperatureinthefeedforCVD,thereweremuchmoreend-openingcarbonnano-tubesproduced,ataslightlyhighercarbonyield.Theseinspiringworksopenedaremarkableandalternativenewapproachforcarbondioxidecatalyticcapturetosolid-formproduct,comparingwiththatofCO2sequestration(CCS)orCO2mineralization(solidification),etc.Asaresult,therewasmuchlessbodyvolumeandalmostnogreenhouseeffectforthissolid-formcarbon-materialthanthoseofprimitivecarbondioxide.
简介:TheobjectiveoftheApollonprojectisthegenerationof10PWpeakpowerpulsesof15fsat1shot/minute.InthispapertheApollonfacilitydesign,thetechnologicalchallengesandthecurrentprogressoftheprojectwillbepresented.
简介:Thescientificprogramofthegroupcoversbigbangnucleosynthesis,hydrostaticburninginstarsandexplosivenucleosynthesisinsupernova.Byconsideringnon-equilibriumstatistics,wesuggestapossiblewaytosolvetheLiprobleminbigbangnucleosynthesis.The13C(α,n)16Oisthemajorneutronsourceforthes-processhappeninginAGBstars.The19F(p,α)16Oisrelevanttotheproductionoffluorine.WearedevelopingexperimentalplatformstostudytheimportantreactionforthefirsttimedirectlyattheirstellarenergiesinJinpingUndergroundLaboratory.The59Festellardecayrateisimportantfortheproductionof60Fe,animportantisotopewhosegammarayhasbeenobservedbysatellites.WedetermineitsstellardecayrateforthefirsttimeusingexperimentalB(GT)strength.Thenewratereducesthediscrepancyofthe60Feyieldsbetweenthemodelpredictionsandtheobservations.Theundergroundexperimentisexpectedtobeginin2018.
简介:“夜生活”的概念并不纯粹,对某些人来说,它就是一种白天的生活。有那么一群人.当我们于梦乡中酣畅淋漓时.还在默默地忙碌着,我们笑称他们为夜猫子,其实他们只是和我们作息时间表不同罢了。“日落而作.日出而息”.是他们基本的作息时间.“黑白颠倒”是他们的基本特征.他们自我标榜:我们是夜行一族。在万籁俱寂的夜晚,人的思绪却很容易被集中起来。而夜行一族乃至很多可以自主时间的人宁愿将工作时间定在晚上,据说这样可以取得比白天更高的工作效率。可是当看到他们的工作状态时.我们不禁会暗地佩服他们的勇气和能力,就是在那气压骤降、血压骤升的时段里,他们也一样找到了人生很HIGH的境界。以下十个职业便是夜行族堪称最具快感最过瘾又不乏时尚魅力的职业.我们一起看看他们都在忙些什么……
简介:TheobjectiveoftheApollon10PWprojectisthegenerationof10PWpeakpowerpulsesof15fsat1shotmin-1.InthispaperabriefupdateonthecurrentstatusoftheApollonprojectispresented,followedbyamoredetailedpresentationofourexperimentalandtheoreticalinvestigationsofthetemporalcharacteristicsofthelaser.Morespecificallythedesignconsiderationsaswellasthetechnologicalandphysicallimitationstoachievetheintendedpulsedurationandcontrastarediscussed.