简介:1-Ethoxycarbonylalkyldiphenylpolystyrylphosphoniumtriflatescanbeeasilypreparedbyquaternizingdiphenylpolystyrylphosphinewithethyl2-trifloxyalkanoates;basetreatmentofthesepolymer-supportedphosphoniumtriflatesaffords1-ethoxycarbonylalkylidenephosphoraneswhicharestableandundergosatisfactoryWittigreactions.
简介:PolymericGrignardReagent(PGR)basedonthechloromethylatedpoly(ST-co-DVB)resinhasbeenpreparedbymeansofanthracene-magnesiumcomplexinTHF(Anth-Mg-THF),andpolymermatrixwithlongpolymethylenespacerwassynthesizedviathecouplingreactionbetweenPGRandα,ω-dibromoalkanes.Basedonthestudiesoffactorsaffectingthecoupling,suchascatalyst,reactiontime,thelengthofspaceretc.,thispaperofferstheoptimalreactionconditionsandthreetypicalexperimentprocedures.ThemechanismfortheformationandcouplingreactionofPGRarealsodiscussed.
简介:Anovelbeadfromofploymerofhighsorptioncapacityforureawereobtainedbythereactionofglutaricdialdehydewithchitosandispersedinaceticacidsolution.Thesorptioncapacityreached-82.0mg/gsorbentat37℃andpH7.4Theconcentrationofureainthebuffersolutionwas1300mg/l.Thesorptionofureawasrelatedtothedegreeofcrosslinkingofthesorbent,concentrationofurea,ionicstrengthandtemperature.