简介:RamanpeaksofvarioushydratesintheH2O-NaCl-CaCl2systemhavebeenpreviouslyidentified,butaquantitativerelationshipbetweentheRamanpeaksandXNaCl(i.e.,NaCl/(NaCl+CaCl2))hasnotbeenestablished,mainlyduetothedifficultytofreezethesolutions.Thisproblemwassolvedbyaddingaluminapowdertothesolutionstofacilitatenucleationofcrystals.Cryogenic(-185oC)Ramanspectroscopicstudiesofalumina-spicedsolutionsindicatethatXNaClislinearlycorrelatedwiththetotalpeakareafractionofhydrohalite.Capsulesofsolutionsmadefromsilicacapillarywerepreparedtosimulatefluidinclusions.Mostoftheseartificialfluidinclusionscouldnotbetotallyfrozenevenattemperaturesaslowas-185oC,andthetotalpeakareafractionofhydrohaliteisnotcorrelatedlinearlywithXNaCl.However,thedegreeofdeviation(?XNaCl)fromthelinearcorrelationestablishedearlierisrelatedtotheamountofresidualsolution,whichisreflectedbytheratio(r)ofthebaseline"bump"area,resultingfromtheinterstitialunfrozenbrinenear3435cm-1,andthetotalhydratepeakareabetween3350and3600cm-1.Alinearcorrelationbetween?XNaClandrisestablishedtoestimateXNaClfromcryogenicRamanspectroscopicanalysisforfluidinclusions.
简介:Naturalgascontaininghydrogensulphide(H2S)hasbeenfoundinseveralpetroliferousbasinsinChina,suchastheSichuanBasin,BohaiBayBasin,OrdosBasin,TarimBasin,etc.NaturalgaswithhigherH2Scontents(H2S>5%mol.)ismostlydistributedinboththegasreservoirsofDukouhe,Luojiazhai,PuguangandTieshanpo,whichbelongtotheTriassicFeixianguanFormationinthenortheasternSichuanBasinandthoseoftheKongdian-ShahejieformationsinthenortheasternJinxianSagoftheJizhongDepression,BohaiBayBasin.IntheSichuanBasin,theH2Scontentsofnaturalgasaverageover9%andsomecanbe17%,whilethoseoftheBohaiBayBasinrangefrom40%to92%,beingthenoneofthegasreservoirswiththehighestH2Scontentsintheworld.Basedondetailedobservationandsampleanalysisresultsofatotal5000mofcorefromover70wellsintheabove-mentionedtwobasins,especiallysulfurisotopicanalysisofgypsum,brimstone,pyriteandnaturalgas,alsowithintegratedstudyofthegeochemicalcharacteristicsofhydrocarbons,itisthoughtthatthenaturalgaswithhighH2Scontentsresultedfromthermochemicalsulfatereduction(TSR)reactions.Amongthem,thenaturalgasintheFeixianguanFormationresultedfromTSRreactionsparticipatedbyhydrocarbongas,whilethatintheZhaolanzhuangoftheJinxianSagbeingtheproductofTSRparticipatedbycrudeoil.DuringtheconsumptionprocessofhydrocarbonsduetoTSR,theheavyhydrocarbonswereapttoreactwithsulfate,whichaccordinglyresultedinthedrycoefficientofnaturalgasincreasingandthecarbonisotopesbecomingheavier.
简介:<正>1IntroductionTheundergroundbrineresourcesdistributingwidelyinSichuanBasin,Chinahavedrawnworldwideattentionduetotheirunusualelementabundanceandexcellentquality.
简介:OurfieldworkandgeochronologicstudiesinnorthernHebeiandwesternLiaoningareasindicatethatthemajorMesozoiccontractionaleventsintheYanshanbeltareof(1)pre-MiddleJurassic(Indosinian?),(2)LateJurassicand(3)EarlyCretaceousage.ThefirstN-SshorteningcouldbeaconsequenceofthecollisionoftheMongolianarcsalongtheSolonsutureagainsttheNorthChinaplate.Siberian-NorthChinaplatecolli-
简介:The10thCoalGeologyConference,jointlyorganizedbytheFacultyofScienceoftheCharlesUniversityinPrague,theCzechGeologicalSurveyandtheInstituteofGeologyoftheAcademyofSciencesoftheCzechRepublic,tookplaceinJune7-11,2004,attheFacultyofScience.Thecoalgeologyconferenceshavebeenheldatthefacultyeverythreeorfouryearssince1972.Theywereprecededbycoalgeologyseminarswhichbeganevenearlier,inJanuary1968.Theseseminarsandconferencesprovidedanexcellentopportunitytoexchangeknowledgeandnewinformationoncoalgeologyandrelatedfieldsand,aboveall,tobringtogetherpeoplefromvariousfieldsstartingwithscienceandendingupwithawidespectrumofinterests.
简介:M7.0Lushan地震触发了的s山崩的一个巨大的数字。印射的山崩危险性是很重要的。证据(悲痛)和逻辑回归(LR)的重量方法广泛地为LSM(印射的山崩危险性)被使用了。然而,限制仍然存在。悲痛能够估计每个因素的不同的班的影响,但是忽视在因素之间的关联。当它不能够评估不同的班的影响时,LR能在因素之中分析关系。这份报纸为LSM建议LR和悲痛的一个联合方法,利用他们的单个优点并且克服他们的限制。1289山崩的库存被使用:70%为为确认训练并且留下是选择随机的。11个山崩条件因素在模型被采用,结果用操作特征(巨鸟)曲线的接收装置被验证。结果证明LR悲痛模型比LR模型有更好的精确性,生产在有0.802成功的价值的曲线下面的一个区域并且0.791预兆,比LR模型的高(0.715成功并且0.722预兆)。悲痛和LR的联合方法能为印射的导致地震的山崩危险性提供精确性的有希望的水平,这因此被结束。