简介:使用傅里叶变换光谱仪(FTIR)测试甚长波宽波段(6.4~15μm)红外探测器响应光谱的过程中,发现短波方向响应光谱异常。通过分步测试分析发现:探测器和放大器工作在非线性工作区导致某些情况下仪器信号发生饱和,引起了短波方向响应光谱畸变的现象。对FTIR测量甚长波宽波段(6.4~15μm)红外探测器响应光谱的畸变现象进行了分析,认为探测器的响应时间是影响其响应光谱的重要因素,并通过试验确定了测试系统对不同探测器所设置的测试参数,消除了响应光谱畸变的现象,并提高了测试准确度。
简介:MonovalentionsLi+,Na+,andK+,aschargecompensators,areintroducedintoCaYAl3O7:M(M=Eu3+,Ce3+)inthisletter.TheircrystalphasesandphotoluminescencepropertiesofdifferentalkalimetalionsdopedinCaYAl3O7areinvestigated.Inaddition,theinfluenceofchargecompensationionLi+whichhasamoreobviousroleinimprovingluminescenceintensityonCaYAl3O7:Eu3+phosphorisintentionallydiscussedindetailandapossiblemechanismofchargecompensationisgiven.Theenhancementofredemissioncenteredat618nmbelongingtoEu3+isachievedbyaddingalkalimetalionLi+under393-nmexcitation.
简介:Weprovidethefirstdemonstrationofpureredemissioninthevisiblelightregionviathree-photonexcitationinmonodisperseNa_3ZrF_7:Ernanoparticles(NPs)byusingalaseroperatinginthetelecommunicationband.NPsof~22nmindiameteraresynthesizedat260°Cbythethermaldecompositionmethod.TheexperimentalresultsrevealthattheNa_3ZrF_7:ErNPsexhibitpureredemissioninthevisibleregionunder1480nmlaserexcitation,andtheemissionintensityissignificantlyinfluencedbytheEr~(3+)ionconcentration.Thedecaytimesofthe~4S_(3∕2)→~4F_(15∕2)and~4F_(9∕2)→~4F_(15∕2)transitionsoftheEr~(3+)ionsat540and655nm,respectively,arereducedbyincreasingtheEr~(3+)ionconcentrationintheNa_3ZrF_7:ErNPs.Thesuppressedemissionintensityresultfromthedefect-relatedquenchingeffect:whentrivalentEr~(3+)ionsreplactetravalentZr~(4+)ions,extraNationsandFvacanciesareformedtore-balancethechargeintheNa_3ZrF_7matrix.TheemissioncoloroftheNa_3ZrF_7:ErNPsisrelatedtothecrossrelaxationbetweenEr~(3+)ions.Theseresultsprovideanimportantsteptowardmoreeffectivebiologicalimagingandphotodynamictherapybyminimizingthescatteringoftheexcitationlightandincreasingthepenetrationdepth.
简介:ZnCuInS/ZnS量子点是一种无重金属“绿色”半导体纳米材料。制备出了直径为2.9nm的ZnCuInS/ZnS核壳量子点。从ZnCuInS/ZnS量子点的吸收及光致发光光谱中可以看到,量子点的斯托克斯位移为410meV。这样大的斯托克斯位移表明,ZnCuInS/ZnS量子点的复合机制与缺陷能级有关。研究并计算了在辐射及非辐射驰豫过程的(Huang-Rhys)因子及平均声子能量。结果表明在50~373K范围内,能量带隙的变化以及光致发光光谱的增宽是分别由光从能带边缘向缺陷能级跃迁及载流子声子耦合导致的。
简介:考虑光场限制因子、温度变化和阱间载流子非均匀分布,给出A1GaInAs多量子阱增益求解的分析模型。对量子阱应变量、阱宽和载流子浓度对材料增益TE模和TM模的影响进行了分析。设计出C波段内增益低偏振相关的混合应变多量子阱结构。在15~45℃温度范围,其模式增益具有低的偏振相关性(2%以内);当注入载流子浓度从2×10^24m^-3。增大到3×10^24m^-3时,模式增益逐渐增大,且能在一定温度下保持低的偏振相关(3%以内)。