简介:ToseparatethecadmiumandnickelresourcesinwasteNi-Cdbatteries,aself-designedvacuumdistillationrecyclingsystemwasstudiedunderlaboratoryconditions.Theeffectsofsystemtemperature,operatingpressure,andtimeontheseparationofNiandCdwerestudiedrespectively.Themechanismofvacuumthermalrecyclingwasalsodiscussed.ResultsshowthatvacuumdistillationisaveryeffectiveseparationmethodforwasteNi-Cdbatteries.AtaConstantpressure,theincreaseoftemperaturecanimprovetheseparatingefficiencyofCd.Whenthetemperatureis1173K,Cadmiumcanevaporatecompletelyfromthesamplesduring3hat10Pa,ThereductionofpressureinacertainrangeiseffectivetotheseparatingofCdfromNi-Cdbatteriesbyvacuumdistillation.
简介:TheCurietemperatureof(Nd1-xPrx)2Fe14CoyBcompounds(x=0,0.2,…,1.0andy=O,2,4,6,14)hasbeendeterminedwithACinitialsusceptibilitymeasurement.ItwasfoundthatthevariationsofCurietempera-turewithxisnotlinearfory=0and14,whereasitislinearforothervaluesofy.Thelatticeconstantsof(Nd1-xPrx)2Fet14BweredeterminedbyusingX-raydiffraction.Thelatticeexpansionwasmostlyalongthecaxis,whereasthatalongthea-axisremainedpracticallyzeroforthewholeseries.ItissuggestedthatPratomsmayshowsitepreferenceinR2M14Bcompounds(M=FeorCo).DuetothesubstitutionofCoforFe.thetendencyofsitepreferenceofPrbecomeslesspronounced,whichmaybeattributedtothedecreaseofdiffer-enceofcrystalelectricfield(CEF)actingonthetworareearthsiteswiththeintroductionofCoorFe.Incon-trasttothatofthePratoms,thesitepreferenceofCoiu(Nd(1-x)Prx)2Fe(14-y)CoyBcompoundsdoesnotdependonthecompositionoftherareearthsublattice(R=NdorPr).
简介:Themicrostructuresofas-castandas-solutionMg–12Gd–2Er–1Zn–0.6Zralloyswereinvestigatedbyopticalmicroscopy(OM),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),highresolutiontransmissionelectronmicroscopy(HRTEM)X-raydiffraction(XRD)andselected-areaelectrondiffraction(SAED)inthepresentinvestigation.TheresultsshowthattheprimaryeutecticphaseMg5(Gd,Er,Zn)andsomeflocculentfeaturesarefoundintheas-castalloy;theSAEDpatternindicatesthattheseflocculentfeaturesarethedenseareasofstackingfaults.The14H-LPSOstructureprecipitatesinthetemperaturerangeof673–793K,andthevolumefractionof14H-LPSOstructureincreaseswiththeextensionofheatingtime;however,thereisnoprecipitationof14H-LPSOstructurewhenthetemperaturereachesupto803K.Inaddition,theMg5(Gd,Er,Zn)phasedissolvesgraduallyalongwiththeprecipitationof14H-LPSOstructure.
简介:针对23Co14Ni12Cr3Mo超高强度钢材料,研究喷丸强化对其表面性能的影响。采用扫描电镜、白光干涉仪等设备,分析喷丸强化对试样表面形貌、粗糙度、硬度、残余应力、元素含量等的影响。结果表明:喷丸强化后,试样表面留有大量弹坑,产生明显塑性变形;表面粗糙度增大,算术平均粗糙度为1.33μm;硬度显著增大,最表层硬度由喷丸前的HV476增加至HV497,硬化层深度约150μm;试样表层的残余压应力值由375MPa增加至475MPa,最大残余压应力值约518MPa,位于距表面50μm深度处,喷丸形成的残余压应力层深度约为134μm;喷丸后试样中C、Si、Cr等各元素的质量分数均略有增加。喷丸在一定程度上改善了23Co14Ni12Cr3Mo钢材料的表面性能,有利于提高其疲劳抗力和耐腐蚀性。