学科分类
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19 个结果
  • 简介:PhaseEquilibriaCalculationoftheGaInSbTernarySystemXieYun′an,QiaoZhiyu,XingXianranandWangCong(谢允安)(乔芝郁)(邢献然)(王聪)Dept.ofPhys...

  • 标签: GA In SB PHASE EQUILIBRIA GA
  • 简介:CoerciveForceofγ-PhaseinWC-CoCementedCarbidesLiuShourongandSunJing(刘寿荣)(孙景)(TianjinInstituteofHardAlloys,Tianjin300222,Tianji...

  • 标签: WC-CO CEMENTED carbides γ-phase SPECIFIC coercive
  • 简介:ThesubmicronpowdermixturesofTiC-TiN-WC-Mo-C-Nisinteredat1400℃orbelowinvacuumwerestudiedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM)analyses.TheresultsshowedthatMo2Cformedat800℃orbelow.BothWCandMo2Cdisappearedat1200℃,andTiNdisappearedat1250℃.Inaddition,thevariationsoflatticeconstantsofthetitaniumcarbonitrideandnickelbinderphasewithsinteringtemperaturewereexperimentallyobtained,andthereasonwasanalyzed.

  • 标签: SUBMICRON CERMET PHASE SINTERING
  • 简介:晶体结构和加氢行为(La_(1-x)Mg_x)_3Al(x=0.1,0.2,0.3,和0.4)合金被调查。这被发现有x=的合金0.1La和第0.2consi(Mg,艾尔),La,和一个新奇阶段。新奇阶段作为La_2Al被决定。当Mg满足增加,La_2Al的数量减少,这被显示出。当x增加到0.3时,onlyLa(Mg,艾尔)并且La_2Al的小数量存在。当x是0.4时,La_2Al阶段消失,合金包含两La(Mg,艾尔)并且La(艾尔,Mg)_2洗阶段。(La_(0.9)Mg_(0.1))_3Al并且(La_(0.7)Mg_(0.3))_3Al合金能被氢的吸收在473K分解成LaH_3,MgH_2,和La_2Al_5。

  • 标签: 金属间化合物 (La1-xMgx)3Al合金 镧基合金 铝基合金 相位关系 氢化性质
  • 简介:用于有机化合物的抽取的稳固阶段的抽取(SPE)技术有创作力地在纸被用作无机的黄金的抽取。技术的二种类型被建议并且探索,也就是SPE和第四级的铵表面活化剂的liquidliquid抽取(LLE)[cetytrimethyl铵溴化物(CTMAB),cetylpyridine溴化物(CPB),本甲基dimethyldodecyl铵氯化物(BDMDAC),并且dodecyltrimethyl铵氯化物(DTMAC)]。表面活化剂能与Au(CN)2到形式,离子的建筑群,和混合物能被反向阶段的结合的硅石胶化的SPE列提取。因此,SPE的一个新方法被建议与高选择,可靠性,和简洁的这些特征提取黄金。黄金的恢复率是超过98的试验性的结果表演?%,和稳固阶段的抽取列容易没被损坏,它能反复被使用。新方法能也从碱的氰化物答案被用作黄金的抽取过程。而且,纸也提出金抽取的一个新过程。

  • 标签: 季铵盐表面活性剂 固相萃取柱 溶液 氰化 碱性 十六烷基三甲基溴化铵
  • 简介:基于锆的合金的Intermetallics和阶段转变,Zr-1.0Sn-0.3Nb-0.3Fe-0.1Cr,被常规X光检查调查衍射(XRD),微分扫描热量测定(DSC),和膨胀测量。三种类型也就是,猛抛(ZrNb)2Fe,Zr(CrFe)2,并且Zr3Fe,被XRD检测。立方的Ti2Ni类型(ZrNb)2Fe被发现是主要猛抛在里面合金,和它被建议溶解在861点

  • 标签: 金属间化合物 相变 X射线衍射 锆合金
  • 简介:1.6公里厚的表的非合金的钛的变硬的激光转变(LTH),更近,到ASTM,等级3化学作文用2kWCWNd被调查:钇铝柘榴石激光。激光力量的效果(750-1250W),扫描速度(10003000mm/min)和焦点的点位置(从?10到?30公里)在热输入,和变硬祷告的几何学上(即变硬的祷告宽度(HBW),变硬的深度(HD)和变硬的祷告的入口的角度与表面(AEHB)介绍)用反应表面方法论(RSM)被调查。试验性的计划基于Box-Behnken设计矩阵方法。为预言热输入和变硬的祷告几何学的线性、二次的多项式方程被开发。结果显示建议模型在变硬的参数的限制以内足够地预言回答被使用。回归方程能被用来为需要的标准发现最佳变硬条件,这被建议。

  • 标签: 激光相变硬化 硬化参数 热输入 合金 质量 作者
  • 简介:电子结构和在不同压力(260,320,400和600GPa)的新奇Na-hP4高压力阶段的光性质被密度调查有为交换和关联精力的概括坡度近似(GGA)的功能的理论(DFT)。沿着在Brillouin地区,状态(DOS)的密度和状态(PDOS)的部分密度的更高的对称斧子的乐队结构被介绍。乐队差距增加,精力乐队膨胀到某程度,压力增加。绝缘的功能,反射率,精力损失功能,光吸收系数,光传导性,折射索引和扑灭系数为在不同压力讨论Na-hP4高压力阶段的光性质被计算。

  • 标签: 光学特性 电子结构 高压相 第一性原理 广义梯度近似
  • 简介:1IntroductionIthasbeendemonstratedthatspinelstructurelithiummanganeseoxideisthemostpromisingcathodefor“lithiumion”bateriesbe...

  • 标签: LITHIUM MANGANESE oxide Lithiumion battery SYNTHESIS
  • 简介:β-phase上的超声的处理的效果(Mg17Mg-9.0wt.%Al合金的艾尔12)形态学被学习。结果证明与在Mg-9.0wt.%Al团结期间采用的高紧张的超声的颤动,在营舍的全部生气的节的β-phase显著地被精制并且也变化了从对不连续的形态学连续。球形的β-phase在与高紧张的超声的颤动对待的营舍的团结期间被形成。

  • 标签: 镁合金 精化 超声波振动 相位形态学
  • 简介:Inthiswork,transformationbehaviorsandmechanicalpropertiesofcold-rolledshapememoryalloyTi50Ni49Fe1bysevereplasticdeformation(SPD)wereintensivelyinvestigated.Thephasetransformationbehaviors,phaseanalysis,andmicrostructureswerecharacterizedbydifferentialscanningcalorimetry(DSC),X-raydiffraction(XRD),andtransmissionelectronmicroscopy(TEM),respectively.TensiletestingwasperformedtoanalyzetheeffectofSPDonthemechanicalpropertiesandshapememoryofTi50Ni49Fe1alloy.Whenthethicknessreductionisbeyond30%,themartensitictransformationissuppressed.Aftercold-rolling,thealloyismainlycomposedofB2parentphaseswithsomestress-inducedmartensiticB190phases,andhighdensityofdislocationsaregeneratedandthegrainsareobviouslyrefined.Theyieldstressrbsignificantlyraisesfrom618MPaof0%coldrollingto1,338MPaof50%SPD.Shape-memoryeffectincreasesfrom6.5%withoutcoldrollingto8.5%after30%SPD,ascribedtotheinduceddefectsincoldrolling.ThoseresultsindicatethatTi50Ni49Fe1alloyhasimprovedmechanicalpropertiesandpotentialcommercialapplicationsafterSPD.

  • 标签: 形状记忆合金 大塑性变形 机械性能 相变行为 差示扫描量热法 透射电子显微镜
  • 简介:Thesegregationanddiffusionofboronduringheattreatmentswerestudied.Theinfluenceofboroncontents,agingtimeandappliedstressonFeMo2B2formationwasalsostudied.Finally,theeffectsofboroncontentsandFeMo2B2formationonthehightemperaturestrengthwerestudied.Boronatomsweresegregatedtoprioraustenitegrainboundaryduringnormalizingtreatment.Andtheseboronatomswereslowlydiffusedintothegraininteriorduringtemperingandagingat700℃.TheFeMo2B2phasewasonlyformedafter1,000hagingat700℃inalloycontaining196ppmboron.TheformationofFeMo2B2phaseisacceleratedbytheappliedstress.ItwasexpectedthattheformationofFeMo2B2iscloselyrelatedtotheredistributionofboronatoms.Thetensilestrengthsat700℃areincreasedwiththeincreaseofboroncontents.However,theformationofFeMo2B2phaseresultsinlowertensilestrength.

  • 标签: 9Cr-1.5Mo ferritic STEELS PRECIPITATION behavior BORON
  • 简介:AnexperimentalMg97Zn1Y2(molarfraction,%)alloywasproducedbyrollingtheas-castalloy.Themicrostructureofthealloyiscomposedoftheα-Mg(alsomarkedas2H-Mgwithreferencetolong-periodstackingstructureaccordingtohexagonalclosepackedstructure)andlong-periodstacking(LPS)phase.TensiletestsofMg97Zn1Y2alloyincomparisonwithpureMgwereconducted.Thefracturemorphologiesofthetensilespecimenswerecharacterizedandthemicrostructuresnearfracturesurfacewereobserved.TheresultsshowthattherolledMg97Zn1Y2alloyshowsamixedfracturemodeincludingdimplesindicatingaductilefracturepatternandasmallfractionofcleavageplanesindicatingabrittlefracturepattern,whichisdifferentfromthesinglebrittlefractureoftheas-castalloy.Inaddition,theplasticdeformationismainlyfromdislocationsinducedstrainwithsmallstrengtheningeffectduringplasticdeformationintheas-castMg97Zn1Y2alloy,andthestrainhardeningrateissimilartothatoftheas-castpuremagnesium.ThedeformationmechanismofMg97Zn1Y2alloyisdifferentfromthatofthepuremagnesiumaccordingtoametallographicalobservationthatwhethertwinsarefoundornot.ThestrengtheningeffecthardlyexistsintherolledMg97Zn1Y2alloyunderthesamedislocationsinducedstrain,whichisdifferentfromthatoftheas-castalloywithmoderatestrengtheningeffect.

  • 标签: 铸态合金 镁合金 长周期 拉伸断裂 热轧 六角密堆积结构
  • 简介:TheprecipitatingkineticsofNi75Al17Zn8alloywasstudiedatboth873Kand973Kbymicroscopicphase-fieldmodel.Thecalculationresultsshowthattheorder-disordertransformationexperiencesthematrix→lowly-orderedL10phase→L12phaseat973K.AndthenucleationofL12particlesbelongstothespinodaldecompositionmechanism.Astemperatureincreases,orderingsofAlandZnatomsareresisted,butcoarseningofL12particlesispromoted.Thevalueofcoarseningkineticexponentsapproachesto1/2.Inaddition,thediscussionsaboutNi-Alanti-sitedefectandZnsubstitutionsforNisiteandAlsiteexhibitthatthehigherthetemperature,themoredistinctivetheNi-Alanti-sitedefect,butthelesstheZnsubstitution.

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  • 简介:反的尖晶石类型金属氧化物,magnesium-manganese-titanium氧化物(Mg2Mn0.5Ti0.5O4),用coprecipitation/thermal结晶化方法被准备。有这材料的抽取/插入反应被X光检查,交换的浸透能力,pH滴定,和分发系数(Kd)测量调查。Mg2Mn0.5Ti0.5O4的酸处理引起了Mg2+超过81%的抽取,而Mn4+和Ti4+的溶解是不到10%。试验性的结果证明酸处理的样品有交换56mg的一个能力

  • 标签: 萃取反应 插入反应 氧化金属 离子交换机械 尖晶石
  • 简介:为在水样品的踪迹水银的分析的一个新方法被开发,基于用象由冷蒸汽的稳固的阶段提炼之物和决心的修改dithizone的纳米钛二氧化物(TiO2)的preconcentration/separation的联合原子吸附spectrometry(CVAAS)。Dithizone与酒精被溶解并且在缩放nano的TiO2粉末的表面上装载了由激动人心。修改dithizone的nanoparticles上的Hg2+的静态的吸附行为详细被调查。为Hg2+的优秀吸附比率能与15min,和3.5摩尔的5mL的一摆动时间在78的pH范围被获得,这被发现

  • 标签: 分析化学 水银 固体相位萃取 氧化钛纳米颗粒 吸附作用
  • 简介:TheeffectsoftheintroductionofCetoLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloyson1:13phaseformationmechanism,thefirst-ordermagneticphasetransitionstrengtheningcharacteristics,andmagnetocaloricpropertywerestudied,respectively.Theresultsshowthattheformationmechanismsof1:13andLaFeSiphasesinLa_(1-x)Ce_xFe_(11.5)Si_(1.5)alloysarethesameasthoseofCe_2Fe_(17)andCeFe_2phasesinCe–Febinarysystem,respectively.ThesubstitutionofCein1:13phasewhichislimitedcanmakethefirst-ordermagneticphasetransitioncharacteristicsstrengthen,whichcanmakethermalandmagnetichysteresisincrease,thetemperatureintervaloftemperatureinducedphasetransitiondecrease,andthecriticalmagneticfieldoffield-inducedmagneticphasetransition(HC)increase,respectively.Owingtothelatticeshrinkof1:13phasewiththeincreaseinCecontent,theCurietemperatures(TC)showalineardecrease.Themaximumchangeinmagneticentropygraduallyincreasesduetothedecreaseintemperatureintervaloftemperature-inducedphasetransition,buttherelativecoolingcapacitiesareallabout80Jákg-1atmagneticfieldof2T.

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  • 简介:Basedonclustervariationmethod(CVM)andnaturaliterationmethod(NIM),order-disorderphasetransitionintheintercalationcompoundsM1/2TiS2issimulatedbycomputer.Thefavorableconditions,underwhich3a0×a0superstructureisformed,aregiven,andtheresultsareingoodagreementwiththeexperimentsandtheoreticalcalculations.TherelationshipbetweencriticaltemperatureandM-ion-vacancyinteractionparameterislinear.

  • 标签: 计算机模拟 群集变分法 迭代法 插层化合物 有序无序相转换 铁钛硫化合物
  • 简介:TheeffectsofheattreatmentsonthephasetransformationbehaviorofTi49Ni49.5Fe1V0.5andTi48Ni48.5Fe1V2.5alloyswereinvestigated.TheresultsindicatethatthealloyssubjectedtodifferentheattreatmentshaveB2structureatroomtemperature.AllthespecimensexhibitatwostageB2→R→B190martensitictransformationoncooling,butaB190→B2one-stagereversemartensitictransformationonheatingexceptagedA1alloy,whichundergoesanabnormaltwo-stagetransformationuponheating.ThephasetransformationtemperaturesareaffectedbyheattreatmentsandVcontent,whichcanbeattributedtothevariationofthesecond-phaseparticlescontentinthematrix.

  • 标签: 相变行为 热处理 合金 马氏体相变 B2结构 相变温度