简介：Inthisstudy,titaniumdioxidesupportedbymulti-walledcarbonnanotubes(MWCNTs/TiO2)andCr-dopedTiO2supportedbyMWCNTs(MWNTs/Cr-TiO2)weresynthesizedbythesol-gelmethod.Thepreparedsampleswerecharacterizedbytransmissionelectronmicroscopy,X-rayphotoelectronspectroscopy,X-raydiffraction,theBrunauerEmmett-Telleranalysis,andtheRamanspectroscopy.TheoxidationandefficiencyforremovalofSO2inasimulatedfluegaswereinvestigatedexperimentallyinafixed-bedreactor.The15%MWCNTs/Cr-Ti02sampledisplayedexcellentadsorptionproperties,andaSO2removalrateequatingto30.4151mg/gfromthesimulatedfluegascontaining2300μg/gofSO2,8%of02,and5%ofH20wasachievedunderoptimalconditionscoveringatemperatureof333.15K,andaspacevelocityof1275h^-1.TheadsorptionprocesswasenhancedbecauseCrdopingmodifiedtheporestructureandinhibitedthegraingrowthofTiO2.Inaddition,theFreundlichandLangmuirmodelsrevealedthatSO2wasmainlyadsorbedthroughchemicaladsorptiononthesamplesurfaces,andthethermodynamicmodelanalysisindicatedthattheadsorptionwasaspontaneous,exothermic,andentropy-reducingprocess.TheadsorptionkineticsofSO2canbedescribedbythepseudosecond-orderkineticandtheBanghamdynamicsmodels.Thepossiblereactionmechanisminvolvedindesulfurizationprocesswasalsoproposed.

简介：南海东部油田勘探过程中,部分储集层发现非烃CO2气层,由于目前尚未形成CO2气层商业开发,快速识别CO2气层对于勘探开发决策有着非常重要的作用。受CO2物理、化学性质和钻井液等因素影响,录井过程中CO2数值较低,甚至出现无值的现象,仅使用录井手段,对CO2的识别存在较大的困难。通过分析有取样证实的6口井CO2储集层资料,提出了综合利用录井和随钻测井资料快速识别CO2气层的新方法,而且现场应用中解决了南海东部油田CO2气层评价难的问题,取得了非常好的效果。

简介：AninnovativeapproachtoH2Scapturehasbeendevelopedusingseveralmetal-basedionicliquids([Bmim]Cl·CuCl2,[Bmim]Cl·FeCl3,[Bmim]Cl·ZnCl2,[Bmim]Br·CuCl2,and[Bmim]Br·FeCl3)immobilizedonthesol-gelderivedsilica,whichissuperiortopurelyviscousionicliquidwithacruciallimitofhightemperature,lowmasstransferrate,andmassloss.TheadsorbentswerecharacterizedbytheFouriertransforminfraredspectrometer,transmissionelectronmicroscope,N2adsorption/desorption,X-rayphotoelectronspectroscopy,andthermalanalysistechniques.TheeffectsofthemetalandhalogeninIL,theloadingamountofIL,andtheadsorptiontemperaturewerestudiedbydynamicadsorptionexperimentsatagasflowrateof100mL/min.TheH2Sadsorptionresultshaveshowedthattheoptimaladsorbentandadsorptiontemperatureare5%[Bmim]Cl·CuCl2/silicageland20-50℃,respectively.H2Scanbecapturedandoxidizedtoelementalsulfur,and[Bmim]Cl·CuCl2/silicagelcanbereadilyregeneratedbyair.TheexcellentefficiencyofH2Sremovalmaybeattributedtotheformationofnano-scaledandhigh-concentration[Bmim]Cl·CuCl2confinedinsilicagel,indicatingthattheimmobilizationof[Bmim]Cl·CuCl2onthesol-gelderivedsilicacanbeusedforH2Sremovalpromisingly.

简介：河流相储集层横向变化快往往导致水平井砂岩钻遇率较低而降低水平井的产能优势,因此需要利用地质导向技术并结合地震资料对水平井实施过程中钻遇砂体发育模式进行解析。对于河流相储集层而言,不同成因类型在随钻过程中所表现出砂泥剖面的测井曲线特征存在差异:“砂体拼接”型模式钻遇砂泥岩界面往往表现为砂泥“突变”的电性特征;“微构造”型模式钻遇砂泥岩界面表现为“渐变”的电性特征;“浅着陆”型模式钻遇泥岩界面可以表现出多种电性特征。通过不同的电性特征可以进一步识别河流相储集层的边界面发育模式及储集层内部砂体拼接状况。基于对地质模式的识别,采用相应的随钻调整策略,可有效提高河流相储集层水平段砂体钻遇率。