简介:Thecurrentapplicablerelease&dispersionmodelsarereviewed.AtypicalmodelisdevelopedonthebasisofLPGstorageconditionsinChinaandtheauthors'research.ThestudyisfocusedontherelationshipbetweenLPGcompositionandreleaserate,andontheinfluenceofbuildingsorstructureslocatedinthesurroundingareaonthedispersionofgasplume.Theestablishedmodeliscomparedwithexistingmodelsbytheuseofpublishedfieldtestdata.
简介:Inordertofurtherreducethesulfurcontentingasoline,anewdesulfurizationprocesswasproposedbyusingcatalyticoxidationandextractionrealizedinanelectrochemicalfluidizedreactor.Thefluidizedlayerofloadedcatalystparticlesconsistedofleaddioxide(PbO2)supportedonactivatedcarbonparticles(PbO2/C)andtheelectrolytewasaqueousNaOHsolution.ThePbO2/Cparticleanodescouldremarkablyacceleratetheelectrochemicalreactionrateandpromotetheelectrochemicalcatalysisofsulfurcompounds.Thesulfurcompoundswereatfirstoxidizedtosulfonesorsulfoxides,whichwerethenremovedafterextraction.Theexperimentalresultsindicatedthattheoptimaldesulfurizationconditionswereasfollows:Thecellvoltagewas3.2V,theconcentrationofhydroxylionsinelectrolytewas0.12mol/L,andthefeedratewas300mL/min.Undertheseconditionstheconcentrationofsulfuringasolinewasreducedfrom310ppmto70ppm.Basedontheseexperimentalresults,amechanismofindirectelectrochemicallycatalyticoxidationwasproposed.
简介:ThispaperreportstheinfluencesofheattransfersurfacepropertiesontheformationofCaSO4foulingdepositionduringflowboilingheattransfer.Thesurfacesofseveraltestheatershavebeentreatedbysurfacemodificationtechniques.suchasdynamicmixingionbeamimplantationanddynamicmixingmagnetronsputteringtoreducesurfaceenergy.Foulingrunswiththeseheaterswerecarriedoutatdifferentheatfluxes,flowvelocitiesandsaltconcentrations.TheresultsshowthatheattransfersurfaceswithlowsurfaceenergyexperiencedsignificantlyareducedformationofCaSO4deposit.
简介:Thespraybehaviorsofthecombinedtrapezoidspraytray(CTST)haveasignificanteffectonthegas-liquidinterface.Inthispaper,thesprayprocessofCTSTinacolumn,570mmindiameter,wasexperimentallyinvestigatedbyusingahigh-speedcamera,andatheoreticalmodeloftheaveragedropletsizewasestablishedaccordingtotheunstablewavetheory.Theresultsdemonstratedthatgasvelocitypassingthroughtheholeisthekeyfactoraffectingthesprayangle,whichincreasesgraduallywithanincreaseinthegasvelocity.Whenthegasvelocityexceeds7.5m/s,thesprayanglebecomesstableataround55°.Theaverageflowvelocityoftheliquidsheetatthespray-holeincreasessignificantlywithanincreaseinthegasvelocity,anddecreasesslightlywithanincreaseintheliquidflowrate;moreover,itincreasesfromthebottomofsprayholeupwardtothetop.ThedensityofliquiddropsdistributioninthesprayareacanbedescribedbytheRosinRammlerfunction.Inaddition,theliquiddropsaremainlyconcentratedintheareaofsprayanglerangingfrom20°to40°,andtheygraduallybecomeuniformwiththeincreaseinthegasvelocityandtheliquidflowrate.Theaverageliquiddropsizedeceaseswithanincreaseinthegasvelocity,andincreasesslightlywithanincreasingliquidflowrate.Inthenormalworkingrange,theaverageliquiddropsizeisabout1.0mmto2.5mmindiameter.
简介:ATi/Sicomplexzeolitehasbeenprepared.X-raydiffractionandinfraredspectrometrystudyhasshownthattwostructures,namelytheZSM-5andMCM-41,existinthesample.BETtestshaverevealedthatthecomplexzeolitecontainsregularmesoporesof2.6nm.UltravioletspectrometryanalysishasshownthattheTispeciesexistinthezeoliteskeletonintheformoftetra-coordinatevalence.TheTi/Sicomplexzeolite(TS-1/Ti-MCM-41)hasapparentlyimprovedcatalyticactivitywithrespecttothemacromolecularorganiccompoundoxidationascomparedtoindividualcomponentsofeitherTiorSicontainingzeolites(TS-1andTi-MCM-41).
简介:Sprayauto-ignitionexperimentswerecarriedoutinaconstantvolumecombustionchamberforsomepurealkanes(n-paraffinswithdifferentchainlength,cyclohexane,n-butylcyclohexane,andisooctane)andblendsofn-decanewithStandardBlendedFuel(isooctane/n-heptane)andproductgasoline.Testresultsshowedthatthereactionactivityofn-paraffinswasrelativelyhigh.Meanwhile,theauto-ignitioncharacteristicsdifferedsignificantlywiththemolecularstructuresofalkanes.Addingdifferentvolumefractionsofn-decanetoStandardBlendedFuelandproductgasolinecouldimprovethefuelreactionactivityatvaryingdegree.Finally,functionalgroupseffectswereusedtosimulatetherelationshipbetweenthemoleculartopologyandtheauto-ignitionquality.
简介:TheVenturi-roddecktrayisatypeofdualflowtraysusedinfluegasdesulfurization(FGD)process.Inthispaper,thehydrodynamiccharacteristicsoftheVenturi-roddecktraywerestudiedintheexperimentsandcomparedwiththeconventionalsievetray.Resultsshowedtheturndownratioofthistraywasintherangeof2.71-3.77,whichwasby9%higherthanthesievetray.Besides,thepressuredropofthistraywasbymorethan50%lowerthanthesievetray.Basedontheexperimentaldata,thecorrelationfunctionsforthepressuredropandthefrothheight,respectively,wereobtained.TheindustrialscaleuppracticeofthistrayinFGDprocesswasdescribedwiththeefficiencyofthistraydemonstrated.
简介: 1OverviewonChina'sEnergyDevelopment OverthepasttwentyyearsChinahasmadeastonishingachievementsintheenergydomainandthetotaloutputofcoal,electricityandpetroleumrankedrespectivelythefirst,secondandfifthplaceintheworld.……
简介:Onthebasisofformulatingthe9-lumpkineticmodelforgasolinecatalyticupgradingandthe12-lumpkineticmodelforheavyoilFCC,thispaperisaimedatdevelopmentofacombinedkineticmodelforatypicalFDFCCprocessafteranalyzingthecoupledrelationshipandcombinationofthesetwomodels.Themodelisalsoverifiedbyusingcommercialdata,theresultsofwhichshowedthatthemodelcanbetterpredicttheproductyieldsandtheirquality,withtherelativeerrorsbetweenthemainproductsoftheunitandcommercialdatabeinglessthanfivepercent.Furthermore,thecombinedmodelisusedtopredictandoptimizetheoperatingconditionsforgasolineriserandheavyoilriserinFDFCC.SothispapercanoffersomeguidancefortheprocessingofFDFCCandisinstructivetomodelresearchanddevelopmentofsuchmulti-reactorprocessandcombinedprocess.
简介:ZnOnanoparticleswithanaveragesizeof125nmwerepreparedviahomogeneousprecipitationmethodandwerecharacterizedbySEM.Theproductsweresurface-modifiedbythesurfactantSDS.Surface-modifiednanoparticleswereaddedatamassratioof1.0%,2.0%,3.0%,and4.0%,respectively,inbaseoilandtheirfrictionandwearbehaviorswereevaluatedonaMRS-10Dtypefour-ballweartester.Afterfour-ballweartests,themorphologyoftherubbingsurfaceswasevaluatedwithmetallographicmicroscope.ItwasrevealedthatthemodifiednanoZnOhadexcellentbehaviorforimprovinganti-wearpropertyandfrictioncoefficient,whichcouldgreatlyreducethefrictionofmachineparts.
简介:Inthisarticle,theFCCdieselfuelischemicallytreatedwithGZreagent.Theexistentgum,insolublesafteroxidation,andiodinemunberaregreatlyreducedafterchermicaltreatment.Thismethodhasagoodeffectandissimple.Thismethodischaracterizedbyhighrecoveryrateoffuel(>99.7?andlowcost.Thepropertyofthemixtureofchemicallytreateddieselfuelwithstraight-rundieselfuelcanmeettherequirementsofnationalstandardGB252-2000.Thecolorandoxidationstabilityofthemixedfuelafterhavingbeenstoredforthreemonthswerestilllowerthanthevaluesspecifiedinthenationalstandard.
简介:Thepolypropylene(PP)nanocompositesfilledwithpretreatedhalloysitenanotubes(HNTs)werepreparedbythemelt-blendingmethod.Beforefilling,theas-receivedHNTspowderwasatfirstpurifiedandthenmodified.ThecharacterizationtestsshowedthatthepurifiedHNTshadlessimpurityandmoreuniformporesizedistributionandthesurfacehydrophobicityofthemodifiedHNTswasobviouslyimproved.ThemechanicalandtribologicalpropertiesofthePP/HNTsnanocompositeswereextensivelyinvestigated.Theresultsshowedthatthetensile,bendingandnotchedimpactstrengthofthePP/HNTsnanocompositeswassomewhatimproved,butthewearresistanceofthePP/HNTsnanocompositeswasobviouslyenhanced.
简介:Crudeoilisthemostimportantbasicenergyintheworldnowadaysandiscloselyconnectedwiththedevelopmentofnationaleconomy,consolidationofnationaldefenseandthelivingstandardofthepeople.Changesincrudepricecanhaveadecisiveimpactonanation'spoliticalandeconomicsituation.Hencethegovernmentofeverycountrysticksgreatimportancetocontrolovercrudeoilresourcesandadjustmentofcrudepricetoassurethestabilizationofitsdomesticcrudeoilmarket.
简介:Oxidativedesulfurization(ODS)ofAzericrudeoilwasstudiedundertheelectricfield.Bymeansoforthogonalexperiments,theoptimumconditionsfordesulfurizationofcrudeoilwereidentified,whiletheeffectofoxidativedesulfurizationundertheelectricfieldwascomparedwiththatofthesingleoxidativedesulfurizationmethod.Thetestresultsshowedthatthedesulfurizationreactiontakingplaceundertheelectricfieldwouldbebetterthanthetraditionalmethod.Thedesulfurizationrateofcrudeoilcouldreachupto77.06%at115℃atadistilledwateramountof10m%,adesulfurizerdosageof200μg/g,andademulsifierdosageof50μg/g.
简介:二新奇的灰更少添加剂-benzothiazole衍生物包含硼和氯,OBC和BBC,被综合。在在油菜籽的添加剂上油的不同集体比率(RO)的OBC和BBC的tribological表演在一台四球的机器上被检验。油样品润滑的更低的钢球的穿的表面借助于扫描电子显微镜学(SEM)被分析。测试结果显示出那OBC,BBC在底有好溶解度上油,并且能有效地增加基础油的带负担的能力。包含1.5m%BBC的油样品的最大的非抓住负担是1117N,它2.3倍于基础油的。OBC和BBC能改进禁止性能和基础油的热稳定性的反穿和腐蚀,谁的起始的分解温度在350°C上面。然而,在不同集中的OBC和BBC能增加基础油的磨擦系数。油润滑的钢球的SEM形态学取样包含1.5m%添加剂似乎比形成的基础油,和疤的更一致、光滑是很浅的。
简介:根据过程特征和FDFCC技术的反应机制,它的二个反应分系统,为重油起床人反应堆的,其它为汽油起床人反应堆,分别地被学习。相应地,12块为重油FCC的运动模型和9块为汽油的运动模型催化升级被介绍。把工作基于这,在涉及全面反应系统的反应分系统和那些的feeds和产品的块的数学关联详细被分析。然后,为FDFCC的一个联合运动模型,基于从一个商业单位恢复的数据,被提出。运动常数为FDFCC的联合模型表达的反应表演根据催化裂开的反应机制。模型计算的值接近了在商业规模获得的数据。模型是安逸的在实践被使用并且能也为FDFCC为关于运动模型的进一步的研究提供一些理论地基。
简介:到在不同反应条件下面的石蜡(MTO)的甲醇的变换试验性地在不同催化剂上被调查,并且比较在SAPO-34andGOR-MLC催化剂之间被做。反应条件的优化被探索了。到在在不同反应温度下面的这些催化剂上的石蜡的甲醇的变换是试验性地,studied.Ina修理了床微反应堆,温度的影响被发现是石蜡产出的主要factors.Forboth催化剂之一当水被加到460-480degC的methanolfeed.A温度范围时,显著地被增加与适当催化剂活动和C_2-C_3石蜡对甲醇变换显得是最佳范围合适产量。一些另外的烃面对SAPO-34催化剂出现在MTO反应期间,当当GOR-MLC催化剂被使用时,很多ofdimethylether被形成时。在MTO反应期间,theGOR-MLC催化剂被发现让更快的催化剂释放与SAPO-34catalyst相比评价。
简介:Aninnovativeideawasproposedtopreparetheoverbasednano-sizedcalciumcarbonate-calciumpetroleumsulfonatein-situtheHIGEEreactor.ThetestsamplepreparedbythistechnologycouldmeettherequirementoftheindustrystandardSH0042-91forthefirst-gradeproductonaparwithsimilaroverseasproduct.Thetestresultsobtaineduponobservationundermicroscopeafterfreezingetchingofspecimenrevealedthatthecrystalsizeofcolloidalcalciumsulfonatewasintherangeof10-30nmwithanaveragesizeof20nm.Thesizeofthedetergentadditivewasuniformwithgoodtransmittanceandfluidity.TheHIGEEtechnologypossessesfivespecificfeaturesasshownbelow:Firstly,thecarbonationreactioniscompletedinonestepwiththereactiontimereducedbymorethan50%ascomparedtotraditionalbatchreactorprocessalongwithenhancedreactionefficiency,goodoperabilityoftheprocessandstabilizedproductquality.Secondly,ammoniaemittedfromthereactionisusedastheco-promoterwithouttheneedforaddingammoniaandwateraspromoterstosimplifythepromotersystemalongwitheffectiveandstrongcouplingofreactions.Thirdly,theutilizationrateofCa(OH)2andCO2isincreasedby15%and30%,respectively,withproductyieldincreasedby15%,andcalciumresiduedecreasedby65%.Fourthly,theHIGEEtechnologyisenvironmentalbenignbecauseofgasolineisusedinthistechnologyinsteadoftoxictolueneandxylene.Fifthly,thedimensionofHIGEEreactorisreducedbyabovetwo-thirds.ThesuccessindevelopmentofthisnewtechnologywilloffernewideasandtechnologyplatformforthesynthesisofmetaldetergentadditivetolubricatingoilsinChina.