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500 个结果
  • 简介:ThephaseandmorphologytransformationduringthehydrothermaltreatingprocessofY2O3wasevaluatedwithX-raydiffcrcnce(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),particlesizeandspecificsurfaceareadetermination.TheresultsshowedthatthecubicY2O3didnottransferintohexagonalY(OH)3inpurewater.Therefore,purehexagonalY(OH)3withnanotubeandmicrorodmorphologieswereobtainedbyhydrothermaltreatingY2O3at150℃for12hin15mlof2mol/LNaOHsolutionwithandwith-outPVAorPEGItwassuggestedthatthecharacteristicpreferentialgrowthofY(OH)3wasattributedtothestructureanisotropyofhexahedronY(OH)3.TheadditionofPVAorPEGcouldpromotetheformingprocessofnanotubesbyselectiveadsorptionondifferentcrystalplanes,whichalteredthegrowthratealongdifferentdirectionsandresultedinthediffusionlimitofconstructingionsinthecentertopofrods.Finally,Y(OH)3:EuandY2O3:Eunanotubeswerealsosynthesizedbyusingthismethod,andtheirphotoluminescencepropertieswereevaluated.

  • 标签: HYDROTHERMAL synthesis Y(OH)3 Y(OH)3:Eu Y2O3:Eu NANOTUBE
  • 简介:Thesolutionreactionmechanisms,composition,donoratoms,propertiesofcoordinatelinkandstabilityofthecomplexesonthesystemsofadrenalinewithNa3+,Gd3+andTm3+havebeenstudiedbypH-potentiometrictitrationandelectronicspectroscopy.Adrenalineperturbsthef-felectronictransitionofNd3+andTm3+sothattheabsorptionspectraoftheircomplexesareshiftedtowardlongerwavelengths.Theabsorptionspectraofthecomplexesformedbythethreef-blockelementionswithadrenalineareshiftedtowardshorterwavelengthswiththeincreaseofPHinΔγ=350~650nm

  • 标签: ADRENALINE NEODYMIUM GADOLINIUM THULIUM Solution EQUILIBRIUM
  • 简介:数字电视是一种产业.尽管中国数字电视经历了十多年的发展,已经成为世界数字电视大国,但不是数字电视强国.究其原因就是中国数字电视还没有实现产业化.数字电视的经营能力和产业能力薄弱.本文梳理了中国数字电视产业现状及其存在问题,以期引起电视业界和相关产业主管部门注意,为中国数字电视产业的发展提供决策依据.

  • 标签: 数字电视 产业
  • 简介:YbAl3(BO3)4crystalofgoodopticalqualitywasgrownbythefluxmethod.ThestructureofYbAl3(BO3)4crystalwasdeterminedbysingle-crystalX-raydiffraction.TheexperimentshowsthatYbAl3(BO3)4belongstothedoubleborateswithatrigonalstructure.ThespacegroupisR32anditsunitcellconstantsweremeasuredtobea=0.92965nm,c=0.72129nm,V=0.53673nm3,Z=3.Thetransmittancespectraweremeasured.Thecut-offofYbAl3(BO3)4crystalis216nm,andtherearetwoabsorptionpeakslocatedat940and975nmfrom190nmto2600nm.ThethermalpropertiesofYbAl3(BO3)4crystalwerestudiedforthefirsttime.Theaveragethermalexpansioncoefficientsweredeterminedtobe2×10-6/℃,9.5×10-6/℃alonga-andc-direction.ThespecificheatofYbAl3(BO3)4crystalwasmeasuredtobe0.6695J·(g·℃)-1atroomtemperature.AllresultsindicatethattheYbAl3(BO3)4crystalisanexcellentstoichioimetriclasermaterial.

  • 标签: YbAl3(BO3)4 CRYSTAL TRANSMITTANCE SPECTRA thermal properties
  • 简介:通过对攀钢冷轧厂酸洗3号纠偏装置跑偏原因的分析和对纠偏角度的计算,提出了可行的改进方案,完全消除了跑偏现象,取得了圆满成功。

  • 标签: 纠偏 跑偏 机构
  • 简介:Er3+-Tm3+-Yb3+tri-dopedBaMoO4phosphorsweresynthesizedbyco-precipitationtechniqueandcharacterizedbyX-raydiffractionanalysis,absorptionstudyandfieldemissionscanningelectronmicroscopyanalysis.Upconversionaswellasdownconversionluminescencestudieswereperformedbyusingnearinfrared(980nm)andultraviolet(380nm)excitations.Energyleveldiagram,pumppowerdependenceandcolourcoordinatestudywereutilizedtodescribethemulticolorupconversionemissionproperties.Undersingle980nmdiodelaserexcitationthedualmodesensingbehaviourisrealizedviaStarksublevelsandthermallycoupledenergylevelsoftheTm3+andEr3+ionsinthepreparedtri-dopedphosphors.AcomparativefluorescenceintensityratioanalysisforintegratedemissionintensitiesarisingfromtheStarksublevels{1G4(a)and1G4(b)}andthermallycoupledenergylevels{2H11/2and4S3/2}oftheTm3+andEr3+ions,respectivelywascarriedoutinthepreparedtri-dopedBaMoO4phosphors.ThemaximumsensitivityforthermallycoupledenergylevelsoftheEr3+andStarksublevelsoftheTm3+ionwasreported.Thedevelopedphosphorscouldbeusefulinthedisplaydevicesandopticalthermometricapplications.

  • 标签:
  • 简介:本文采用高温团相反应合成TCaTiO3∶Pr3+红色发光材料、报道了Pr3+激活的CaTiO3的光谱特征及长余辉特性,并与CaS∶Eu的光谱特性及长余辉进行了比较。CaTiO3∶Pr3+将是一种具有广泛用途的新材料

  • 标签: CaTiO3∶Pr3+ 合成 发光特性 长余辉
  • 简介:介绍了武山铜矿中段运输系统原3m3底侧卸矿车的设计特点。结合生产实际状况,对3m3底侧卸矿车在运行过程中出现的问题进行了分析,总结产生故障的原因,针对性的提出改进措施。现场使用表明,通过改进后,取得了良好效果,满足了矿山生产的需要。

  • 标签: 底侧卸矿车 轮轴 卸载轮 车箱 改进措施
  • 简介:Eu3+activatedSr1–xEuxZrO3(x=0.01–0.04)phosphorwithperovskitestructurewassuccessfullysynthesizedbyusingcombustionmethod.Thestructure,morphologyandopticalpropertiesofthematerialwerecharacterizedbyX-raydiffraction,scanningelectronmicroscopyandfluorescencespectrometry.TheXRDresultsindicatedthatcrystalsofSrZrO3:Eu3+belongstotetragonalperovskitesystem.ThephosphorcouldbeeffectivelyexcitedbyUVlightandtheemissionspectraresultsindicatedthatreddish-orangeluminescenceofSrZrO3:Eu3+duetomagneticdipoletransition5D0→7F1at593nmwasdominant.Thus,thepreparedphosphorshowedremarkableluminescentpropertieswhichfindapplicationsinfieldemissiondisplay(FED)andplasmadisplaypanel(PDP)devices.

  • 标签: 钙钛矿结构 铕激活 荧光粉 光学特性 合成 扫描电子显微镜
  • 简介:Calciumtitanatedopedwithpraseodymiumwaspreparedthroughsolidstatereactionanditexhibitedintenseredemissionat612nm.Phosphorswerecharacterizedforphotoluminescence,thermo-luminescenceandafterglowemissions.Studyofeffectsofrareearthsonphotoluminescenceaswellasafterglowintensitywasreported.Presenceofgadoliniumenhancedluminescence.Presenceofsomemonovalentionsenhancedbothafterglowandphotoluminescenceemission.Thermo-luminescenceglowcurveswereanalyzedand...

  • 标签: perovskites 钙 titanates 红晚霞 稀土元素
  • 简介:在石灰窑大修过程中对石灰窑存在的薄弱环节采取了一些改进措施,建造新型石灰窑可以从根本上扭转公司石灰生产的被动局面。

  • 标签: 石灰窑 大修 窑体 耐火材料
  • 简介:Er~(3+)andLa~(3+)codopedY_2O_3nanocrystallinepowdersweresynthesizedbygelcombustionmethodandcharacterizedwiththermalanalysis,X-raydiffraction(XRD),transmissionelectronmicroscopy(TEM),high-resolutionTEM(HRTEM)techniquesandfluorescencespectroscopy.Afterbeingcalcinedat1200oC,the(Y_(1–x)La_x)_2O_3:Er~(3+)powderswereconfirmedtobecubicY_2O_3phasewiththecrystallinegrainsizeintherangeof20–40nm.TheEr~(3+)emissionat1.53μmfromthe~4I_(13/2)→~4I_(15/2)transitionwasobserved,whichwasfoundtobeenhancedbyintroducingLa~(3+)ions.SuchenhancementcouldbeattributedtotheadjustmentofEr~(3+)ions'localenvironmentbythecodopingofLa~(3+)ions,leadingtotheincreasedgroundstateabsorptioncrosssectionofEr~(3+)ions.

  • 标签: POWDERS IONS crystalline CALCINED attributed cubic
  • 简介:Duetotheremarkablemagnetoresistance(MR)effectonperovskite-typemanganite,magnetoelectronicsandspintronicshavebecomeattractivesubjectsofexperimentalandtheoreticalinvestigationsfortheapplicationpurpose.(La0.9Nd0.1)2/3Ca1/3Mn1-xFexO3(x=0,x=0.05)werepreparedsuccessfullybysol-gelmethod.Thestructure,magneticproperties,andtransportpropertiesofthecompoundswereinvestigated.Themagnetoresistanceeffectdependsonthecompositionandthetemperature.XRDpatternsshowthatthecompoundisasinglephasepolycrystalwithpseudocubicstructure.Alargenegativeisotropicmagnetoresistanceeffectinthesampleswereobservedatlowtemperatureregion.ThemaximumMRofthesampleswas77%and97%,respectively.Itwasmostlikelyduetothescatteringorthetunnelingtransportofspin-polarizedcarriersinlatticeunderstrongmagneticfield.

  • 标签: SOL-GEL method MAGNETORESISTANCE effect PEROVSKITE pseudocubic
  • 简介:InordertosensitizetheluminescenceofEu3+ionsinheavymetalglass,zincleadborateglasssamplescontainingvariousconcentrationsofEu3+andTb3+ionswerepreparedtostudytheTb3+toEu3+non-radiativeenergytransferphenomena.EnergylevelstructuresofTb3+andEu3+ionswereplottedtoshowtheexcitationandenergytransferroutes.EfficientenergytransferfromTb3+toEu3+wasobservedandstudiedqualitativelyintermsofdopingconcentrations.Thesensitizationturnedouttobelesseffectivethanexpected.FurtherstudiestocharacterizetheoxidationofTb3+intotetravalentstateandtoexaminethemechanismofenergytransferareproposed.

  • 标签: energy transfer ZINC LEAD BORATE glass
  • 简介:本文针对酒钢450m~3高炉矿种种类多、原料单程序无法设置、手动操作控制中心抽焦等现状,提出了多矿种自动控制布料研究应用的攻关课题,并对实施的内容、步骤以及取得的效果进行了介绍。项目的实施,实现了高炉控制系统具备吃多矿杂种、中心抽焦自动配料及布料等功能,降低了工作劳动强度。

  • 标签: 多矿种布料 中心抽焦 自动控制 程序优化
  • 简介:随着闪速炉的投料量和精矿中杂质含量的逐步升高,进入余热锅炉和后续排烟系统的烟尘量也随之大幅增加,部分在余热锅炉未能硫酸盐化的烟尘,由于其粘附性较强、不易清除,在余热锅炉、鹅颈烟道、沉降室以及电收尘内大量粘结,为了确保余热锅炉和后续排烟系统的正常运转和排烟畅通,通过大量研究论证,对炉况、控制参数、物料性质、系统漏风、EF烟气等方面的控制,成功有效降低了SO,发生率。

  • 标签: 余热锅炉 排烟系统 SO3发生率 电收尘 烟尘