简介:TiO2nanoparticleswithdifferentphasesarepreparedbyhydrolysisoftitaniumtetrabutoxideinthepresenceofHCl.ThecompositionandmicrostructureoftheresultingsamplesarestudiedbyXRDandTEM.TheseresultsshowthattherangeofparticlesizeofTiO2isfrom20to30nm.ThemechanismofTiO2photocatalysisreactionhasbeendiscussedextensively.PhotocatalyticactivitiesofnanometerTiO2arealsoevaluatedbydegradationofthecrystalvioletsolution.ExperimentalresultsindicatethatthesynergisticactionofH2O2andultrasonicwavegreatlyenhancesphoto-catalyticreactionofTiO2.
简介:玻璃纤维由于它的介电常数高和损耗大,通常只作为普通印制电路基板的增强材料。本文介绍了可用于微波电路基板的低介性能(εr2.35,Dk0.00007)的新型增强纤维-环烯烃共聚物纤维及其应用。通过将环烯烃共聚物纤维与玻璃纤维结合在独特的混合布中制成εr3.08,Dk0.013印制电路板基板;将混合布中环烯烃共聚物纤维熔化构成树脂的一种成分,制成εr3.25,Dk0.0013印制电路板基材;通过将含环烯烃共聚物纤维的混织布涂上独特的低介电树脂制成εr2.8,Dk0.0009印制电路板基材的试验,表明环烯烃共聚物纤维是适应当今电子技术发展要求,制作优异介电性能印制电路基板的新型增强材料,用环烯烃共聚物纤维可制出比目前最好的低介电基材质量更轻、介电性能、机械性能更有竞争力的基材。
简介:Iron(Ⅲ)-dopednanostructureTiO2-coatedSiO2(TiO2/SiO2)particleswerepreparedusingthelayer-by-layeras-semblytechniqueandtheirphotocatalyticpropertywasstudied.TiO2colloidsweresynthesizedemployingthesol-gelmethodwithTiCl4asaprecursor.ThesampleswerecharacterizedbyFouriertransforminfraredspectroscopy(FTIR),SEM,EDS,XPS,andXRD.TheexperimentalresultsshowthatTiO2nanopowdersonthesurfaceofSiO2particlesarewelldistributed,theamountofTiO2isincreasedwiththeaddingofcoatinglayers,thepureanatase-TiO2coatinglayersaresynthesizedat500°C,andthephotocatalyticactivityofFe3+-dopedTiO2/SiO2ishigherthanthatofundopedTiO2/SiO2.
简介:Nb-24Ti-18Si-2Al-2Hf-4CrandNb-24Ti-18Si-2Al-2Hf-8Cralloyswerepreparedbyarcmeltinginawater-cooledcrucibleunderargonatmosphere.Microstructuralcharacteristicsandoxidationresistanceofthealloysat1250℃wereinvestigated.Theresultsshowthat,whentheCrcontentis4at%,themicrostructuresconsistof(Nb,Ti)_(ss)andNb_5Si_3;asCrcontentincreasesto8at%,C14LavesphaseCr_2Nbisformed.Theisothermaloxidationtestsshowthattheoxidationkineticsofthetwoalloysfollowsimilarfeatures.Theweightgainsofthetwoalloysafteroxidationat1250℃for100hare235.61and198.50mg·cm~(-2),respectively.Duringoxidation,SiO_2,TiO_2,Nb_2O_5andCrNbO_4areformedatfirst.Then,Ti_2Nb_(10)O_(29)isformedafteroxidationfor20minandbeginstochangeintoTiNb_2O_7astheoxidationproceeds.SiO_2isformedassolidstateatfirstbutlaterevolvesintoglassystatetoimprovethecohesionofthescale.Afteroxidationfor100h,oxidationproductsconsistofSiO_2,TiNb_2O_7,Nb_2O_5andCrNbO_4.
简介:ElectrocrystallizationMechanismofTungsteninMoltenKF-B_2O_3-K_2WO_4WenZhenhuanandLiGuoxun文振环,李国勋(GeneralResearchInstiiuteforNo...