简介:Nb-24Ti-18Si-2Al-2Hf-4CrandNb-24Ti-18Si-2Al-2Hf-8Cralloyswerepreparedbyarcmeltinginawater-cooledcrucibleunderargonatmosphere.Microstructuralcharacteristicsandoxidationresistanceofthealloysat1250℃wereinvestigated.Theresultsshowthat,whentheCrcontentis4at%,themicrostructuresconsistof(Nb,Ti)_(ss)andNb_5Si_3;asCrcontentincreasesto8at%,C14LavesphaseCr_2Nbisformed.Theisothermaloxidationtestsshowthattheoxidationkineticsofthetwoalloysfollowsimilarfeatures.Theweightgainsofthetwoalloysafteroxidationat1250℃for100hare235.61and198.50mg·cm~(-2),respectively.Duringoxidation,SiO_2,TiO_2,Nb_2O_5andCrNbO_4areformedatfirst.Then,Ti_2Nb_(10)O_(29)isformedafteroxidationfor20minandbeginstochangeintoTiNb_2O_7astheoxidationproceeds.SiO_2isformedassolidstateatfirstbutlaterevolvesintoglassystatetoimprovethecohesionofthescale.Afteroxidationfor100h,oxidationproductsconsistofSiO_2,TiNb_2O_7,Nb_2O_5andCrNbO_4.
简介:ThedosimetricphosphorsLi_3PO_4:M(M=Tb,Cu)wereproducedbymodifiedsolid-statemethod.ThestructuralandmorphologicalcharacterizationwascarriedoutthroughX-raydiffraction(XRD)andscanningelectronmicroscope(SEM).Additionally,thephotoluminescence(PL),thermoluminescence(TL)andopticallystimulatedluminescence(OSL)propertiesofpowderLi_3PO_4dopedwithTbandCuwerestudied.ItisadvocatedthatLi_3PO_4:CuphosphornotonlyshowshigherOSLsensitivity(25timesormore)butalsogivesfasterdecayinOSLsignalsthanthatofLi_3PO_4:Tb~(3+)phosphor.Theminimumdetectabledose(MDD)ofLi_3PO_4:M(M=Tb,Cu)phosphorsisfoundtobe21.69×10~(-3)and3.33×10~(-6)J·kg~(-1),respectively.InOSLmode,phosphorshowslineardoseresponseintherangeof0.02-20.00J·kg~(-1).InTLmode,sensitivityofLi_3PO_4:CuphosphorismorethanthatofLi_3PO_4:Tbphosphor.Thekineticsparameterssuchasactivationenergyandfrequencyfactorsweredeterminedbypeakshapemethod,andphotoionizationcrosssectionsofpreparedphosphorwerecalculated.
简介:ThehotdeformationbehaviorofextrudedAZ80magnesiumalloywasinvestigatedusingcompressiontestsinthetemperaturerangeof250-400℃andstrainraterangeof0.001-1.000s^-1.The3Dpowerdissipationmapwasdevelopedtoevaluatethehotdeformationmechanismsanddeterminetheoptimalprocessingparameters.Twodomainsofdynamicrecrystallizationwereidentifiedfromthe3Dpowerdissipationmap,
简介:TheHAZmicrostructureandperformanceofQuenchingandTemperingmodetemperbeadweldingandgeneralweldedjointswhichweremadeonSA508-3steelof60mmthicknesswerecomparedinthisarticle.Theresultshowsthattemperingsorbitewhichhasexcellentoverallperformancewasobtainedinbothmodes.ThemicrostructureofQuenchingandTemperingmodeweldedjointsgotmorefinegrain.Eventhoughthehardnessoftemperingbeadweldedjointsishigherthanthegeneralone,itstillmeetsthestandardswhichislowerthan350HV.TheimpactabsorbingenergyofeachdistrictoftemperingbeadweldedjointsHAZreached170J,whichisequaltogeneralone.
简介:InordertoimprovethehydrogenstoragepropertiesofLiBH_4-MgH_2composite,twodifferentkindsofNb-basedcatalysts,NbCandNbF_5,wereaddedtoLiBH_4-MgH_2compositebyballmilling,andtheeffectofcatalystsonhydrogenstoragepropertiesofthemodifiedLiBH_4-MgH_2systemwasinvestigated.TheexperimentalresultsshowthatLiBH_4-MgH_2compositeisatwo-stepdehydrogenationprocess,andNb-basedcompoundscanremarkablyenhanceitsdehydrogenationkinetics.Forthecompositewithoutadditionofcatalysts,thestartingdecompositiontemperatureforthefirstdehydrogenationstepisaround320℃,andthereisalongperiodofincubationtime(around220min)fortheoccurrenceoftheseconddecompositionstepevenathightemperatureof450℃.Itneedsmorethan10htocompletethedecompositionprocessandreleasearound9wt%H_2.Afteradditionof5mol%NbF_5,thestartingdecompositiontemperatureforthefirstdehydrogenationstepisaround150℃,thereisnoincubationtimefortheseconddecompositionstep,andittakesaround40mintocompletethesecondstepandreachesatotaldehydrogenationcapacityof9.5wt%.NbF_5hasbettercatalyticeffectthanNbC.Basedonthehydrogenation/dehydrogenationbehaviorsandstructuralvariation,themechanismofcatalyticeffectwasdiscussed.
简介:GrainboundarydiffusiontechniquewithTbH_3nanoparticleswasappliedtofabricateTb-lesssinteredNdFe-Bpermanentmagnetswithhighcoercivity.Themagneticpropertiesandmicrostructureofmagnetsweresystematicallystudied.Thecoercivityandremanenceofgrainboundarydiffusionmagnetareimprovedby112%andreducedby26%comparedwiththoseoftheoriginalmagnet,respectively.Meanwhile,boththeremanencetemperaturecoefficient(α)andthecoercivitytemperaturecoefficient(β)ofthemagnetsareimprovedafterdiffusiontreatment.MicrostructureshowsthatTbelementenrichesinthesurfaceregionofNd_2Fe_(14)Bgrainsandisexpectedtoexistas(Nd,Tb)_2Fe_(14)Bphase.Thus,themagneto-crystallineanisotropyfieldofthemagnetimprovesremarkably.Asaresult,thesinteredNd-FeBmagnetsbygrainboundarydiffusionwithTbH_3nanoparticlesexhibitenhancedcoercivity.
简介:采用B50A789材料制备的压气机叶片产生的缺陷,主要是由于原材料内部夹杂、局部偏析、组织粗大,带状偏析和折叠引起的.本研究采用金相和能谱分析方法研究了锻造压气机叶片表面裂纹的形成机理,并对其锻造裂纹的形成过程进行有限元模拟.结果表明结合低倍及高倍形貌特征,可以得出叶片缺陷为锻造加工过程产生的折叠裂纹;通过有限元模拟分析认为锻造叶片表面裂纹是源于锻件在制坯过程中,在连接杆与安装圆盘的转接处形成啃伤台阶,导致终锻结束时在叶身形成折叠裂纹缺陷.同时通过对试验过程中锻造工艺调整,采用分料卡子对过渡区分料或进行打磨来保证转角半径圆滑过渡,可有效避免叶片表面折叠和裂纹缺陷的形成.
简介:Reducingthemanufacturingcostofsolarcellsisnecessarytotheirindustrialproduction.Electrodepositingisaneffective,non-vacuummethodwhichisverysuitableforcuttingthemanufacturingcostofthinfilmsaswellasdevelopingitslarge-scaleindustrialproduction.Inthisstudy,about1-μm-thickCu(In,Ga)Se_2(CIGS)precursorswereelectrodepositedonMo/glasssubstratesinaqueoussolutionutilizingathree-electrodepotentiostaticsystem.Triethanolaminewasusedascomplexingagent,andallparametersofelectrodepositionwerepreciselycontrolled.Afterthat,theelectrodepositedprecursorswereselenizedinaSeatmospherewithdifferentheatingramprates(60and600℃·min~(-1)).High-qualityCIGSfilmswereobtained,andtheircharacteristicswereinvestigatedbyX-rayfluorescence,scanningelectronmicroscopy,energydispersivespectroscopy,X-raydiffraction,Ramanspectraandnear-infrared-visible(NIR-Vis)spectra.Theresultsrevealthattherearemanydifferencesbetweenthepropertiesofthefilmsunderdifferentheatingrates.Finally,CIGSsolarcellswerefabricatedusingafastandaslowheatingrate.Themaximumefficienciesachievedforthefilmsselenizedat60and600℃-min~(-1)are3.15%and0.71%,respectively.
简介:TheeffectofAl-3Ti-0.2C-5Sr(wt%)grainrefinerontherefiningperformanceandmodificationofA356alloywasinvestigatedusingopticalmicroscope(OM).ThemorphologyandcrystalstructureofternaryAl-Ti-SrphasesinAl-3Ti-0.2C-5Srrefinerwereanalyzedbyscanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM).TheresultsshowthattheternaryAl-TiSrphasesinAl-3Ti-0.2C-5SrrefinercanpromotethegrainrefiningefficiencyofA356alloy.TheternaryAl-Ti-Srphasesco-existintwomorphologies,i.e.,blocky-likephaseandsurround-likephase,besides,whichbothhavethesamechemicalcompositionofAl_(34)Ti_3Sr.ThecrystalstructureofAl_(34)Ti_3Srisface-centeredcubic,andthelatticeparameterisdeterminedtobeabout1.52nm.
简介:ThediffusionbondingofAZ3\BMgalloyandQ235steelwasinvestigatedwithaZn-5AIalloyasinterlayerandunderdifferentholdingtimerangingfrom3to1200s.Themicrostructureandphasecompositionsofbondedjointswerecharacterizedbyscanningelectronmicroscopy(SEM),energydispersivespectrometer(EDS)andX-raydiffraction(XRD)methods.TheshearstrengthofMgalloy/steeljointswasmeasuredbytensiletester.Itwasfoundthatthemicrostructureofbondedjointsevolveddramaticallyalongwiththeprolongationofholdingtime.Undertheholdingtimeof3s,themainpartofjointwascomposedofMgZn2phaseanddispersedAl-richsolidsolutionparticles.Whenincreasedtheholdingtimemorethan60s,theexcessivesolutionofAZ3\Bintotheinterfacialreactionarealedtotheformationofcoarsephaseandeutecticmicrostructure,andalsothecomplexFe-AlandMg-Al-ZnIMCsattransitionlayerclosedtoQ235steelside.Accordingtothetensiletestingcharacterizations,thejointsobtainedunderholdingtimeof3sexhibitedthebestshearstrengthof84MPa,andthefractureoccurredattheintermediarypartofjointwheretheflexibleAl-richsolidsolutionparticlescouldhelptoimpedethemicrocrackpropagations.Withprolongingtheholdingtimeto600s,theshearstrengthofjointswasdeterioratedenormouslyandthefracturepositionwasshiftedtothetransitionlayerpartclosedtoQ235steel.