简介：Nb-24Ti-18Si-2Al-2Hf-4CrandNb-24Ti-18Si-2Al-2Hf-8Cralloyswerepreparedbyarcmeltinginawater-cooledcrucibleunderargonatmosphere.Microstructuralcharacteristicsandoxidationresistanceofthealloysat1250℃wereinvestigated.Theresultsshowthat,whentheCrcontentis4at%,themicrostructuresconsistof(Nb,Ti)_(ss)andNb_5Si_3;asCrcontentincreasesto8at%,C14LavesphaseCr_2Nbisformed.Theisothermaloxidationtestsshowthattheoxidationkineticsofthetwoalloysfollowsimilarfeatures.Theweightgainsofthetwoalloysafteroxidationat1250℃for100hare235.61and198.50mg·cm~(-2),respectively.Duringoxidation,SiO_2,TiO_2,Nb_2O_5andCrNbO_4areformedatfirst.Then,Ti_2Nb_(10)O_(29)isformedafteroxidationfor20minandbeginstochangeintoTiNb_2O_7astheoxidationproceeds.SiO_2isformedassolidstateatfirstbutlaterevolvesintoglassystatetoimprovethecohesionofthescale.Afteroxidationfor100h,oxidationproductsconsistofSiO_2,TiNb_2O_7,Nb_2O_5andCrNbO_4.

简介：本文基于三轴磁阻传感器HMC5983设计了磁记忆检测探头,研制了基于USB2I2C控制模块的二维金属磁记忆检测系统,以45钢为试验对象开展了金属磁记忆试验研究。通过分析磁记忆二维分量以及其微分分量合成的李萨如图大小,确定试件中存在应力集中的严重程度,试验结果表明：磁记忆二维检测不仅能够准确定位试件中应力集中的部位,而且能够从梯度变化角度对应力集中严重程度进行预判评估。

简介：p类型(100)上的HfO2电影的乐队排列磁控管劈啪作响种的InP底层被调查。化学状态和系统的结合的特征被X光检查光电子光谱学(XPS)描绘。结果证明没有Hf-P或Hf在里面的存在，有在2在接口的O3和InPO4。紫外分光光度计(UVS)被采用获得HfO2的乐队差距价值。在3d和Hf4f，核心级的系列和原子价系列被采用获得HfO2/InP的原子价乐队偏移量。试验性的结果出现(5.88??T

简介：InordertoimprovethehydrogenstoragepropertiesofLiBH_4-MgH_2composite,twodifferentkindsofNb-basedcatalysts,NbCandNbF_5,wereaddedtoLiBH_4-MgH_2compositebyballmilling,andtheeffectofcatalystsonhydrogenstoragepropertiesofthemodifiedLiBH_4-MgH_2systemwasinvestigated.TheexperimentalresultsshowthatLiBH_4-MgH_2compositeisatwo-stepdehydrogenationprocess,andNb-basedcompoundscanremarkablyenhanceitsdehydrogenationkinetics.Forthecompositewithoutadditionofcatalysts,thestartingdecompositiontemperatureforthefirstdehydrogenationstepisaround320℃,andthereisalongperiodofincubationtime(around220min)fortheoccurrenceoftheseconddecompositionstepevenathightemperatureof450℃.Itneedsmorethan10htocompletethedecompositionprocessandreleasearound9wt%H_2.Afteradditionof5mol%NbF_5,thestartingdecompositiontemperatureforthefirstdehydrogenationstepisaround150℃,thereisnoincubationtimefortheseconddecompositionstep,andittakesaround40mintocompletethesecondstepandreachesatotaldehydrogenationcapacityof9.5wt%.NbF_5hasbettercatalyticeffectthanNbC.Basedonthehydrogenation/dehydrogenationbehaviorsandstructuralvariation,themechanismofcatalyticeffectwasdiscussed.

简介：Reducingthemanufacturingcostofsolarcellsisnecessarytotheirindustrialproduction.Electrodepositingisaneffective,non-vacuummethodwhichisverysuitableforcuttingthemanufacturingcostofthinfilmsaswellasdevelopingitslarge-scaleindustrialproduction.Inthisstudy,about1-μm-thickCu(In,Ga)Se_2(CIGS)precursorswereelectrodepositedonMo/glasssubstratesinaqueoussolutionutilizingathree-electrodepotentiostaticsystem.Triethanolaminewasusedascomplexingagent,andallparametersofelectrodepositionwerepreciselycontrolled.Afterthat,theelectrodepositedprecursorswereselenizedinaSeatmospherewithdifferentheatingramprates(60and600℃·min~(-1)).High-qualityCIGSfilmswereobtained,andtheircharacteristicswereinvestigatedbyX-rayfluorescence,scanningelectronmicroscopy,energydispersivespectroscopy,X-raydiffraction,Ramanspectraandnear-infrared-visible(NIR-Vis)spectra.Theresultsrevealthattherearemanydifferencesbetweenthepropertiesofthefilmsunderdifferentheatingrates.Finally,CIGSsolarcellswerefabricatedusingafastandaslowheatingrate.Themaximumefficienciesachievedforthefilmsselenizedat60and600℃-min~(-1)are3.15%and0.71%,respectively.

简介：研究1Cr17Ni2不锈钢中不同δ铁素体相含量变化分别在FeCl3溶液和HNO3＋HF溶液中的耐腐蚀行为。通过腐蚀失重率计算及光学金相显微镜、扫描电子显微镜的观察发现：在FeCl3溶液中,δ铁素体的存在减弱了1Cr17Ni2不锈钢的耐腐蚀性能,δ铁素体是优选腐蚀相;而在HNO3＋HF溶液中,δ铁素体的存在增强1Cr17Ni2不锈钢的耐腐蚀性能,优选腐蚀相则变成了回火索氏体。通过表面腐蚀形貌表征可以实现反推其受到腐蚀介质环境的性质,为1Cr17Ni2不锈钢腐蚀失效与预防提供可行的方法和依据。

简介：为确定热加工性能的最佳条件，在温度350~500°C、应变率0.0005~0.5s-1下研究Al6061/Al2O3纳米复合材料的热压缩行为。采用双曲正弦函数得到材料热压缩测试活化能为285kJ/mol。用动态材料模型和相应的加工图，确定了温度450°C、应变速率0.0005s-1和温度500°C、应变速率0.0005~0.5s-1为Al6061/Al2O3材料的热加工性能安全区，最大功率损耗率为38%。由于材料大变形，在温度400°C和应变速率0.5s-1下得到了被伸长和扭结晶粒。