简介:AsimplespectrophotometricassayofH2O2andglucoseusingAgnanoparticleshasbeencarriedout.RelyingonthesynergisticeffectofH2O2reductionandultraviolet(UV)irradiation,Agnanoparticleswithenhancedabsorptionsignalsweresynthesized.H2O2servedasareducingagentintheAgnanoparticlesformationinwhichAg+wasreducedtoAg0byO2àgeneratedviathedecompositionofH2O2inalkalinemedia.Ontheotherhand,photoreductionofAg+toAg0underUVirradiationsalsocontributedtothenanoparticlesformation.ThesynthesizednanoparticleswerecharacterizedbyTEM,XPS,andXRD.TheproposedmethodcoulddetermineH2O2withconcentrationsrangingfrom5.010à7to6.010à5mol/L.Thedetectionlimitwasestimatedtobe2.010à7mol/L.SincetheconversionofglucosetogluconicacidcatalyzedbyglucoseoxidasewascompaniedwiththeformationofH2O2,thesensingprotocolhasbeensuccessfullyutilizedforthedeterminationofglucoseinhumanbloodsamples.Theresultswereingoodagreementwiththosedeterminedbyalocalhospital.Thiscolorimetricsensorthusholdsgreatpromisesinclinicalapplications.
简介:TiO2@ZrO2@Y2O3:有coremultishell结构的Eu3+合成粒子通过layer-by-layer(LBL)的联合被综合自己组装方法和一个solgel过程。获得的样品与扫描电子被描绘显微镜学(SEM),传播电子显微镜学(TEM),X光检查光电子光谱学(XPS),X光检查衍射(XRD),和荧光spectrophotometry。结果证明合成粒子有coremultishell结构,球形的形态学,和狭窄的尺寸分布。TiO2核心上的ZrO2层的存在能有效地阻止在TiO2核心和Y2O3壳之间的反应;为在在TiO2@ZrO2@Y2O3的TiO2核心和Y2O3壳之间的反应的温度:Eucoremultishell黄磷能被300提高
简介:Ahighlyeffcientandgeneralmethodforthesynthesisofpolyfunctionalized4H-pyransisestablishedthroughaone-potmulticomponentcyclocondensationofaromaticaldehydeswithCHacids,malononitrileandethylacetoacetateusingnanosilicasupportedtin(II)chlorideasacatalyst.InthismethodSnCl2/nanoSiO2wasusedasgreenandreusablecatalyst.Excellentyields,shortreactiontimes,simpleworkup,andinexpensivenessandcommerciallyavailabilityofthecatalystaretheadvantagesofthismethod.
简介:ThecorrelationbetweenphasestructuresandsurfaceacidityofAl2O3supportscalcinedatdifferenttemperaturesandthecatalyticperformanceofNi/Al2O3catalystsintheproductionofsyntheticnaturalgas(SNG)viaCOmethanationwassystematicallyinvestigated.Aseriesof10wt%NiO/Al2O3catalystswerepreparedbytheconventionalimpregnationmethod,andthephasestructuresandsurfaceacidityofAl2O3supportswereadjustedbycalciningthecommercialγ-Al2O3atdifferenttemperatures(600–1200C).COmethanationreactionwascarriedoutinthetemperaturerangeof300–600Catdifferentweighthourlyspacevelocities(WHSV=30000and120000mL·g-1h-1)andpressures(0.1and3.0MPa).ItwasfoundthathighcalcinationtemperaturenotonlyledtothegrowthinNiparticlesize,butalsoweakenedtheinteractionbetweenNinanoparticlesandAl2O3supportsduetotherapiddecreaseofthespecificsurfaceareaandacidityofAl2O3supports.Interestingly,NicatalystssupportedonAl2O3calcinedat1200C(Ni/Al2O3-1200)exhibitedthebestcatalyticactivityforCOmethanationunderdifferentreactionconditions.LifetimereactiontestsalsoindicatedthatNi/Al2O3-1200wasthemostactiveandstablecatalystcomparedwiththeotherthreecatalysts,whosesupportswerecalcinedatlowertemperatures(600,800and1000C).ThesefindingswouldthereforebehelpfultodevelopNi/Al2O3methanationcatalystforSNGproduction.
简介:针对珠海“国家园林城市”需要定量评估的问题,利用遥感模型和Landsat卫星图像反演地表温度、NDVI植被指数和MNDWI水体指数,定量分析其空间分布特征及影响关系。结果表明,大部分居民区的绿化覆盖率较高,NDVI在0.1~O.2,而大部分林地的NDVI在0.4~0.5,没有出现连续大面积的高地表温度区。NDVI〉O.3时,地表温度随NDVI的增加而快速下降,而NDVI在0.0~0.3地表温度随NDVI的增加而升高,平均地表温度峰值在NDVI为0.3,裸露的海滩、河滩等滩涂表面温度较低,减弱了裸露人工建筑高温像元的影响,使得结果与已有对其它内陆城市的研究不同。地表温度随水体指数的增加而降低,呈负相关关系。茂密的绿化林地、海洋等大面积水体、大面积滩涂和沼泽等湿地对调节珠海城市热环境发挥重要作用。