简介:Inthispaper,analmostP-stabletwo-stepsixth-orderHybridmethodwithphase-lagoforderinfinityandaclassexpliciteighth-orderObreckoffmethodswithphase-lagoforder10-24aredevelopedforthenumericalintegrationofthespecialsecond-orderperiodicinitial-valueproblems.Thesemethodshavetheadvantageofhigheralgebraicorderandconsiderablysmallerphase-tagcomparedwithsomemethodsin[1-6].Numericalexamplesindicatethatthesenewmethodsaremoreaccuratethanmethodsdevelopedby[1-6].
简介:一个新上面、更低的答案理论为第二个顺序问题(G'(y))被介绍“+f(t,y)=0在有限、无限的间隔上。有限间隔上的理论基于一种Leray鈥揝chauder选择,而无限的间隔上的理论在有限间隔和一个diagonalization过程上基于结果。关键词上面、更低的答案-无限的间隔-diagonalization过程-Leray鈥揝chauder选择先生(2000)题目分类34B15-34B18-34B40由捷克的共和国的资助机构和捷克的政府J14/98:153100011的委员会的资助号码201/01/1451支持了
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简介:Thedifferentregioselectiveandstereoselectiveproductswereobtainedbythereductionofstigmast-4,22-dien-3,6-dionewithNaBH4-CH3OHwhendifferentkindsofmetalionswasaddedtothereaction.
简介:TwoseriesofterritremBanalogues(10a-10cand18)havebeendesignedandsynthesizedfromjujubogenin5awhichwaspreparedfromjujubogeninglycosides5bobtainedfromtheleavesofZizyphusjujuba.Thestructuresofthenewcompoundswereconfirmedby1H-,13C-NMRandMSdata.Compounds10cand18showedweakinhibitoryeffectonAChEat10^-4mol/E.
简介:Lophenol,cholest-4α-methyl-7-en-3β-ol(1),obtainedfromDracaenacochinchinensis(Lour.)S.C.Chen,wasstructurallymodified.Itwasacetylatedtoprotect3β-hydroxylgroup,andthenoxidisedbyseleniumdioxideinaceticacidtogivecholest-4a-methyl-8-en-3β,Ta-dioldiacetate(3).Thiscompound3isunstableinchloroformsolutionorwhenheatedandeasilyconvertedtoadienecompound,cholest-4a-methyl-7,14-dien-3β-olacetate(4).Thestructuresof3and4wereelucidatedbymeansofIR,^1HNMR,^13CNMRandMS,andtheabsoluteconfigurationof3wasestablishedbyX-raycrystallography.Thepropertyof3wasalsodiscussedinthispaper.Both3and4arenewcompoundsandwerereportedforthefirsttime.
简介:Wepresenttheextendedhydrogenatomandmonopole-hydrogenatomtheorythroughgeneralizingtheusualhydrogenatommodelandwithamonopolemodelrespectively,inwhichY(sl(2))algebrasarerealized.WederivetheHamiltoniansofthetwomodelsbasedontheY(sl(2))andthegeneralizedPauliequation.TheenergyspectraofthesystemsarealsogivenintermsofYangianalgebraandquantummechanics.
简介:NewrareearthvanadatesYSrQ-xCaxV3O9-y(x=0.0,0.67,1.0,1.33and2.0)havebeensynthesizedbyanewsimplemethod.X-raypowderdiffractionresultsshowthattheyaremono-phase.Theybelongtoorthorhombicstructureandtheirlatticeconstantsarecalculated.TheresultsofweightgainsinTGcurvesshowthatthelowervalentvanadiumisoxidizedtohighervalentstateathighertemperature.Theoxygencontentsofnewcompoundsarecalculatedfromtheweightgains.BothV3+andV4+coexistinYSr2-xCaxV3O9-y.Thesecompoundsexhibitlowelectricresistivityatroomtemperature.
简介:ForquadraticnumberfieldsF=Q(√2pl…pt-1)withprimespj≡1mod8,theauthorsstudytheclassnumberandthenormofthefundamentalunitofF.TheresultsgeneralizenicelywhathasbeenfamiliarforthefieldsQ(√2p)withaprimep≡1mod8,includingdensitystatements.Andtheresultsarestatedintermsofthequadraticformx2+32y2andillustratedintermsofgraphs.
简介:采用水热方法合成一种新型钼-氧簇化合物Ni(en)3MoO4,并通过X射线单晶结构分析、红外光谱分析、元素分析、差热热重分析对该化合物进行了表征.结构分析数据表明:该化合物属三方晶系,P-31c空间群,晶胞参数a=0.9226(13)nm,b=0.9226(13)nm,c=0.9959(2)cm,α=90°,β=90°,γ=120°,V=0.7342(2)nm3,Z=2,Dc=1.805mg/m3,μ=2.153mm-1,F(000)=408,R=00553,Rw=0.1732;该化合物是分立结构,是由MoO4四面体簇和Ni(en)3八面体簇形成,其中MoO4四面体簇和Ni(en)3八面体簇交替排列,存在较强的氢键作用,结构中分立的手性配合物Ni(en)3的两种对映体构象以MoO4簇为中心对称排布.