简介:Theadsorptionandelectronicpropertiesofisolatedcobaltphthalocyanine(CoPc)moleculeonanultrathinlayerofNaClhavebeeninvestigated.High-resolutionSTMimagesgiveadetailedpictureofthelowestunoccupiedmolecularorbital(LUMO)ofanisolatedCoPc.ItisshownthattheNaClultrathinlayerefficientlydecouplestheinteractionofthemoleculesfromtheunderneathmetalsubstrate,whichmakesitanidealsubstrateforstudyingthepropertiesofsinglemolecules.Moreover,strongdependenceoftheappearanceofthemoleculesonthesamplebiasintheregionofrelativelyhighbias(>3.1V)isascribedtotheimagepotentialstates(IPSs)ofNaCl/Cu(100),whichmayprovideuswithapossiblemethodtofabricatequantumstoragedevices.
简介:阐明physisorbed的效果几何学和hydrogenated钻石电影的电子结构上的活跃离子,HCO3-的模型,H3O+,并且哦hydrogenated钻石(100)上的离子physisorbed出现被构造。密度功能的理论被用来计算状态的几何学,吸附精力,和部分密度。结果证明表面都在离子吸附以后改变了到不同的度的hydrogenated钻石(100)的几何学。在他们之中,H3影响的O+离子hydrogenated钻石(100)的几何学出现大多数。这与计算吸附精力的结果很好一致,它显示一个强壮的静电的吸引力发生在hydrogenated钻石(100)之间表面和H3O+离子。另外,电子从hydrogenated钻石(100)显著地转表面到吸附的H3O+离子,它导致一向下变在H3O+离子。然而,为活跃离子喜欢哦和HCO3-,没有戏剧的变化为吸附的离子的电子结构出现。
简介:Twotransmissioncurvedcrystalspectrometersaredesignedtomeasurethehardx-rayemissioninthelaserfusionexperimentofComptonradiographyofimplosiontargetonShenGuang-IIIlaserfacilityinChina.Cylindricallycurvedα-quartz(10–11)crystalswithcurvatureradiiof150and300mmareusedtocoverspectralrangesof10–56and17–100keV,respectively.Thedistancebetweenthecrystalandthex-raysourcecanbechangedoverabroaddistancefrom200to1500mm.Theopticaldesign,includingtheintegralreflectivityofthecurvedcrystal,thesensitivity,andthespectralresolutionofthespectrometers,isdiscussed.WealsoprovidemechanicdesigndetailsandexperimentalresultsusingaMoanodex-raysource.High-qualityspectrawereobtained.Weconfirmedthatthespectralresolutioncanbeimprovedbyincreasingtheworkingdistance,whichisthedistancebetweentherecordingmediumandtheRowlandcircle.
简介:Wepresentanovelandsimplemethodtoobtainanultrawidefreespectralrange(FSR)siliconringresonatortogetherwithatuningrangecoveringtheentirespectrumfrom1500to1600nm.AringresonatorwithalargeFSRtogetherwithahighQfactor,hightuningefficiency,andlowfabricationcostandcomplexityisdesiredformanyapplications.Inthispaper,weintroduceanovelwaytomakesucharingresonator,whichtakesadvantageofthewell-knownresonance-splittingphenomenon.ItisasingleringresonatorwithanFSRofmorethan150nmaround1550nmandwhichhasaneasythermo-optictunabilitythatcanproduceatuningrangearound90nmorevenmore.Moreover,thedeviceissimpletoimplementandcanbefabricatedinstandardcomplementarymetal-oxidesemiconductortechnologywithoutrequiringanykindofcomplicatedprocessingorextramaterials.Thepotentialapplicationsincludesinglemodelasercavities,wavelengthdivisionmultiplexingfilters,(de)multiplexers,opticalsensors,andintegratedreflectors.