简介:Thispapercarriesoutabinitiocalculationstostudythe80Se2(X3Σg-)stateand80Se2(X2Πg),80Se2(a4Πg)statesbyusingcompletedactivespaceself-consistentfieldandmulti-referencesecondorderperturbationtheory.Theelectroniccurvesofthesestatesincludingspin-orbitcouplingarecalculated,andthenthespectroscopicparametersareobtained.Thephotoelectronspectraof80Se2moleculeingasphaseareassignedaccordingtoFranck-Condonanalysisbasedoncalculatedpotentialenergycurves.Theionizationenergiesof80Se2moleculearedeterminedbythepresentcalculation.
简介:ThisvolumeisdedicatedtoProfessorXiaqiDing,anacademicianoftheChineseAcademyofSciences,ontheoccasionofhiseightiethbirthday.ProfessorXiaqiDingwasbornonMay25,1928,inTaoJiangcounty,Hunanprovince.Hewasgraduatedin1951fromtheDepartmentofMathematics,WuhanUniversity.Becauseofhisoutstandingacademicperformance,hewasselectedrightaftercollegeforhisstudyandresearchat
简介:Wehaveshownthat,incontrasttotheresultsintheliterature,theBraggpeakintensityofNi80Fe20/Cusuperlatticesisenhancedattheincidentx-rayenergyslightlyhigherthantheabsorptionedgeoftheheavierelement(Cu).TheatomicdensityatNi80Fe20/Cuinterfacewasanalysedbythediffractionanomalousfinestructuretechnologywiththeincidentangleofx-rayfixedatthefirstBraggpeak.OurresultsdemonstratetheepitaxygrowthofNi80Fe20/Cusuperlattices.Uponannealing,theepitaxityofNi80Fe20/Cumultilayersbecomespoorbutthelocalcrystallinityineachlayerisimproved.
简介:Wereportonaone-stageerbium-dopedfibreamplifiedspontaneousemission(ASE)sourcewith80nmbandwidthand13.5dBmoutputpower.thebroadbandwidtherbiumASEsourcewasrealizedinanerbium-dopedfibrewith37mlengthbya1480nmlaserdiodeanda980nmlaserdiodeasforwardandbackwardpumpsources,respectively.Thetotalpumppowerisonly95.7mW.
简介:Variousagriculturalcropresiduesincludingcornstover,corncob,andsorghumstalkwithamoisturecontentof75wt%weresubjectedtoalongpretreatment(12-60h)withsupercriticalCO2(scCO2),atlowtemperature(50-80℃)andapressureof17.5-25.0Mpa.Thesugaryieldsfromtheenzymatichydrolysis(EH)ofthepretreatedsampleswereasmuchasthree-tofourfoldgreaterthanthoseaffordedbytherawmaterials.However,whenpretreatmentwasconductedwithinashorttime(e.g.0.5h),aspreviouslyreportedintheliterature,onlyaslightincreaseintheEHsugaryieldswasobserved.TheproposedscCO2pretreatmentmechanismdemonstratedtheroleofmoistureinthesystem.Wetting,softening,andswellingwereobservedtomainlyaffectthelignocellulosewhenasuitableamountofwaterwasadded.Finally,thesampleswereanalysedbyX-raydiffractionandscanningelectronmicroscopy,beforeandafterpretreatment,toinvestigatethechangesinthemicroscopicstructureofthebiomass.
简介:HeBinglinwasbornonAugust24,1918inFanyuCounty,GuangdongProvince.HegraduatedfromtheChemistryDepartmentofSouthwestAssociatedUniversityin1942.AftergraduationheworkedinChongqingCentralInstituteofIndustryforoneyearasanassistantengineerandthenreturnedtohisAlmaMaterUniversity
简介:Thermoelectricityisatherrnorelatedpropertythatisofgreatimportanceinsingle-moleculejunctions.Theelectricalconductance(σ),electron-derivedthermalconductance(kel)andSeebeckcoefficient(S)ofBgo-basedsingle-moleculejunctionsareinvestigatedbyusingdensityfunctionaltheoryincombinationwithnon-equilibriumGreen'sfunction.Whenthedistancebetweentheleft/rightelectrodesis11.4A,therelationshipbetweenσandkelobeystheWiedemann-FranzlawverywellbecauseofthestronghybridizationbetweenB80molecularorbitalsandthesurfacestatesofAuelectrodes.Furthermore,thecalculatedLorenznumberisclosetothefamousvalueinmetalordegeneratesemiconductors.Inaddition,Sisonly—19.09μV/Kat300K,thusleadingtothesmallerelectron'sthermoelectriefigureofmerit(ZeiT=S^2σT/Kel).Interestingly,thestrainandchemicalpotentialcanmodulateB80-basedsingle-moleculejunctionsfromn-typetop-typewhenthecompressivestrainreaches—0.6Aorthechemicalpotentialshiftsto—0.16eV.ThismightbeattributedthatSreflectstheasymmetryintheelectricalconductancewithrespecttothechemicalpotentialandisproportionaltotheslopesofthetransmissionspectrum.
简介:ThedetailedmicrostructuresofNi80Fe20/Fe50Mn50superlatticeshavebeencharacterizedusingbothx-raydiffractiontechniquesandtransmissionelectronmicroscopy.Theobrivouslayeredstructure,typicalcolumnstructureandtwinswhichexistinNi80Fe20/Fe50Mn50superlatticeswereobservedthroughperformingtransmissionmicroscopy.Bycombiningthetechniqueoflowanglex-rayreflectivity(specularandoff-specularscans)withtheanomalousscatteringeffectandhigh-anglex-raydiffraction(usingconventionalx-ray),wequantitativelyanalysedthemicrostructuralvariationasafunctionofannealingtemperature.Itisfoundthatthelateralcorrelationlength,the(111)peakintensityofthesuperlatticesandtheaveragemultilayercoherencelengthallincreasewithariseinannealingtemperatureannealingcandecreasetherootmean-squareroughnessattheinterfacesofNi80Fe20/Fe50Mn50superlattices.theobtainedmicrostructuralknowledgewillbehelpfulinunderstandingthemagneticpropertiesoftheni80Fe20/Fe50Mn50exchangebiassystem.
简介:Wehavereportedthemassmeasurementsofneutron-deficientnuclides79Y,81;82Zr,83;84Nbinthisyear’sAnnualReport.However,fortheN=ZnuclidesclosetoA=80,theyieldismuchlowerandeveniftheycanbeproduced,thereisstillgreatdifficulttoidentifythembecauseoftheirquitesimilarmass-to-chargeratioandrevolutiontimes.However,theirmassareextremelyimportantforrapidprotoncaptureprocess,forexample,80Zrand84Moarewaitingpointsofrp-process.Theirmassescangreatlyeffectthereactionflowofprotoncaptureonthemandthentheabundanceoftheheaviernuclides.Inaddition,theseparationenergyof84Mo(determinedbythemassof80Zrand84Mo)hasastrongimpactonthe83Nb(p,α)reactionrateandplaysakeyroleintheformationofZr-NbFig.