简介:Inthispaper,analmostP-stabletwo-stepsixth-orderHybridmethodwithphase-lagoforderinfinityandaclassexpliciteighth-orderObreckoffmethodswithphase-lagoforder10-24aredevelopedforthenumericalintegrationofthespecialsecond-orderperiodicinitial-valueproblems.Thesemethodshavetheadvantageofhigheralgebraicorderandconsiderablysmallerphase-tagcomparedwithsomemethodsin[1-6].Numericalexamplesindicatethatthesenewmethodsaremoreaccuratethanmethodsdevelopedby[1-6].
简介:Twonewdicyanamidecoordinationpolymers,{Mn(dmpz)[N(CN)2]2}2(1)and{Cu(dmpz)[N(CN)2]2}2(2)(dmpz=3,5-dimethylpyrazole),weresynthesizedandcharacterizedbysinglecrystalX-raydiffractionanalysisandIRspectroscopy.In1and2themetalionshavetwodifferentcoordinationmodes,whereoneiscoordinatedtofourdicyanamideanionsandtwomonodentatedmpzmoleculestoformaslightlydistortedoctahedralgeometry,whiletheotheradoptsoctahedralgeometry,surroundedbyfournitrileNatomsandtwoamideNatomsofthedicyanamideanions.Bothcomplexescontaintwoalternatingchainsthatareparalleltoeachother.
简介:一个新上面、更低的答案理论为第二个顺序问题(G'(y))被介绍“+f(t,y)=0在有限、无限的间隔上。有限间隔上的理论基于一种Leray鈥揝chauder选择,而无限的间隔上的理论在有限间隔和一个diagonalization过程上基于结果。关键词上面、更低的答案-无限的间隔-diagonalization过程-Leray鈥揝chauder选择先生(2000)题目分类34B15-34B18-34B40由捷克的共和国的资助机构和捷克的政府J14/98:153100011的委员会的资助号码201/01/1451支持了
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简介:ItisknownthatthereexistsanisogenysortofChevalleygroupsG(∑,F)associatedtoanyindecomposablerootsystem∑andanyfieldF.InthispapertheauthordeterminesallnontfivialhomomorphismsfromG(∑,k)toG(∑,K)whentherootsystem∑isoftypeCnorG2,andthefieldskandKarefinitefieldsofcharacteristiep.
简介:Inthisarticle,first,asufficientconditionforastarlikemappingoforderαf(x)definedontheunitballinacomplexBanachspaceisgiven.Second,thesharpestimateofthethirdhomogeneousexpansionforfisestablishedaswell,wheref(z)=(f1(z),f2(z),...,fn(z))’isastarlikemappingoforderαoranormalizedbiholomorphicstarlikemappingdefinedontheunitpolydiskinCn,andOurresultstatesthattheBieberbachconjectureinseveralcomplexvariables(thecaseofthethirdhomogeneousexpansionforstarlikemappingsoforderαandbiholomorphicstarlikemappings)ispartlyproved.
简介:合成了氰根桥联配合物Co[Fe(CN)5NO].5H2O,使用元素分析、热重分析、红外光谱、XRD对配合物进行了表征。红外光谱显示金属离子通过氰根桥联即FeII-CN-NiII传递磁相互作用,是属于桥式氰根配体的CN伸缩振动,而粉末XRD衍射图表明此化合物为面心立方体结构(FCC),空间群为Fm3m(225),晶格常数a=10.2856。通过对该配合物的直流变温磁化率和交流磁化率测定表明金属离子通过氰根传递弱反铁磁作用,根据Curie-Weiss定律,拟合数据获得居里常数C=1.55cm3·K/mol,顺磁居里温度θ=-1.87K。
简介:采用HF/DFT的混合泛函PBE0和UPBE0优化了配合物[Os(PH3)2(CN)2(N^N)](其中N^N=2,2′-吡啶)的基态和激发态结构.在基态和激发态结构的基础上,利用含时密度泛函理论(TD-DFT)方法,结合极化连续介质(PCM)模型分别计算了它在二氯甲烷(1)、甲醇(2)、气态(3)和乙腈(4)溶液中的吸收和发射光谱.研究结果表明:优化得到的几何结构参数和相应的实验值符合得非常好.在极性较大的溶剂(2和4)中Os—P(1)和Os—C(1)键较长,Os—N(3)键较短,溶剂的极性会影响配合物的电子云分布.配合物在1-4溶剂中的最低能吸收和发射均来自分子轨道68→71的激发,该激发被指认为[d(Os)+π(CN)+π(N^N)→π*(N^N)]的跃迁具有混合的MLCT/LLCT特征.配合物在1-4溶剂中的最低能吸收和发射分别在471,410,488和445nm以及598,536,634和545nm,表明随着溶剂极性的逐渐增大(3〈1〈4〈2),最低能吸收和发射发生明显的蓝移.这显示出通过改变溶剂极性可以调节配合物的发光颜色.
简介:Wepresenttheextendedhydrogenatomandmonopole-hydrogenatomtheorythroughgeneralizingtheusualhydrogenatommodelandwithamonopolemodelrespectively,inwhichY(sl(2))algebrasarerealized.WederivetheHamiltoniansofthetwomodelsbasedontheY(sl(2))andthegeneralizedPauliequation.TheenergyspectraofthesystemsarealsogivenintermsofYangianalgebraandquantummechanics.