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  • 简介:Thesolidaddofthefirstprotonatedzincoborophosphate,(H3O)Zn(H2O)2BP2O8·H2O(1),wassoventothermallysyn-thesizedbythereactionofZn(NO3)2·6H2OandH3BO3withH3PO4inamixedsolvent,andstructurallycharacterizedbysingle-ystalX-raydiffractionanalysis.ItcrystallizesinthehexagonalP6122,a=0.9604(4)nm,c=1.5297(6)nm,V=1.2218(8)nm^3,Dc=2.921g/cm^3,Z=6,F(000)=1080,μ=3.495mm^-1.Thestmchwefeaturesthatthetetrahedra-te-trahedrahdlcesinterconnectedbyoctahedraandstronghydro-gembondinteractionsformathree-dimensionalframework.Theprotonatedwatermoleculesarelocatedatuniquepositions.othercharacterizationsbyIRandthermalanalysisarealsode-scribed.

  • 标签: (H3O)Zn(H2O)2BP2O8·H2O 合成 结构 质子化 螺旋带状物 硼磷酸锌化合物
  • 简介:Theobjectinthispaperistoconsidertheproblemofexistence,uniqueness,explicilrepresentationof(0,2)-interpolationonthezerosof(1-x2)Pn-1(x)/xwhennisodd,wherePn-1denotesLegendrepolynomialofdegreen-1,andtheproblemofconvergenceofinterpolatorypolynomials.

  • 标签: INTERPOLATION CONST UNIQUENESS details polynomial arbitrary
  • 简介:Wegiveaconstructionofthemaximum,andtheminimumofthesetofnondecreasmgapproxmantsinthediscretecase,whereisapositiveconoexfunction.Acharacterizationofthatsetisalsoobtained.

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  • 简介:On △I=4 Bifurcation PhenomenaOn△I=4BifurcationPhenomena¥ZhangJingye;YangSunandMikeGuidryTheexperiments-bythenew7--raydetector...

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  • 简介:让{X,Xn;n鈮?1}i.i.d的一个序列是随机变量,前=0,前2=蟽2<鈭?给Sn=X1+X2+吗?+Xn,Mn=最大k鈮鈭k鈭?n鈮?1。让n=O(1/木头木头n)。在这份报纸,我们证明那,为b>?1,

  • 标签: 切断法 随意变量 叠对数定律 序列
  • 简介:Inthispaperwestudytheaverageσ-Kwidthandtheaverageσ-linearwidthoftheunitballofl1x(R)inl2α(R).Theexactvaluesofthesewidthsarecalculatedandanoptimalsubspacewiththeoptimallinearopera-tor(fortheσ-linearwidth)areidentified.

  • 标签: exact inequality opera subspace AVERAGE R)IN
  • 简介:WeuseMnforthesetofalln×nrealmatrices;(n)for{1,…,n};Snforthesymmetricgroupon〈n〉;A[α]α∈

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  • 简介:Theenantiomersofthirty-nineO-ethylO-phenylN-isopropylphosphoroamidothioateshavebeenseparatedbyhighperformanceliquidchromatographyonaPirklemodelchiralstationaryphaseusingtenmobilephase.Chromatographicdataarepresentedfortheseparationoftheseorganicphosphorusenantiomersonthechiralphase.Theinfluencesofmolecularstructuresandcompositionsofmobilephaseshavebeendescribed.

  • 标签: HPLC phosphorus ENANTIOMER SEPARATION PESTICIDE ENANTIOMERS
  • 简介:Thispaperstudiestheinteractionofshockandgradientwave(soundwave)ofsolutionstothesystemofinviscidisentropicgasdynamicsasamodelforthecorrespondingproblemsfornonlinearhyperbolicsystems.Theproblemcanbereducedtoaboundaryvalueprobleminawedgeddormain,ByusingthemethodofconstructingasymptoticsolutionsandNewton'siterationprocessitisprovedthatifaweakshockhitsagradientwave,thenthegrandientwavewillsplitintotwogradientwaves,whiletheshockcontinusespropagating.Inthispapertheauthorreducestheproblemtoastandardformandconstructsasymptoticsolutionoftheproblem.Theexistenceofthegenuinesolutionwillhegiveninthefollowingpaper.

  • 标签: 震动交感 声波 气体动力学 数学模型
  • 简介:Theauthorintroducesanotionofweak1sequencesandcharacterizessuchsequencesbymeansofhomologicalmethods.ThisnotionextendsthenotionofweekM-sequencesandthusextendsthenotionsofgeneralizedCohen-MacaulaymodulesandBuchsbaummodulestomoregeneralcases.

  • 标签: Noetherian局部环 上同调群 Koszul同调群 M序列
  • 简介:ThemultivariatesplineswhichwerefirstpresentedbydeBooorasacompletetheoreticalsystemhaveintriguedmanymathematicianswhohavedevotedmanyworksinthisfieldwhichisstillintheprocessofdevelopment.Theauthorofthispaperisinterestedintheareaofinter-polationwithspecialemphasisontheinterpolationmethodsandtheirapproximationorders.ButsuchB-splines(bothunivariateandmultivariate)donotinterpolateddirectly,soIap-proachedthisprobleminanotherwaywhichistoextendmyinterpolatingsplineofdegree2n-1inunivariatecase(See[7])tomultivariatecase.Iselectedtriangulatedregionwhichisinspiredbyothermathematicians’works(e.g.[2]and[3])andextendtheinterpolatingpolynomialsfromunivariatetom-variatecase(See[10])Inthispapersomeresultsinthecasem=2arediscussedandprovedinmoreconcretedetails.Basedonthesepolynomials,theinterpolatingsplines(itisdefinedbymeaspiecewisepolynomialsinwhichtheunknownpar-tialderivativesaredeterminedundercertaincontinuousconditions)arealsodiscussed.Theapproximationordersofinterpolatingpolynomialsandofcubicinterpolatingsplinesareinverstigated.Welunitedourdiscussionontherectangulardomainwhichispartitionedintoequalrighttriangles.Astothecaseinwhichtherectangulardomainispartitionedintounequalrighttrianglesaswellasthecaseofmorecomplicateddomains,wewilldiscussinthenextpa-per.

  • 标签: univariate MULTIVARIATE partitioned interpolation discussion DETAILS
  • 简介:有N-(2-propionic酸)的新奇金轧(III)建筑群-salicyloylhydrazone(C10H10N2O4,H3L)并且1,10-phenanthroline(C12H8N2,phen)被准备并且描绘。水晶结构[Gd(H2L)(HL)-(H2O)3]2潲楰湯捩???慳楬祣潬汹?票牤穡湯??ㄠ??桰湥湡桴潲楬敮???????楢慯瑣癩瑩?

  • 标签: 邻二氮杂菲 晶体结构 X射线衍射 三斜晶系
  • 简介:利用直接法合成未见文献报道的K8[ZnMg(H2O)W11O39]·15H2O,通过ICP,IR和XRD等方法对其结构进行表征,结果表明所合成的配合物具有Keggin结构.采用化学热扩渗法对合成配合物进行稀土扩渗实验,经XPS测试表明,有微量的钆渗进配合物的体相,并与组成元素存在键合作用,导电性测试结果表明,扩渗后试样的导电率提高10^5倍,是一种优良的固体电解质,有望成为具有实用价值的功能材料.

  • 标签: 多金属氧酸盐 稀土多元渗 导电性
  • 简介:TheauthorsconsiderthemultilinearoscillatorysingularintegraloperatordefinedbyTA1,A2,…,Akf(x)=∫R^ne^ip(x,v)k/∏/j=1Rmi(Ajix,y)(Ω(x-y))/(│x-y│^n+M)f(y)dy,whereP(x,y)isareal-valuedpolynomialonR^n×R^n,Ωishomogeneousofdegreezero,Rmj(Aj;x,y)denotesthemj-thorderTaylorseriesremainderofAjatxexpandedabouty,M=k/∑j=1mj,ItisshownthatifΩbelongstothespaceLlog^+L(S^n-1)andhasvanishingmomentuptoorderM,then‖TA1,A2,…,Akf‖q≤ck/∏/j=1(∏/│α│=mj‖D^αAj‖rj)‖f‖p,providedthat1

  • 标签: 多重线性摆动 积分算子 单一性 极大算子
  • 简介:Fivechiralstationaryphases(CSPs)wereusedtoseparatetheenantiomersofaseriesofO,O-diethyl(p-methyl-benzenesulfonamindo)-aryl(alkyl)-methylphosphonates.Achiralrecognitionmechanismwaspresentedtoexplaintheresolutionofthesecompounds.ResultsshowthatCSPwithstrongπ-acceptor3,5-dinitrobenzoylgroupandhighsterichindrancehasthebestresolutionabilityinchiralseparationofO,O-diethyi(p-methyl-benzenesulfonamindo)-aryl(alkyl)-methylphosphonates.WhenaCSPhasjustastrongπ-acceptor3,5-dinitrobenzoylorhighsterichindranceitdoesnothavegoodchiralresolutionability.ThechiralrecognitionismoredifficultwhentheCSPhasmorethanoneasymmetriccenter.

  • 标签: CHIRAL stationary PHASES (CSPs) CHIRAL recognition
  • 简介:AquantummechanicalcalculationwasperformedtostudytheTranslation-Vibration(T-V)energytransferofacolinearOH+O/OD+Osystem,forwhichDelvescoordinatesandR-matrixpropagatationmethodswereappliedtoaMulius-Blintpotentialenergysurface.ThecalculatedresultoftheT-Venergytransferprobabilityshowsstrongoscillationphenomenaandthecollisiondelaytimeofthetitlesystemwasinthe10-15—10-12stimescale.Thekineticisotopeeffectwasdiscussedinthisworktoo.

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