简介:Theapplicabilityandlimitationofseveralquadraticstrengththeorieswereinvestigatedwithrespectto2D-C/SiCand2.5D-C/SiCcomposites.Akindofdamage-basedfailurecriterion,referredtoasD-criterion,isproposedfornonlinearceramiccomposites.Meanwhile,thenewlydevelopedcriterionispreliminarilyvalidatedundertension-shearcombinedloadings.ThepredictionshowsthatthefailureenvelopegivenbyD-criterionislowerthanthatfromTsai–HillandHoffmancriteria.Thisrevealsthatthedamage-basedcriterionisreasonableforevaluationofdamage-dominatedfailurestrength.
简介:Twocompactandintense2.45GHzpermanentprotonsourcesandtheircorrespondinglowenergybeamtransport(LEBT)systemsweredevelopedsuccessfullyforChinaAcceleratorDrivenSub-criticalsystem(C-ADS)in2014,oneofwhichwasbuiltatIMP,LanzhouandtheotheratIHEP,Beijing.Bothprotonsourcescandeliverstable10mA/35keVprotonbeamsatCWmodetotheentrancesofthedownstreamRFQs.AsshowninFig.1,thebeamsextractedbya3-electrodeextractionsystemaretransportedbytheLEBTsystem,whichiscomposedof2identicalsolenoids,andintothe3.2or2.1MeVradio-frequencyquadrupole(RFQ).Inordertoensuresuperconductingcavitiescommissioningandprotection,anelectrostatic-chopperhasbeendesignedandinstalledintheLEBTlinethatcanchopthecwbeamFig.2Totalhydrogenionbeamcurrentversusinputpower.intoapulsedone.Theachievedfall/risetimeofthechopperislessthan20ns.
简介:APt-MoO3/Ccatalyst,aimedtoeliminatetheharmfuleffectofsulfurdioxide(SCb)ontheperformanceofPtnanoparticles(NPs)forcatalysisofoxygenreductionreaction(ORR)inprotonexchangemembranefuelcells(PEMFC),isdevelopedandcharacterizedbyTEM,XRDandXPS.TheresultsrevealthatPt-MoO3/Ccatalystexhibitsnotonlyahighercatalyticactivity,butalsoabetterSO2poisoningresistanceandabetterrecoveryperformancethanthecommercialPt/Ccatalystdoes.
简介:InthispaperweestablishsharpH¨olderestimatesofharmonicfunctionsonaclassofconnectedpostcriticallyfinite(p.c.f.)self-similarsets,andshowthatfunctionsinthedomainofLaplacianenjoythesameproperty.Somewell-knownexamples,suchastheSierpinskigasket,theunitinterval,thelevel3Sierpinskigasket,thehexagasket,the3-dimensionalSierpinskigasket,andtheVicseksetarealsoconsidered.
简介:采用密度泛函B3LYP/6-311G(d,p)方法对CH3F与C2H3的反应体系进行了理论研究,获得了反应的势能面信息及可能的微观机理.在QCISD(T)/6-311++G(d,p)水平上精确计算了各反应物种的单点能.结果表明,除抽提氢反应外,标题反应还存在抽提氟(R1)、消氟化氢(R2)、消氢(R3)和自由基形成(R4)四类反应.在QCISD(T)/6-311++G(d,p)//B3LYP/6-311G(d,p)水平上,R1,R2,R3和R4反应的能垒分别是163.9,152.2,209.8和224.2kJ·mol-1,相应反应能为-56.6,-164.3,-2.7和-156.0kJ·mol-1,所有反应均放热,为热力学允许的反应.
简介:介绍了2014年美国大学生数学建模竞赛C题的背景与立意,针对6篇获得Outstanding奖的论文的解题思路与方法进行了归纳与总结,指出了学生答卷中的亮点与不足,并给出了建议和改进方案。
简介:采用密度泛函方法对11顶点巢式碳硼烷C2B9H112-异构体进行了几何结构优化,分析了稳定性、电荷分布及分子轨道.结果表明,9个异构体都有对应的稳定构型,保持了巢式骨架结构.C取代开口五元环上B的异构体更稳定,且随取代数目增加和C原子间距增加而增加,C—C键和C—B键作用增强.C取代内层B使异构体稳定性降低,C—C键和C—B键长随之增长.负电荷主要集中在C原子上,开口五元环上的C原子上负电荷要比内层C原子更多,成为亲核取代反应中心.异构体分子前线轨道具有和η5-C5H5-相似的π键性质,ΔELUMO-HOMO反映的化学稳定性与结构能量稳定性趋势一致.