简介:为探索以D-甘露糖与氨基酸的美拉德反应制备Amadori化合物的可行性问题,以D-甘露糖和L-色氨酸为原料合成了1-L-色氨酸-1-脱氧-D-果糖,利用IR、NMR和HR-MS对产物进行了结构表征,采用单因素试验和正交试验优化了合成工艺,利用在线裂解气相色谱/质谱联用(Py-GC/MS)法研究了产物的热裂解行为。结果表明:(1)最佳合成条件为:当L-色氨酸投料量为30mmol时,反应温度65℃、反应时间6.0h、物料比1:1(D-甘露糖与L-色氨酸的物质的量比)、催化剂用量0.5mmol及溶剂用量80mL,此条件下产率达到45.2%;(2)无论有氧或无氧条件下裂解,产物种类均随温度升高而增加,有氧条件裂解产物种类多于无氧条件;在600℃有氧条件下,1-L-色氨酸-1-脱氧-D-果糖裂解生成具有花香、烘烤香、坚果香、焦糖香等香韵的产物;(3)以D-甘露糖和L-色氨酸为原料合成1-L-色氨酸-1-脱氧-D-果糖的技术方法可行,产品收率较高。
简介:采用热重-微分热重技术研究了1-L-谷氨酸-1-脱氧-D-果糖的热失重和裂解温度,通过在线裂解气质联用技术分别分析研究了无氧和有氧条件下1-L-谷氨酸-1-脱氧-D-果糖在300℃、600℃、750℃和900℃四个温度的热裂解产物。研究结果表明1-L-谷氨酸-1-脱氧-D-果糖的裂解温度为161.3℃,在700℃时失重达到90.50%。无氧和有氧条件下裂解产物的种类和数量随着裂解温度升高而增多,有氧条件下裂解产物总数稍多于无氧条件,但种类有明显差异。无氧裂解和有氧裂解产物主要为酮类、吡咯类、吡啶类、呋喃类、吡嗪类、吲哚类以及少量芳香族化合物。有氧热裂解产物的香韵分析结果表明1-L-谷氨酸-1-脱氧-D-果糖裂解产物具有烘烤香、坚果香、甜香、花香、奶香等香韵。
简介:Thelight-harvestingchlorophylla/b-proteincomplexplaysanimportantroleinphotosynthesisofplants.Afull-lengthcDNAoflight-harvestingchlorophylla/b(cab)genewasclonedfromthefirststrandofMoso(Phyllostachysedulis)cDNAthroughRT-PCRandRACEmethods,namedascab-PhE10(cabgene10fromPh.edulis).Thelengthofcab-PhE10(GenBankaccessionnumber:EU118754)is1151bp,whichcontainsanopenreadingframeencoding283aminoacidsfrom81stto932ndposition.Thebioinformaticsanalysisindicatedthattheproteinencodedbycab-PhE10hadachlorophlla/bbindingdomain(83rd-247thposition),twoproteinkinaseC-phosphorylationsites,threeN-myristoylationsitesandayiaA/Bdoublehelixdomain.Theaminoacidsequenceofcab-PhE10showedhighsimilaritywiththecabgenesofOryzasativa,Zeamays,Hordeumvulgare,andVitisvinifera,morethan80%,respectively,whichindicatedthatcab-PhE10genebelongstolhcb5genefamily.
简介:ThispaperhighlightstheresearchanddevelopmentactivitiesbeingdoneonurbanforestryinthePhilippines.TherolethatR&Dplaysinurbanforestryislikewisediscussedintheintroduction.Recommendedtreespeciesforurbanplantingarepresentedincludingtheircharacteristicsanddistribution.Researchesrelatedtourbanforestrybeingconductedarelistedwithashortdescriptionofeachproject.Developmentactivitiesonurbanforestryarelikewisediscussed.Finally,recommendedR&DagendaandresearchableareasbasedonthePhilippineAgenda21andtheDepartmentofEnvironmentandNaturalResources(DENR)R&DFrameworkarepresented.
简介:XixiaCountyissituatedinthesouthwestborderareaofHenanProvinceandtheuppervaleyoftheDanjiangRiverwiththeFuniushanMountaintothes...
简介:到怀有基因Pi-d2从pCB6.3kb,pCB5.3kb和pZH01-2.72kb的三不同表示向量转变了的米饭强风抵抗的转基因的米饭线的米饭强风的抵抗被分析。有Pi-d2基因的九根先进产生的转基因的米饭线显示了各种各样的抵抗到39米饭强风紧张,并且最高疾病抵抗的频率到达了91.7%。有Pi-d2基因的四根早产生的同型结合的转基因的线展出了抵抗到58米饭强风紧张中的超过81.5%个,显示出宽光谱的抵抗的特征。当在文化媒介的粗略的毒素的集中增加了,米饭强风真菌的粗略的毒素选择的转基因的胚胎的calli证明从转基因的米饭植物的不成熟的胚胎的胼胝正式就职率减少了。当粗略的毒素的集中到达了40%时,从转基因的线的不成熟的胚胎的胼胝正式就职率是49.3%,并且受体控制的是5%。在正式就职下面的地里的转基因的大米线的颈强风的疾病发生是0%~50%,显示转基因的大米线的大米强风抵抗比受体控制的高得多。
简介:Background:Monitoringforesthealthandbiomassforchangesovertimeintheglobalenvironmentrequirestheprovisionofcontinuoussatelliteimages.However,opticalimagesoflandsurfacesaregenerallycontaminatedwhencloudsarepresentorrainoccurs.Methods:Toestimatetheactualreflectanceoflandsurfacesmaskedbycloudsandpotentialrain,3DsimulationsbytheRAPIDradiativetransfermodelwereproposedandconductedonaforestfarmdominatedbybirchandlarchinGenheCity,DaXing’AnLingMountaininInnerMongolia,China.Thecanopyheightmodel(CHM)fromlidardatawereusedtoextractindividualtreestructures(location,height,crownwidth).Fieldmeasurementsrelatedtreeheighttodiameterofbreastheight(DBH),lowestbranchheightandleafareaindex(LAI).SeriesofLandsatimageswereusedtoclassifytreespeciesandlandcover.MODISLAIproductswereusedtoestimatetheLAIofindividualtrees.CombiningalltheseinputvariablestodriveRAPID,high-resolutionopticalremotesensingimagesweresimulatedandvalidatedwithavailablesatelliteimages.Results:Evaluationsonspatialtexture,spectralvaluesanddirectionalreflectancewereconductedtoshowcomparableresults.Conclusions:Thestudyprovidesaproof-of-conceptapproachtolinklidarandMODISdataintheparameterizationofRAPIDmodelsforhightemporalandspatialresolutionsofimagereconstructioninforestdominatedareas.