简介:Nuclearfusionhasenormouspotentialtogreatlyaffectglobalenergyproduction.Thenext-generationtokamakITER,whichisaimedatdemonstratingthefeasibilityofenergyproductionfromfusiononacommercialscale,isunderconstruction.Wallerosion,materialtransport,andfuelretentionareknownfactorsthatshortenthelifetimeofITERduringtokamakoperationandgiverisetosafetyissues.Thesefactors,whichmustbeunderstoodandsolvedearlyintheprocessoffusionreactordesignanddevelopment,areamongthemostimportantconcernsforthecommunityofplasma-wallinteractionresearchers.Todate,lasertechniquesareamongthemostpromisingmethodsthatcansolvetheseopenITERissues,andlaser-inducedbreakdownspectroscopy(LIBS)isanidealcandidateforonlinemonitoringofthewallsofcurrentandnext-generation(suchasITER)fusiondevices.LIBSisawidelyusedtechniqueforvariousapplications.Ithasbeenconsideredrecentlyasapromisingtoolforanalyzingplasma-facingcomponentsinfusiondevicesinsitu.ThisarticlereviewstheexperimentsthathavebeenperformedbymanyresearchgroupstoassessthefeasibilityofLIBSforthispurpose.
简介:Laser-inducedbreakdownspectroscopy(LIBS)isapromisinganalyticalspectroscopytechnologybasedonspectroscopicanalysisoftheradiationemittedbylaser-producedplasma.However,forquantitativeanalysisbyLIBS,theso-calledself-absorptioneffectsonthespectrallines,whichaffectplasmacharacteristics,emissionlineshapes,calibrationcurves,etc,cannolongerbeneglected.Hence,understandinganddeterminingtheself-absorptioneffectsareofutmostimportancetoLIBSresearch.Thepurposeofthisreviewistoprovideaglobaloverviewofself-absorptioninLIBSontheissuesofexperimentalobservationsandadverseeffects,physicalmechanisms,correctionoreliminationapproaches,andutilizationsinthepastcentury.Webelievethatbetterunderstandingandeffectivesolvingtheself-absorptioneffectwillfurtherenhancethedevelopmentandmaturityofLIBS.
简介:Laser-inducedbreakdownspectroscopy(LIBS)hasbeenextensivelyappliedduetothecapabilitiesofreal-time,multi-phaseandmulti-elementanalysis.Withtheadvantages,portableLIBSisinrapiddevelopmentwithgreatpotentialoffieldmeasurements.Inthiswork,aportableLIBSwasdevelopedbya50μJlevellaserforexcitationandanobjectivelensforfocusingorimaging.Elementdetectionwassuccessfullyachievedbythissetup,andalsothemicroscopicobservationcouldbeobtainedwiththemagnificationof350×.ApreliminaryinvestigationwascarriedoutformineralrecognitionbythedevelopedportableLIBS.Theobtainedresultsindicatethattheelementdetectioncombinedwithmicroobservationwasaneffectivewayforrecognizingminerals,especiallyforsimilarmineralidentificationordiscrimination.Itissuggestedthatthemicro-joulelasercouldbealternativeforthecommercialportableLIBS,andtheon-sitemineralorrockrecognitionisapromisingfieldfortheapplication.
简介:Theaccuracyoflaser-inducedbreakdownspectroscopy(LIBS)quantitativemethodisgreatlydependentontheamountofcertifiedstandardsamplesusedfortraining.However,inpracticalapplications,onlylimitedstandardsampleswithlabeledcertifiedconcentrationsareavailable.Anovelsemi-supervisedLIBSquantitativeanalysismethodisproposed,basedonco-trainingregressionmodelwithselectionofeffectiveunlabeledsamples.Themainideaoftheproposedmethodistoobtainbetterregressionperformancebyaddingeffectiveunlabeledsamplesinsemi-supervisedlearning.First,effectiveunlabeledsamplesareselectedaccordingtothetestingsamplesbyEuclideanmetric.Twooriginalregressionmodelsbasedonleastsquaressupportvectormachinewithdifferentparametersaretrainedbythelabeledsamplesseparately,andthentheeffectiveunlabeledsamplespredictedbythetwomodelsareusedtoenlargethetrainingdatasetbasedonlabelingconfidenceestimation.Thefinalpredictionsoftheproposedmethodonthetestingsampleswillbedeterminedbyweightedcombinationsofthepredictionsoftwoupdatedregressionmodels.Chromiumconcentrationanalysisexperimentsof23certifiedstandardhigh-alloysteelsampleswerecarriedout,inwhich5sampleswithlabeledconcentrationsand11unlabeledsampleswereusedtotraintheregressionmodelsandtheremaining7sampleswereusedfortesting.Withthenumbersofeffectiveunlabeledsamplesincreasing,therootmeansquareerroroftheproposedmethodwentdownfrom1.80%to0.84%andtherelativepredictionerrorwasreducedfrom9.15%to4.04%.