简介:Byuseofmicro-DTAtechniqueaswellasambientandhightemperatureX-rayanalysisthephasediagramofNaCl-CaCl2hasbeenchecked.Itis.asimpleeutecticsystemwithasolidsolubilityinthesodiumchlorideside.Theeutecticpointisat773K,49mol%NaCl.Theexperimentalresults,especiallythoseoftheX-raydiffractionstudieshaveshowedthattheincongruentcompound4NaCl-CaCl2doesnotexistintheNaCl-CaCl2system.
简介:Thefollowingdocumentationisanevaluationofthetwo-dimensionalMadelungconstantfortheNaClstructure.TheinfiniteseriesforthestructureisformultedasThefirsttermintheformulaconvergesto41n2.TheseriesafterK=2inthesecondtermisputtogetherwiththethirdtermandaconstant-4/2isleft.ThecombinationofthethirdtermandtheseriesafterK=2inthesecondtermisassumedtobe8Sn.TheconvergingseriesSncanbesolvedonacomputer.Thesevensignificantfiguresofthetwo-dimensionalMadelungconstantfortheNaClstructureisthendeterminedas1.615558.
简介:Theadsorptionandelectronicpropertiesofisolatedcobaltphthalocyanine(CoPc)moleculeonanultrathinlayerofNaClhavebeeninvestigated.High-resolutionSTMimagesgiveadetailedpictureofthelowestunoccupiedmolecularorbital(LUMO)ofanisolatedCoPc.ItisshownthattheNaClultrathinlayerefficientlydecouplestheinteractionofthemoleculesfromtheunderneathmetalsubstrate,whichmakesitanidealsubstrateforstudyingthepropertiesofsinglemolecules.Moreover,strongdependenceoftheappearanceofthemoleculesonthesamplebiasintheregionofrelativelyhighbias(>3.1V)isascribedtotheimagepotentialstates(IPSs)ofNaCl/Cu(100),whichmayprovideuswithapossiblemethodtofabricatequantumstoragedevices.
简介:针对海水冲厕工程的实施,本实验采用序批式活性污泥反应器(SBR)处理实际含盐生活污水,考察了NaCl盐度冲击对耐盐活性污泥强化生物除磷系统(EBPR)的影响。结果表明,经过10g/L盐度长期驯化后的耐盐活性污泥可以较好的适应含盐环境,系统的磷去除率可以稳定在81.73%左右,COD去除率能够达到80.22%;聚磷菌(PAO)约占总菌的5.27%。在厌氧阶段,系统的比放磷速率会随着盐度变化幅度的加大而逐渐降低,相应的糖原降解量和PHA合成量也会逐渐减少。当冲击盐度达到335g/L时,PHA的合成量开始变化负值,此时聚磷菌的除磷作用被彻底掏,系统的耐盐极限为35g/L。在好氧阶段,升高盐度(高于10g/L)对聚磷菌的抑制作用要大于降低盐度(低于10g/L)。系统的比吸磷速率、磷去除率和COD去除率均会随头上盐度变化幅度的加大而逐渐降低,相应的PHA降解量和糖原合成量也会逐渐减少。
简介:Thecorrosionfatiguebehaviorofepoxy-coatedMg–3Al–1Znalloywasinvestigatedinairand3.5wt%NaClsolution.Epoxycoatingasanewmethodwasusedtoimprovethecorrosionfatiguepropertyofthematerial.Resultsshowthatthefatiguelimit(FL)ofthecoatedspecimensishigherthanthatoftheuncoatedspecimensin3.5wt%NaClsolutionbecauseofthestrengtheningandblockingfunctionsoftheepoxycoating.TheFLofthecoatedspecimensin3.5wt%NaClsolutionisashighasthatinair.Itimpliesthatthecoatedspecimensarenotassensitivetotheenvironmentasthemagnesiumalloy.Thelowtensilestrengthandtheshortelongationofthepureepoxycoatingleadtothatthefatiguecrackofthecoatedspecimenisalwaysinitiatedfromtheepoxy-coatingfilmPoresandpinholesacceleratethefatiguecrackinitiationprocess.PinholesarecausedbythecorrosionreactionsbetweentheepoxycoatingandtheNaClsolution.
简介:RamanpeaksofvarioushydratesintheH2O-NaCl-CaCl2systemhavebeenpreviouslyidentified,butaquantitativerelationshipbetweentheRamanpeaksandXNaCl(i.e.,NaCl/(NaCl+CaCl2))hasnotbeenestablished,mainlyduetothedifficultytofreezethesolutions.Thisproblemwassolvedbyaddingaluminapowdertothesolutionstofacilitatenucleationofcrystals.Cryogenic(-185oC)Ramanspectroscopicstudiesofalumina-spicedsolutionsindicatethatXNaClislinearlycorrelatedwiththetotalpeakareafractionofhydrohalite.Capsulesofsolutionsmadefromsilicacapillarywerepreparedtosimulatefluidinclusions.Mostoftheseartificialfluidinclusionscouldnotbetotallyfrozenevenattemperaturesaslowas-185oC,andthetotalpeakareafractionofhydrohaliteisnotcorrelatedlinearlywithXNaCl.However,thedegreeofdeviation(?XNaCl)fromthelinearcorrelationestablishedearlierisrelatedtotheamountofresidualsolution,whichisreflectedbytheratio(r)ofthebaseline"bump"area,resultingfromtheinterstitialunfrozenbrinenear3435cm-1,andthetotalhydratepeakareabetween3350and3600cm-1.Alinearcorrelationbetween?XNaClandrisestablishedtoestimateXNaClfromcryogenicRamanspectroscopicanalysisforfluidinclusions.
简介:ThemorphologyandcorrosionbehaviorofNi/Al2O3compositecoatingspreparedusingdouble-pulsedelectrodepositingtechniqueafteroxidizedunder800℃NaCldepositinairenvironmentwereanalyzedbyscanningelectricalmicroscope(SEM),X-raydiffraction(XRD)andenergydispersivespectrum(EDS).TheresultsshowedthatthecorrosionofallcompositecoatingswasacceleratedunderNaCldeposits,andthecorrosionproductswereratherporouswithpooradherencetothematrix.Al2O3particlesinthecoatingscanrefinethegrainsizeandimprovethehightemperaturecorrosionresistanceofthecoatings.Withinthetestscope,themoreAl2O3particlesinthecoatings,thelowercorrosionratescouldbeobtained,andthecorrosionmechanismwasalsodiscussed.
简介:TheelectrodeprocessofY3+iononmolybdenumandnickelelectrodeshasbeenstudiedbycyclicvoltammetryandchronopotentiometryintheYCl3-NaCl-KClmelt.Theoverallchargetransferprocessisatwo-stepreaction:Y3++e=Y2+;Y2++2e=Y.YttriumreducedonthenickelelectrodecanformaseriesofNi-Yalloys.X-raydiffractionanalysiswasemployedtodeterminethealloycompositionsformedunderdifferentcon-ditions.
简介:研究了NaCl—MnO2改性沸石填料柱对水中Zn^2+的动态吸附性能。探讨了填料厚度、Zn^2+的初始质量浓度和流速对穿透曲线的影响。结果表明,NaCl-MnO2改性沸石能有效去除水中的zn^2+,填料层增厚,穿透曲线上的穿透点向右移动,穿透时间延长;而流速、Zn^2+的初始浓度增大,穿透曲线上的穿透点向左移动,穿透时间缩短;用Thomas模型描述Zn^2+初始质量浓度为50mg/L、滤速为4mL/min时改性沸石对Zn^2+的吸附动力学,相关系数为0.9994,平衡吸附容量为12.04mg/g。
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简介:研究纯镁在1.0%NaCl中性溶液中的腐蚀行为及其相应的电化学阻抗谱(EIS)和极化曲线,探讨不同时间段EIS的分形维数。结果表明,腐蚀过程及相应的EIS发展可分为3个阶段。初始阶段,EIS由2个重叠的容抗弧组成,相应的极化电阻及电荷转移电阻随着时间的延长而快速增加,而腐蚀速率则降低。而后,EIS图谱上出现2个容易辨认的容抗弧,电荷转移电阻及腐蚀速率基本保持稳定。长时间浸泡后,EIS图谱中低频部分出现感抗成分,电荷转移电阻降低,而腐蚀速率增加。EIS分形维数与材料表面形貌直接相关,将是分析腐蚀形貌极有用的工具。