学科分类
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97 个结果
  • 简介:Inthispaper,sixkindsofactivatedcarbonssuchasAg^+-activatedcarbon,Cu^2+activatedcarbon,Fe^3+-activatedcarbon,activatedcarbon,Ba^2+-activatedcarbonandCa^2+activatedcarbonwereprepared.Themodelforestimatingactivatedenergyofdesorptionwasestablished.Temperature-programmeddesorption(TPD)experimentswereconductedtomeasuretheTPDcurvesofn-hexanolandthenestimatetheactivationenergyfordesorptionofn-hexanolontheactivatedcarbons.Resultsshowedthattheactivationenergyforthedesorptionofn-hexanolontheAg^+-activatedcarbon,theCu^2+-activatedcarbonandtheFe^3+-activatedcarbonwerehigherthanthoseofn-hexanolontheactivatedcarbon,theCa^2+-activatedcarbonandtheBa^2+-activatedcarbon.

  • 标签: 有机化合物 解吸 n-乙烷
  • 简介:Activatedcarbonfiberisonekindofimportantadsorptionmaterials.Thesenovelfibrousadsorbentshavehighspecificsurfaceareasorabundantfunctionalgroups,whichmakethemhavegreateradsorption/desorptionratesandlargeradsorptioncapacitiesthanotheradsorbents.Theycanbepreparedasbundle,paper,clothandfelttomeetvarioustechnicalrequirement.Theyalsoshowreductionproperty.Inthispaperthelatestprogressonthestudiesofthepreparationandadsorptionpropertiesofactivatedcarbonfibersisreviewed.Theapplicationofthesematerialsindrinkingwaterpurification,environmentalcontrol,resourcerecovery,chemicalindustry,andinmedicineandhealthcareisalsopresented.

  • 标签: 制备 结构 应用 活性炭纤维 吸附剂 吸附速率
  • 简介:ThedynamiccompetititveadsorptionbehaviorsofdifferentbinaryorganicvapormixturesonACF-Psunderdifferentoperationconditonswereinvestigatedbygaschromatographyinthispaper,Thestudiedmixtruesincludedbenzene/toluene,toluene/xylene,benzene/isopropylbenzeneethlyacetate/tolueneandbenzene/ethylacetate.ExperimentalresultsshowthatvariousACF-Ps,aswithACF-W,canremovebothvaporsinbinaryvapormixtureswithover99%ofremovalefficiencybeforethebreakthroughpointofthemoreweaklyadsorbedvapor,Indynamiccompetitiveadsorption,themoreweaklyweakleadsorbedvapornoeonlypenetratesearly,butalsowillbedisplacedanddesorbedconsequentlybystrongeradsorbateandthereforeproducesarollingupinthebreakthroughcurve,TheACF-Pspreparedatdifferenttemperatuershavesomewhatdifferentadsorptionselectivity,Thefeedconcentrationratioofvapros,thelength/diameterratioandthethickofbedhaveeffectoncompetitiveadsorption.Thecompetitiveadsorptionabilityofavaporismainlyrelatedtoitsboilingpoint.Usually,thehighertheboilingpoint,thestrongerthevaporadsorbedonACF-P.

  • 标签: 碳纤维 磷酸 吸附
  • 简介:StructuresofaseriesofactivatedcarbonfibersweremodifiedbyimpregnatingthemwithorganicandinorganicmaterialssuchasMethyleneblue(Mb)、p-nitrophenol(PNP)、NaClorbyoxidizingwithKMnO4orHNO3.Theinfluenceofporefillingorchemicaltreatmentontheirxenonadsorptionpropertieswasstudied.TheexperimentalresultsshowthatMbandPNPfillingofactivatedcarbonfibersresultinthedecreaseofxenonadsorptioncapacitiesofthesetreatedACFs,whichisduetothedecreaseoftheirsurfaceareaandmicro-porevolume.However,theadsorptioncapacityincreasesgreatlywithoxidizingtreatmentofactivatedcarbonfibersby7mol/LHNO3.

  • 标签: 制备 活性炭纤维 吸附性能 化学处理 核工业
  • 简介:XPS(X光检查光电子光谱学)分光计EscA-750被用来分析激活的碳,磁性的试剂和磁性的激活的碳的表面特性。他们的C原子价的分发和变化是坚定的。结论是磁性的试剂能化学上在激活的碳的表面上被吸附。在微观结构的磁性的试剂的吸附的机制的解释被讨论。

  • 标签: MAGNETIC REAGENT ACTIVATED CARBON MAGNETIC ACTIVATED
  • 简介:Theadsorptionbehaviorofdyesonavarietyofsisalbasedactivatedcarbonfibers(SACF)hasbeenstudiedinthispaper.TheresultsshowthatthiskindofACFhasexcellentadsorptioncapacitiesforsomeorganic(dye)molecules.SACFcanremovenearlyallmethyleneblue,crystalviolet,bromophenolblueandEriochromeblueblackRfromwaterafterstaticadsorptionfor24h.at30℃.Theadsorptionamountscanreachmorethan400mg/gwhenadding50mgSACFinto50mldyesolution.Underthesameconditions,theadsorptionamountsofxylenolorangefluoresceinandEriochromeblackTwreelower.Ontheotherhand,theadsorptionamountschangealongwiththecharacteristicsofadsorbents.TheSACFsactivatedabove840℃,whichhavehigherspecificsurfaceareasandwiderporeradii,havehigheradsorptionamountsforthedyes.TheresearchingresultsalsoshowthattheadsorptionratesofdyesontoSACFsdecreasebytheorderofmethyleneblue,EriochromeblueblackRandcrystalviolet.

  • 标签: 染料吸附作用 废水处理 活性碳纤维
  • 简介:Pitchbasedactivatedcarbonfiber(PACF)wasprepared,andinfluencesofpreparingconditionsuchasactivatedtemperatureandtimeontheyield.specificsurfaceareaofPACFanditsadsorptionbehaviortowardsn-butanethiolwerestudied.TheresultsshowedthatsimplePACFcouldnotremoven-butanethiolfromn-hexanesolution.Therefore,dispersionofsuitablecatalystsuchascobaltsaltonPACFisneeded,CobaltsolatdispersedPACFcanremoven-butanethiolquickly.

  • 标签: 碳纤维 硫羟 吸附
  • 简介:Threekindsofcommercialactivatedcarbons,suchasNoritRB1,MonolithandChemvironactivatedcarbons,wereusedasadsorbentsforadsorptionofdibenzofuran.Theaverageporesizeandspecificsurfaceareaoftheseactivatedcarbonsweremeasured.TemperatureProgrammedDesorption(TPD)experimentswereconductedtomeasuretheTPDcurvesofdibenzofuranontheactivatedcarbons,andthentheactivationenergyfordesorptionofdibenzofuranontheactivatedcarbonswasestimated.TheresultsshowedthattheChemvironandtheNoritRB1activatedcarbonmaintainedhigherspecificsurfaceareaandlargermicroporeporevolumeincomparisonwiththeMonolithactivatedcarbon,andtheactivationenergyforthedesorptionofdibenzofuranonthesetwoactivatedcarbonswashigherthanthatontheMonolithactivatedcarbon.Thesmallertheporeoftheactivatedcarbonwas,thehighertheactivatedenergyofdibenzofurandesorptionwas.

  • 标签: 活化能 解吸附作用 二苯并呋喃 活性碳 程序升温脱附
  • 简介:激活的污泥的机械除去由于它的高压缩的可能性是困难的,它能被electroosmosis改进。在electroosmosis,直接电场被用于污泥蛋糕。基于不同污泥床的电导率模式,一个模型在在哪个污泥,蛋糕在电路由二系列部分组成被介绍:一张除去的床和一张undewatered床。称为稳固的售票员的除去的床主要由不可移动的水和污泥粒子组成。undewatered床包括活动的水和稳固的售票员,它在电路在平行被连接。模型在污泥蛋糕与时间和电力消费把水内容的变化描述为水内容的功能,并且为除去的electroosmotic的变化解释原因率。有为在经常的电压下面除去的electroosmotic的试验性的数据的比较支持模型的有效性。

  • 标签: 除去的 electroosmotic 激活污泥传导性电力消费
  • 简介:Clusterinisa75-80kDaheterodimericglycoprotein,thatisproducedinmosttissuesbutwhichexactbiologicalroleisstillnotclear.Particularly,itsroleinprotectionorpromotionofapoptosisisheavilydisputed,sincedatasupportingbothviewshavebeenreportedinseveralindependentstudies.Toclarifythisissue,andalsotodeterminewhetherclusterinexpressionitselfmightbeaffectedbyapoptosis,inthepresentstudy,ratthymocytesweretreatedwithdexamethasone,-asyntheticglucocorticoidthatelicitsapoptosisinthymocytes-,andclusterinmRNAexpressionwasanalyzedbysemi-quantitativeRT-PCRbeforeandafterinductionofapoptosis.Interestingly,neitherthetreatmentwithdexamethasoneinvitronortriggeringofapoptosisinvivoup-regulatedclusterinexpression,opposingtheviewthatclusterinisinvolvedinapoptoticprocesses.Ontheotherhand,anewclusterinmRNAisoformwasdetectedandisolated,whoseexpressionwasrestrictedtofreshlyisolatedthymocytes.Thisnovelisoformlacksthepost-translationalproteolyticcleavagesiteandisthereforepredictedtoencodeamonomericprotein.Thebiologicalfunctionundernormalcircumstances,however,willneedfurtherinvestigationsforclarification.Whileapoptosiscouldnotmodulateclusterinexpression,activationofthymocyteswithconcanavalinAandinterleukin-2resultedinup-regulationofclusterinmRNAlevel,indicatingthatclusterinexpressionisratherunderthecontrolofcellactivation-mediatedratherthanapoptosis-inducedsignals.

  • 标签: 大鼠 致活胸腺细胞 凋亡胸腺细胞 丛生蛋白 MRNA 表达
  • 简介:ThehighalkalinitymagmatismandthcacconlpanicdorcmincralizationisconneetedwiththeMeso-zoicactivizationthatcnvelopedthelargeregionsofCentralandEastAsin.Thegeological-structural,magmatieandgeoehemicalrelationsbetweentheoremineralisationandmagmaticassociationshelptodistinguishthebigore-magmaticsrrtems(OM

  • 标签:
  • 简介:Theeffectoftheimprovementofcommercialactivatedcarbon(AC)onitsspecificcapacitanceandhighratecapabilityofdoublelayer(dl)charging/dischargingprocesshasbeenstudied.TheimprovementofACwascarriedoutviaasecondaryactivationundersteaminthepresenceofcatalystNiCl2,andthesuitableconditionwasfoundtobeaheattreatmentatabout875℃for1h.Underthoseconditions,thedischargespecificcapacitanceoftheimprovedACincreasesupto53.67F/g,showinganincreaseofabout25%ascomparedwiththatofas-receivedAC.Thegoodrectangular-shapedvoltammogramsandA.C.impedancespectraprovethatthehighratecapabilityofthecapacitormadeoftheimprovedACisenhancedsignificantly.Thecapacitanceresistance(RC)timeconstantofthecapacitorcontainingtheimprovedACis1.74s,whichismuchlowerthanthatoftheonecontainingas-receivedAC(anRCvalueof4.73s).ItisnotedthatbothkindsofACsamplesshowasimilarspecificsurfaceareaandporesizedistribution,butsomechangeshavetakenplaceinthecarbonsurfacegroups,especiallyadecreaseintheconcentrationofsurfacecarbonylgroupsaftertheimprovement,whichhavebeenverifiedbymeansofX-photoelectronspectroscopy.Accordingly,itissuggestedthatthedecreaseintheconcentrationofsurfacecarbonylgroupsfortheimprovedACisbeneficialtotheorganicelectrolyteionpenetratingintothepores,thusleadingtotheincreaseinboththespecificcapacitanceandhighratecapabilityofthesupercapacitor.

  • 标签: 活性炭 次级活化 电容性能 电偶层电容器 表面群
  • 简介:ShapeMemoryAlloy(SMA)opticallyactivatedisthekeylechnologyofopticalSMAactivator,AccordingtotheshapememorymechanismofSMA,researchesaredoneontheactivatingresponsetimeandlightwavelengthofactivatingsourceelcofSMAopticallyactivatedtoapproachtheparameterswelectionofopticalactivation,SMAhastheoptimumefficiecyintherageof13secondsto27secondswhenSMAisilluminatedcontinuslybywavelengthof675nm;ThepoweroflightwavehasaloweffectonSMA;thelongertheactivatingwavelenth,thequickertheresponsetimeofSMAactivated,Iftheproperactivatingtimeandactivatingwavelength,areadopted,andthestructuredeformationofcompositematerialofSMAimbeddedmaybeactielycontrolled,andidealeffectwillbegotten,TheresarchprovidesanevdenceforthedesignofopticalSMAactivatorandisofgreatsignificncetoitsapplication,Theresarchonsmartstructurehasawideapplicationprospect.

  • 标签: 形状记忆合金 复合材料 智能结构 自适应机构 作动器 光学激活
  • 简介:Severalkindsofactivatedcarbonfiber(ACF),GranuleActivatedcarbon(AC)containingsilverionorfinesilverparticle(Ag-ACF/AC)havebeenpreparedbysoakingACForACinthesaltsolutionofsilver.Ag,AgClandAgIcompoundshavebeenloadedontothefibers:Thestuctureofthefiberswasmeasuredbyscanningelectronmicroscopy(SEM)andpowerX-raydiffraction(XRD),THeAgcontentinthefiberwasobtainedbyanAtomicabsorptionspectroscopy(AAS),TheAg^+contentinwateraftertheantibacterialtestwasmeasuredbyanInductivelyCoupledplasma(ICP)emissionspectroscopy.AntibacterialtestwascarriedoutagainstEscherichiacoli(E.coli)andStaphylococcusaureus(S.aureus).TheresultsshowthatAg-ACF/AChavestrongantibacterialactivityagainstE.ColiandS.aureus.AfterdealtwithACF/ACloadingAg,AgCl,AgI,noE.coliandS.aureusaliveinsolutioncanbedetected.TheanalysisofAgcontentinwaterafterantibacterialtestshowedthatthecontentofAgmeetthequalityrequirementoftheNationalPotableWaterStandrd,ItisindicatedthatACF/AC-Aginthisexperimentwouldbeasafeantibacterialagent.

  • 标签: 碳纤维 含银 吸附
  • 简介:Theadsorptionisothermsoffouractivatedcarbons(NoritRB1,ChemvironBPL,Monolit,andAmbersorb-572)havebeenexaminedbynitrogenadsorptionat77.5K.Amethodforadsorptionpotentialdistributioncalculationhasbeenproposedbasedontheadsorptionisotherms.ThisdistributionprovidesinformationaboutpossiblechangesintheGibbsfreeenergycausedbytheenergeticandgeometricalheterogeneitiesofanactivatedcarbonaswellasbytheadsorbate-relatedentropiceffects.Thegeneralcharacteroftheadsorptionpotentialdistributionisclearlyvisiblebyitssimplerelationtothemicroporeandmesoporedistribution.

  • 标签: 活性碳 吸附等温线 吸附势分配 微孔结构
  • 简介:IntroductionTungsten-copperalloypowdersareusedinmanyfieldsonaccountofthehighelectricandthermalconductivitiesofcopperandhighmeltingpointoftungsten.W-Cupowders,aspreparedconventionallybymeansofinfiltration,hasthedisadvantageofinhomogeneityinmicrostructure,andaredifficulttoworkwithaftersintering.

  • 标签: 微观结构 特征 钨-铜合金粉末 活性 高能球磨 机械磨碎法