简介：Bothdirectandsensitizedirradiationsoftheendotitlecompoundleadtoadecarbony-lationproduct,4-isopropylbiphenyl,viaNorrishType1reaction,whiletheexoisomergivesacarbeneintermediateandsubsequentlyformaldehyde2-biphenylylisopropylhemiacetal,whichinturngraduallydecomposestodimethylphenylbenzylalcoholatroomtemperature.Thetripletpathwaydominatesthephotoreactionoftheexoisomer.Thesingletandtripletlifetimesofthereactantarefoundtobe0.29nsand5.4μs,respectively.~3(n,π~*),~1(n,π~*),~3(π,π~*)electronicconfigurationsoftheexoisomerand~3(π,π~*)oftheendoisomerarephotochemicallyactive,but~1(π,π~*)oftheendoisomershowsindirectphotoreactivity.
客服QQ：30444492琼网文【2021】1550-113号
增值电信业务经营许可证：琼B2-20210322
出版物经营许可证：新出发龙华出字第(2021)009号
广播电视节目制作经营许可证：(琼)字第00779号
版权所有 ©2002-2024 期刊网(www.qikanchina.com) 琼ICP备2021005105号
