学科分类
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18 个结果
  • 简介:对Escherichiacoli和克积极的葡萄球菌aureus微生物的polyaniline(PAni)的优秀抗菌剂性能在黑暗、可见的轻条件下面被表明了。在PAni分子和细菌之间的静电的坚持可以为PAni的抗菌剂反应起一个很重要的作用,由于我们的调查,进行PAni,它的composites/blends被相信作为抗菌剂代理人的一种新类型有用,为改进人的健康和生活环境的自我清洗以及多功能的材料。

  • 标签: 聚苯胺 导电聚合物 抗菌效果 大肠杆菌 生物材料
  • 简介:Polyanilinefilmwaspreparedbyelectrochemicalmethodinanacidicsolutionofaniline.Themicromorphologyofthepolyanilinefilmwastransformedtothree-dimensionalnetworkstructureinsteadoflittleparticleswhilethedepositiontimewasextended.Thepeakwavelengthofthephotoluminescencespectrumwas491nm.Theluminousintensityincreasedwiththeextensionofdepositiontime,andsodidtheelectrochemicalactivity.

  • 标签: 聚苯胺膜 电沉积 表征 三维网络结构 沉积时间 电化学方法
  • 简介:Afreestandingfilmofpolyanilineaslargeas18cm×18cm×0.002cmcanbeobtainedbyevaporationofasolutionofthechemicallysynthesizedbaseinNMP.Itsstructurewasexaminedbytheelementalanalysis,IR,U.V.-visiblespectra,XPS,DSC,SEMandX-rayscatteringanditsconductingbehavioraswellaselectrochemicalpropertieswerestudied.Resultsshowthatthecomposition,structureofmainchain,physicalpropertiesofthefreestandingfilmofpolyanilmeissimilartothatofthepowder.However,somedifferencesinitselectronicstructure,conductivityatroomtemperatureandpotentialofredoxcouplebetweenthefleestandingfilmandpowderareobserved,whichmaybeduetocross-linkingofthefilmofpolyaniline.

  • 标签: CONDUCTING polymers Conductivity POLYANILINE FREE-STANDING FILM
  • 简介:Thephotoelectrochemicalbehaviorofpolyaniline(PAn)filmwasstudiedinaqueouselectrolytesolutioncontainingFe(CN)63-/Fe(CN)+4-redoxcouple.ItwasfoundthatPAnfilmspossessthepropertiesofp-typesemiconducterandacathodicphotocurrentashighas700μA/cm2wasobservedwhenirradiatedunderpolychromaticlightof100mW/cm2.

  • 标签: cathodic ELECTROLYTE redox IRRADIATED irradiation DOPING
  • 简介:ThesecondaryelectronsspectruminXPScanbeusedtodeterminetheworkfunctionofpolyaniline(PANI).ItisshownthattheworkfunctionofPANIdependsontheprotonationstateandthepolymerizationmethodused.

  • 标签: POLYANILINE SECONDARY ELECTRONS SPECTRUM in XPS
  • 简介:Watersolubleconductingpolyanilinewithelectricalconductivityof10-1-10-2S/cmwaspreparedemployingdopantinducedwatersolubilitytechnology.Thewaterresistanceoftheconductingfilmwassignificantlyimprovedemployingsol-gelhybridsmethod,especiallywhentheconductivepolyanilineloadingwasbelow30wt%.Thereasonfortheimprovementisthattheconductingpolyanilinechainsareconfinedinastableinorganicnetwork.

  • 标签: 聚苯胺 溶胶-凝胶混合 无机网络 防水性 稳定性
  • 简介:Photoelectricpropertyofpolyanilinedopedwithdodecyl-benzeneincreasesobviously,whenpolyanilinedopedwithDBSAisirradiatedwithlight,Mixtureofsensitivematerialisadvantageoustotheabsorptionofpolyanilineinvisiblelightspectrum,andtheconductivityisalsoimproved.TheresultsofdielectricmeasurementsonpolyanilinedopedwithDBSAinanAl-PAn-DBSA-Alconfigurationasfunctionoffrequencyandtemperaturearereported.Thespace-chargepolarizationphenomenonisobserved.Carrierlifetimeismicrosecondmagnitudeandmobilityis(0.001-0.1)cm^2/V·s,whichareobtainedbycalculationorexperiment.Theactiveenergyisobtainedfromtherelationbetweenconductivityandtemperature.TheconductingmechanismofPAn-DBSAisanalyzed.

  • 标签: 电介质松驰 添加剂 光电功能材料 聚苯胺
  • 简介:Tosensitizepolyanilinewithdyesbyelectrochemicalpolymerization,HClO4isemployedasthedopantandoxidant,andthepolyanilinewithdiffernetsensitivepropertiesissynthesized.Theeffectofsensitizedemeraldinesaltontheabsorptionspectrumisdiscussedindetails.Themaximumconductivityofsensitizedfilmsreaches1.22S/cm,andinvestigationondyesensitizingofthepolymerrevealsthatC.I.DirectBlue71,C.I.DirectBlue84,C.I.DirectBlack19andCuPc-(COOH)4mayenhancethephotoconductivityofpolyanilinegreatly.

  • 标签: 电气化学聚合 染料 光电导性高聚物 敏化法
  • 简介:Dopedpolyanilinefilmswerepreparedwithelectrochemistrymethod.Asmallconjugatedmolecule,anthracenecarboxylicacid(2-ACA),wasusedasthedopant,consideringitselectricalactivenessduetotheconjugatedπ-π*structure.Filmmorphologyofdopedandundopedpolyanilinesampleswasinvestigated.ThecorrespondingchangesinopticalandelectricalpropertiesafterACAdopingwerediscussed.Bymeasuringandcalculatingtheirenergyleveldistribution,apromisingapplicationofpolyanilinethinfilmsasbufferlayerinoptic-electricdevicesisexpectable.

  • 标签: 聚苯胺薄膜 酸掺杂 制备 表征 共轭分子
  • 简介:ByuseoftheKeldyshnn-equilibriumGreen's-functionmethods,thethirdharmonicsusceptibilitiesoftwopolyanilinefamilies,PANI-HCl巨PANI-H3PO4,arccalculated[x^(3)(ω)≈10^-12esu].Itwasfoundthatthethirdharmonicsusceptibilityofpolyanilinestronglydependsonthedelocalizationoftheelectrons.Therefractiveindicesn(λ=589nm)ofPANI-HClandPANI-H3PO4arecalculatedbyuseofthreecommonmethods(theLorentz-Lorentztheoreticalmodel,theGladstone-DalegroupcontributionandtheVogelgroupcorrelation)basedongroupcontributionstomolarrefraction.Thecalculatenvaluesarevariedfrom1.31to1.42forPANI-HCland1.36to1.45forPANI-H3PO4.

  • 标签: 非线性光敏感性 折射率 电子偏移 聚合物
  • 简介:Asimpleroutetosynthesizethepolyaniline(PANI)nanofiberswithdiameterabout150nmwasreported.Inthisstrategy,thePANInanofiberswerefabricatedbyelectrochemicaldepositionbyusingtwo-electrodeconfigurationin0.01Manilineand0.01MH2SO4electrolytes.Theas-preparedmaterialswerecharacterizedbyscanningelectronmicroscopy(SEM),infraredspectroscopy(FTIR),Ramanspectroscopyandthermogravimetricanalysis(TGA).TheelectrochemicalpropertiesofthePANInanofiberselectrodeassupercapacitormaterialswereinvestigated.ThePANInanofiberselectrodeshowedhighcapacitanceof485F·g-1at0.1A·g-1,andthedecreaseinthespecificcapacitanceisabout3.5%in1000cycles.TheresultsindicatethatthePANInanofiberselectrodeshowshighstabilityandretainsitselectrochemicalcapacitancepropertyover1000cycles,suggestingPANInanofibershavepromisingapplicationsinhigh-performancesupercapacitors.

  • 标签: POLYANILINE NANOFIBERS NANOSTRUCTURED ELECTRODES electrochemical capacitors
  • 简介:Electroactiveconductingcopolymersofaniline(ANI)anddiphenylamine(DPA)arepreparedonindiumtinoxide(ITO)surfacefrom1mol/LH2SO4aqueoussolutionwithdifferentfeedratiosofANItoDPAbyusingapotentiostaticmethod.FTIRspectraandSEMmeasurementsareusedtoconfirmtheformationofcopolymers.DuetothecombinationoftheN,N′-diphenylbenzidineandanilineunitsinthemolecularchain,thecopolymerfilmsexhibitimprovedelectrochemicalandelectrochromicproperties,comparedtoPANIandPDPA.Thecopolymer[markedasP(ANI9-co-DPA1)]filmpreparedataratioof9:1(ANI/DPA)exhibitsnoveltransmittancemodulationbothinvisibleandnear-infrared(NIR)regionbetween-0.8Vand0.8V(52%and67%respectively)andfastresponsetime(3.6sforcolorationand2.3sforbleachingat600nm).Anelectrochromicdevice(ECD)basedonP(ANI9-co-DPA1)andPEDOT:PSSisalsofabricatedandshowsamulticolorelectrochromicperformance,withagoodopticalcontrast(29%invisibleregionand40%inNIRregion),acceptableresponsetime(8.3sforcolorationand7.5sforbleachingat600nm)andlong-termstability.Clearcolorchangesfromtransparent(-0.8V),brightgreen(0V),seagreen(0.4V)todarkslategray(0.8V)aredemonstrated.

  • 标签: 电致变色器件 苯胺衍生物 近红外区 多色 电致变色性能 共聚物膜
  • 简介:ElectrochemicalBettednotonlycanobtaintheconductingfilmofpolyanilineonaglasscarbonelectrode,butalsocanimobilizePMo12O403-inthefilmtoformaorganicconductingfilmelectrodemodifiedbyheteropolyanion.ThepaperherereportselectrochemicalchangesinthepreparationofPMo12O403--polyanilinemodifiedelectrode,theelectrochemicalreactionmechanismofthemodifiedelectrodewasobtainedfromthestudyonitsredoxproperties.Moreover,theaboveelectrodeshowedmarkedelectrocatalysisforthereductionreactionofCIO?-.

  • 标签: CONDUCTING electr redox MARKED ANILINE contin
  • 简介:Ionimplantationmayfavorablymodifythepropertiesofpolyaniline/Siheterojunctionsolarcellsfabricatedbytheelectrochemicalmethod.Influencesoftheimplantationontheabsorptionspectrumandthethermalstabilitywerediscussedandoutputpropertiesweremeasured.Theresultsshowthattheabsorptionspectrumofthepolyanilinefilmsmodifiedbyionimplantationismuchwider;itspyrolytictemperatureincreasesby40℃,andthepolyaniline/Sicellefficiencyincreases18and3timesundertheilluminationof10.92and37.2W/m2,respectively.

  • 标签: 离子注入 异质结太阳电池 SI 性能
  • 简介:Polyaniline(平底锅)敏化nanocrystallineTiO2composites(TiO2/PAn)成功地被准备并且为染料甲又蓝色(MB)的降级用作有效光催化剂。结果证明那个平底锅能高效地敏化TiO2,合成光催化剂能被两个都吸收紫外、可见的光激活(λ:190800nm),而纯TiO2仅仅吸收了紫外光(λ<380nm)。在自然的光的照耀下面,MB能比在TiO2上在TiO2/PAncomposites上更高效地被降级。而且,它能被简单沉积容易与答案分开。

  • 标签: 聚苯胺 亚甲基 老化 自然光
  • 简介:Flyashfloatingbead(FAFB)wasmodifiedbythenonionicsurfactantpolyethyleneglycol(PEG)undervariousconcentrationstoimproveitshydrophobility,andthenPEGmodifiedFAFBcompositedwithpolyaniline(FAFB-PEG/PAn)byemulsionpolymerizationmethodusingdifferentfeedratiosofFAFBPEG.Thechemicalstructure,phasestructure,microstructure,conductivity,anddielectricpropertieswerestudiedbyFT-IR,XRD,SEM,four-probetechnique,andLCRdigitalbridge,respectively.ItwasdemonstratedthattheoptimalconcentrationofPEGwas1mol/Landthecorrespondinggraftingratiowas1.42%.ThephasestructureofFAFBwasnotdestroyedaftermodificationbyPEG,whilethesurfacebecamesmootherandcouldbecoatedbyPAnsuccessfullyaccordingtoSEMtechnique.ComparedtothatofdodecylbenzenesulfonicaciddopedPAn(PAn-DBSA),theconductivityofFAFB-PEG/PAnwasdecreasedby10-100timesafterintroductionofvariousamountsofFAFB-PEG,especiallythevaluecouldbedecreasedto0.01Scm~(-1)if50wt%ofFAFBPEGwasprovided.Additionally,thedielectricconstantandlossfactorofFAFB-PEG/PAncompositesgraduallydecreasedwithincreasingamountofFAFB-PEGinthefrequencyrangeof100KHz-2MHz,namely,thedielectricconstantcouldbestillkeptat500andcorrespondinglythelossfactordecreasedto4.7at100KHzif50wt%ofFAFB-PEGwasprovided.TheleakingcurrentphenomenonderivedfromPAn-DBSAcouldalsobeweakenedbyFAFB-PEG.

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  • 简介:EffectofaddedCo2+(aq)oncopperelectrowinningwasstudiedusingdopedpolyaniline(Pani)andPb-Ag(1%)anodesandastainlesssteelcathode.ThepresenceofaddedCo2+(aq)intheelectrolytesolutionwasfoundtodecreasetheanodepotentials.TheoptimumlevelofCo2+(aq)concentrationintheelectrolyte,withrespecttothemaximumsavingofpowerconsumptionwasestablished.Linearsweepvoltammetry(LSV)wasusedtostudytheinfluenceofaddedCo2+(aq)ontheanodicprocessesinacoppersulfate-sulfuricacidelectrolyte.Theoxygen-evolutionpotentialforPanianodeisdepolarisedatlowercurrentdensities(≤0.01A/cm2)andattainssaturationatρ(Co2+)o≈0.789g/L;whilsttheoxygen-evolutionpotentialforPb-Ag(1%)anodeisdepolarisedathighercurrentdensities(≤0.02A/cm2)andattainssaturationatρ(Co2+)o≈1.315g/L.Thepreferredorientationsofthecopperdepositschangefrom(220)to(111)withtheadditionof0.394?0.789g/LCo2+buthigherconcentrationsfavor(220)orientationagain.

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