简介:IncorporationofstrontiumintoV-Moalumina-supportedcatalystenhanceditsperformance(increasedconversionandselectivity,decreasedreducibilityandimprovedstability)inpropaneoxydehydrogenationtopropylene.12.5%SrloadingwasshowntobetheoptimumcontenttotheV-Mocatalyst.Theresultsweresupportedbyvariouscharacterizationtechniques,namely,BET,XRD,SEM,FTIRandTPD.
简介:ItiswellknownthatthephotocatalyticactivityofTiO2thinfilmsstronglydependsonthepreparingmethodsandpost-treatmentconditions,sincetheyhaveadecisiveinfluenceonthechemicalandphysicalpropertiesofTiO2thinfilms.Therefore,itisnecessarytoelucidatetheinfluenceofthepreparationprocessandpost-treatmentconditionsonthephotocatalyticactivityandsurfacemicrostructuresofthefilms.ThisreviewdealswiththepreparationofTiO2thinfilmphotocatalystsbywet-chemicalmethods(suchassol-gel,reversemicellarandliquidphasedeposition)andthecomparisonofvariouspreparationmethodsaswellastheiradvantageanddisadvantage.Furthermore,itisdiscussedthattheadvancementofphotocatalyticactivity,super-hydrophilicityandbactericidalactivityofTiO2thinfilmphotocatalystinrecentyears.
简介:TiO2/Au/TiO2多层的薄电影用dc(直接水流)在房间温度在聚合物底层被扔磁控管劈啪作响方法。由改变每层的厚度,TiO2/Au/TiO2多层的电影的光、电的性质能被定制适合不同应用。厚度和Au层的光性质和Au绝缘的接口的质量为Au绝缘的多层的薄电影的电、光的表演是批评的。在8nm的厚度,Au层形成有最低抵抗力和它的连续结构一定为高发射度薄。多层的栈能被优化有6的一个表电阻?在在在波长的680nm的超过80%的发射度的/sq.。当时,山峰发射度向长波长区域变二TiO2的厚度(上面、更低)层增加。当二部TiO2电影的电影厚度是45nm时,高发射度价值为全部可见轻波长区域被获得。
简介:TiO_2isapromisingphotocatalyst.However,thelowphotocatalyticefficiencycallsforthemodificationofTiO_2.Metal-andnonmetal-dopingofTiO_2havebeenprovedtobeeffectivewaystoenhancephotocatalyticproperties.Thisreviewprovidesadeepinsightintotheunderstandingofthemetal-andnonmetal-dopedTiO_2photocatalysts.ThisarticlebeginswiththeintroductionofthecrystalstructuresofTiO_2andapplicationsofTiO_2materials.Wethenreviewedthedoped-TiO_2systemintwocategories:(1)metal-dopedTiO_2photocatalystssystem,and(2)nonmetal-dopedTiO_2photocatalystssystem.Bothexperimentalresultsandtheoreticalanalysesareelaboratedinthissection.Inthefollowingpart,fortheadvantagesofTiO_2thinfilmsoverparticles,variouspreparationmethodstoobtainTiO_2thinfilmsarebrieflydiscussed.Finally,thisreviewendswithaconciseconclusionandoutlookofnewtrendsinthedevelopmentofTiO_2-basedphotocatalysts.
简介:TheinfluenceofcalcinationtemperatureonTiO2nanotubes’catalysisforTiO2/UV/O3wasinvestigated.TiO2nanotubes(TNTs)werepreparedviathesol-gelmethodandcalcinedat300—700℃,whichwerelabeledasTNTs-300,TNTs-400,TNTs-500,TNTs-600andTNTs-700,respectively.TNTswerecharacterizedbytransmissionelectronmicroscopy(TEM)andX-raydiffraction(XRD).ItisfoundthatTNTscalcinedat400℃showedthebestthermalstability.Whenthecalcinationtemperatureincreasedfrom400℃to700℃,thespecialstructureoftubeswasdestroyedandgraduallyconvertedintonanorodsand/orparticles.Thetransformationfromanatasetorutileoccurredat600℃,andtherutilephasewasenhancedwhenthecalcinationtemperaturewasincreasedtoover600℃.Thecalcinationtemperature’sinfluenceonTNTs’adsorptionactivityforchemicaloxygendemand(COD)andcatalyticactivityforTiO2/UV/O3wasinvestigatedinlandfillleachatesolution.Inlandfillleachatesolution,theadsorptionactivityofCODdecreasedinthereducedorderofTNTs-300,TNTs-400,TNTs-500,TNTs-600andTNTs-700.Inphotocatalyticozonation,TNTs-400showedthebestcatalyticactivitywhileTNTs-700exhibitedtheworst.Inotherthreeprocesses,theCODremovalofTNTs-300/UV/O3washigherthanthoseofTNTs-500/UV/O3andTNTs-600/UV/O3inthefirst20min,andthenbecameclosetothoseofthelattertwointhefollowing40min.ComparedwithTNTs-300andTNTs-400,TNTs-600hadthebestanti-foulingactivity,whileTNTs-500andTNTs-700hadloweranti-foulingactivitythantheformerthree.Inphotocatalyticozonation,thecalcinationtemperatureof400℃wasappropriatewhenTNTswereobtainedatthesynthesistemperatureof105℃.
简介:ThephotodegradationreactionrateofCHCl3inTiO2particulatesuspensionwasimperovedsignificantlybyHCl-treatment.TheeffectofHCl-treatmentonthephotocatalyticactivityofTiO2wasstrdiedinaPECcellbyusingIntensity-ModulatedPhotocurrentSpectroscopy(IMPS).ThemagntudeofphotocurrentresponseandthecharacteristicfrequenciesoftheupperandlowersemicirclesinthecomplexplaneofIMPSresponsewereanalyzed,andtheccathodicandanodicreactionprocessesofphotogeneratedholesandelectronswerediscussed.Theincreasesinthecathodicandanodicphotocurrentresponseandinthetimeconstantsofbothcathodicandanodicreactionprocessesofphotogeneratedholesandelectronswerediscussed.TheincreasesinthecathodicandanodicphotocurrentresponseandinthetimeconstantsofbothcathodicandanodicreactionprocessesindicatethatHCl-treatmentleadstotheimprovementofthephotocatalyticactivityofTiO2andachangeofthephotocatalytickineticmechanism.
简介:HomogeneousNi2+-dopedtitaniagelwassynthesizedbyasol-gelprocess,andthexerogelwasthenobtainedthroughaginganddrying,leadingtotheformationofNi/TiO2nanocompositeafterheattreatmentunderasuitablereducingatmosphere.TheresultingnanocompositewascharacterizedbyTGA-DSC,TEM,XRDandBETmethods.Theresultsshowthatthestructureandgrainsizeofthenanocompositescouldbemanipulatedbyalteringtheheat-treatmentconditions,andthatthenanocompositepossessesamesoporousstructurewithaporeradiusofca.28nmandaspecifictheanatase-rutilephasetransformation.
简介:hePhotocatalyticcharacterizationofTiO2supportedonactivecarbonwasinvestigatedforphotocatalyticdecompositionofdichloroaceticacid.ItwasfoundthatTiO2/ACexhibitedahigherphotocatalyticactivitythanpureTiO2.ThereasonisthatactivecarbonactingaspowerfuladsorbentsupportsmakeshighconcentrationenvironmentsoforganicpollutantmoleculesaroundTiO2particles.
简介:TiO2filmswereformedonmetallictitaniumsubstratesbytheanodicoxidationmethodinH2SO4solutionunderthe80VD.C..PhasecomponentandmicrostructurewerecharacterizedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Watercontactanglesontitaniumoxidefilmsurfaceweremeasuredunderbothdarkandsunlightilluminationconditions.Corrosiontestswerecarriedoutinseawaterunderdifferentilluminationconditionsbyelectrochemistryimpedancespectrum(EIS)andpolarizationcurves.TheresultshowedthattheTiO2filmpreparedbytheanodicoxidationmethodwasanatasewithauniformstructureandwithoutobviousporesorcracksonitssurface.Theaveragewatercontactangleofthefilmwas116.4?indark,incontrasttoanangleof42.7?undertheUVilluminationfor2hours,whichdemonstratesgoodhydrophobicproperty.Theanti-corrosionbehavioroftheTiO2filmwasdecliningwiththeextendedimmersiontime.Underdarkconditions,however,thehydrophobicTiO2filmretardedthewaterinfiltratingintothesubstrate.Theimpedancechangedslowlyandthecorrosioncurrentdensitywas2ordersofmagnitudelowerthanthatwiththefilmilluminatedbysunlight.AllofthosementionedaboveindicatethattheTiO2filmpossessesmuchbetterperformanceunderdarkcondition,anditcanbeappliedasanengineeringmaterialunderdarkseawaterenvironment.
简介:在玻璃表面上扔的一部PANI/TIO_2合成电影成功地用大音阶的第五音胶化dip-coating技术和化学氧化方法被准备。这部电影用XRD被描绘,AFM,并且紫外。结果证明TiO_2电影由塑造bothcuboid、分阶段执行锐钛矿的TiO_2nanoparticles组成。在这部电影的TiO_2的平均谷物尺寸是约20nm。在有PANI的涂层以后,粒子被变成塑造irregularspherical并且尺寸在直径被增加直到约35nm。UV-Visspectroscopy分析显示有PANI的TiO_2的涂层将导致相片的改进催化效率和TiO_2的相片反应的延期。thePANI/TiO_2电影的乐队差距是3.18eV。相片这部电影的催化性质被rhodamine-B的降级评估。67.1%rhodamine-B和83.2%能作为光催化剂用PANI/TiO_2合成电影在120min以内在日光和紫外照耀下面被降级,这被发现。
简介:TiO2nanometerthinfilmswithphotocatalyticantibacterialactivitywerepreparedbythesol-gelmethodonfusedquartzandsodalimeglassprecoatedwithaSiO2layer.ThethinfilmswerecharacterizedbyX-rayphotoelectronspectroscopy(XPS),scanningelectronmicroscopy(SEM),andX-raydiffraction(XRD).TheresultsshowthatsodiumandcalciumdiffusionintonascentTiO2filmiseffectivelyretardedbytheSiO2layerpre-coatedonthesodalimeglass.Theantibacterialactivityofthefilmswasdetermined.ThecrystallineofTiO2nano-meterthinfilmhasimportanteffectsontheantibacterialactivityofthefilm.