简介:Arylhalidesareakindofextremelyvaluablecompoundsusedintransition-metal-catalyzedcouplingreactions,aswellasimportantstructuremotifsinmanynaturalproductsandmanufactureddrugs[1,2].Theclassicalapproachforpreparationofhaloarenesiselectrophilicaromaticsubstitution(EAS)usingvarioushalogenatingreagentsoroxidativehalogenationswithhalogenatingreagentgeneratedinsitufromhalidesandoxidants,suchasperoxide,oxygenandmeta-cholorperoxybenzoicacid(mCPBA)[3,4].However,harshreactionconditionsarerequiredforhalogenationoflessactivearomatics.orthoMetalationfollowedbyhalogenquenchingisanotherapproachforhalogenationofaromatics[5].However,thereareobviousdrawbacksforthesemethods,suchaslowregioselectivity,harshconditionsandevendangerousprocedures.Therefore,thedevelopmentofanalternativeandpracticalwayremainschallengeinorganicsynthesis.
简介:Tris)(η5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosylclusterwasobtainedfromthereactionofcyclopentadienyldicarbonylirondimerwithnitrogenmonoxideinxylene.Theclusterwascharacterizedbyelementalanalyses,IR,MSand1HNMR.Thecrystalstructureof[(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8OwasdeterminedbyX-raydiffractionanalysis.ItcrystallizesintheorthorhombicspacegroupPnma,a=9.053(2),6=10.545(2),c=22.525(4)A,V=2150.3(7)A3,Z=4,Dc=1.68g.cm-3;structuresolutionandrefinementbasedon1141reflectionswithI>3.0(I)(MoKa,A=0.71073A)convergedatR=0.0540.Theinfraredabsorptionbandat1325cm-1oftheμ3-NOinthecluster,whichisredshifted,showsthatμ3-NOisactivated.
简介:Toeffectivelysolvetheagglomerationproblemsinthesolidstatereactionprocess,pre-addingglucoseisadoptedtothesynthesisofLiFePO4/CenergymaterialsusingFe–Pwasteslag.Theaverageparticle&grainsizeofLiFePO4/Cdecreases,andtheimpuritiesinLiFePO4/Ccompositesreducetoagreatextent.Itmakesgreatsensetothemassindustrialproduction.Theoptimumsynthesisconditionsdeterminedinthisworkarebasedontheorthogonalexperiments.Thesamplessynthesizedinascaleof500gexhibithighpurity,excellentelectrochemicalperformance,highreactionactivity,goodreversibility,andlowpolarizationlevel.Thedischargecapacitiesare145,134,117,and102mAh/gatthecurrentdensitiesof0.1C,0.2C,0.5Cand1C,respectively.ThisworkputsforwardapracticalsuggestionformassproducingenvironmentalbenignandlowcostLiFePO4/Cascathodematerialsoflithiumionbatteries.
简介:AfacilehydrothermalmethodwasdevelopedforthepreparationofFe2O3@CnanocompositesusingFeCl3·6H2Oasironsourceandglucoseascarbonsourceunderalkalinecondition.Themorphologyandstructureoftheas-preparedproductwereidentifiedbytransmissionelectronmicroscopy(TEM),highresolutiontransmissionelectronmicroscopy(HRTEM),field-emissionscanningelectronmicroscopy(FESEM),X-raydiffraction(XRD),Ramanspectroscopy,FourierTransforminfraredspectroscopy(FTIR),andthermogravimetricanalysis(TGA).Theas-prepareα-Fe2O3@Cnanocompositeswereemployedforsupercapacitorelectrodematerial.Thesynergisticcombinationofcarbonelectricaldouble-layercapacitanceandα-Fe2O3pseudo-capacitanceestablishedsuchnanocompositesasversatileplatformforhighperformancesupercapacitors.Thesynthesismethoddevelopedhereisexpectedtoobtainothermetaloxide/carboncomposite.