简介：使用一种唯象的ＮＮ周边模型湮灭势，对１８０Ｍｅｖ的Ｐ－１２Ｃ弹性散射微分截面、极化角分布和自旋旋转参数进行了计算。结果表明，这种势模型与实验符合得较好。更多还原

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简介：若无限长均匀带电直导线（线电荷）与接地平板系统的电场是二维静电场,当求解区域可视为为多边形时,则可应用S-C映射法和电像法为统一模型,求解出线电荷在求解区域所激发的电势。

简介：为了满足我国正在建设的白光中子源（whiteneutronsource,WNS）需求,设计了具有共性化架构的C6D6谱仪读出电子学系统。该系统基于波形数字化技术和PXIe平台,实现对γ能谱和中子飞行时间的测量。介绍了系统设计方案,详细阐述了信号调理模块、时间测量、PXIe平台及相关软件的设计与实现,并开展了系统性能测试和联调实验。测量结果表明：该系统能够正确获得测量数据,满足了白光中子源的首批实验需求。

简介：Cu-Fecompositeoxideswerepreparedbyco-precipitationmethodandtestedforhigheralcoholsynthesisfromsyngas.TheselectivitytoC2+OHandC6+OHinalcoholdistributionwasveryhighwhilethemethaneproductfractioninhydrocarbondistributionwasratherlow,demonstratingapromisingpotentialinhigheralcoholssynthesisfromsyngas.ThedistributionofalcoholsandhydrocarbonsapproximatelyobeyedAnderson-Schulz-Florydistributionwithsimilarchaingrowthprobability,indicatingalcoholsandhydrocarbonsderivedfromthesameintermediates.TheeffectsofCu/Femolarratio,reactiontemperatureandgashourlyspacevelocity(GHSV)oncatalyticperformancewerestudiedindetail.ThesamplewithaCu/Femolarratioof10/1exhibitedthebestcatalyticperformance.Higherreactiontemperatureacceleratedwater-gas-shiftreactionandledtolowertotalalcoholsselectivity.GHSVshowedgreateffectoncatalyticperformanceandhigherGHSVincreasedthetotalalcoholselectivity,indicatingthereexistedvisibledehydrationreactionofalcoholintohydrocarbon.

简介：Theroleofpulseparametersonnanoparticlepropertyisinvestigatedself-consistentlybasedonacoupleoffluidmodelandaerosoldynamicsmodelinacapacitivelycoupledparallel-plateacetylene(C2H2)discharge.Inthismodel,themasscontinuityequation,momentumbalanceequation,andenergybalanceequationforneutralgasaretakenintoaccount.Thus,thethermophoreticforceariseswhenagastemperaturegradientexists.Thetypicalresultsofthismodelarepositiveandnegativeiondensities,electronimpactcollisionsrates,nanoparticledensity,andchargedistributions.Thesimulationisperformedfordutyratio0.4/0.7/1.0,aswellaspulsemodulationfrequencyfrom40kHzto2.7MHzforpureC2H2dischargesatapressureof500mTorr.Wefindthatthepulseparameters,especiallythedutyratio,haveagreataffectonthedissociativeattachmentcoefficientandthenegativedensity.Moreimportantly,bydecreasingthedutyratio,nanoparticlesstarttodiffusetothewall.Undertheactionofgasflow,nanoparticledensitypeakiscreatedinfrontofthepulseelectrode,wherethegastemperatureissmaller.

简介：PolysaccharidecoatedPLAnanoparticlesbearingaldehydegroupswerepreparedbydialysisofDMSOsolutionofcholesterolhydrophobic-modifieddextranpolyaldehydeandPLAagainstwater.Theaveragediameterofthenanoparticleswasabout160nm,andthesizedistributionwasnearlyhomogenous.ThenanoparticleswerefunctionalizedsimultaneouslywithCD71andEGFRantibodythroughtheSchiff'sbasereaction,andthenradiolabeledwith~(99m)Tc.Afterperfusedtheradiolabelednanoparticlesintotumor-bearing...

简介：在CCSD(T)/6-311G(d,p)∥B3LYP/6-311G(d,p)水平上给出了反应C2H3+NO2的详细势能面信息,并列出了中间体和过渡态的几何构型.通过深入分析反应路径及反应机理,得到5个能量可行的产物和6条反应通道,其中产物C2H3O+NO的形成更有利,而产物CH2CO+HNO则是次要产物,其他产物在通常条件下可以忽略.

简介：Amodelstudyleadingtothepreparationoftheuniquetricyclo[6.2.1.0]undecaneBCDringsystemsofaconitineisdescribed.Thesynthesisfeaturesanunprecedenteddiastereoselectiveoxidativedearomatization/dimerization/retro-DA/IMDAcascadereactionandahighlyefficientWagner-Meerweinrearrangement.

简介：双音多频DTMF(DualToneMulti—Frequency)信号是音频电话中的拔号信号，将DTMF信号的检测集成到含有数字信号处理器(DSP)的系统中，是一项较有价值的实际课题．本文给出在TI公司浮点DSP芯片C6711中的实现方案，通过20个并行的哥兹柔信号滤波器成成功地使双音多频信号检测变得准确、迅速和简单。

简介：ＹｉｅｌｄｏｆＴｒａｎｓｔａｒｇｅｔＰｒｏｄｕｃｔｓｆｒｏｍＩｎｔｅｒａｃｔｉｏｎｏｆ４７ＭｅＶ／ｕ１２ＣＩｏｎｓｗｉｔｈＣｓＴａｒｇｅｔｓ￥ＬｉＺｏｎｇｗｅｉ；ＹａｎｇＷｅｉｆａｎ；ＺｈａｏＺｈｉｚｈｅｎｇａｎｄＭｕＷ?..

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简介：Tomeettherequirementsofelectronicvehicles(EVs)andhybridelectricvehicles(HEVs),thehighenergydensityLiNi0.8Co0.15Al0.05O2(NCA)cathodeandSi–Canodehaveattractedmoreattention.HerewereportthethermalbehaviorsofNCA/Si–Cpouchcellduringthecharge/dischargeprocessesatdifferentcurrentdensities.ThetotalheatgenerationsarederivedfromthesurfacetemperaturechangeduringelectrochemicalLi+insertion/extractioninadiabaticsurrounding.Thereversibleheatisdeterminedbytheentropiccoefficients,whicharerelatedwithopen-circuitvoltageatdifferenttemperatures;whiletheirreversibleheatisdeterminedbytheinternalresistance,whichcanbeobtainedviaV–Icharacteristic,electrochemicalimpedancespectroscopyandhybridpulsepowercharacterization(HPPC).Duringtheelectrochemicalprocess,thereversibleheatcontributeslessthan10%tototalheatgeneration;andtheheatgeneratedinchargeprocessislessthanthatindischargeprocess.Theresultsofthermalbehaviorsanalysesareconducivetounderstandingthesafetymanagementandpavingthewayforbuildingareliablethermalmodelofhighenergydensitylithiumionbattery.

简介：有N-(2-propionic酸)的新奇金轧(III)建筑群-salicyloylhydrazone(C10H10N2O4，H3L)并且1,10-phenanthroline(C12H8N2，phen)被准备并且描绘。水晶结构[Gd(H2L)(HL)-(H2O)3]2潲楰湯捩???慳楬祣潬汹?票牤穡湯??ㄠ??桰湥湡桴潲楬敮???????楢慯瑣癩瑩？

简介：为验证CO_2探测仪光学设计的合理性和可行性，采用单通道模拟样机，利用太阳光加漫反射板模式对大气光谱进行实验测试，并在实验室对单通道模拟样机进行光谱定标。利用光谱配准算法对两种方法得出的谱线位置进行匹配计算，结果表明：在吸收线深度稳定位置的配准峰值点偏差小于0．006nm，满足算法的精度要求。此种方法不仅验证了匹配算法的有效性，也验证了光学系统设计的合理性和可行性，为以后的光谱仪设计提供了理论与实验数据。

简介：本文导出了二次多项式保凸的充要条件，通过插值部分新节点，得到了一种新的保凸Ｃ＾１分段二镒多项式插值函数。

简介：ThreeC2-symmetric(10R,11R)-diethylsubstituteddibenzosuberane(DBS)-basedheliceneswithvaryingstericandconjugationdemandsoftheirbottomfragmentsweresynthesized.Onlythehelicene-7a[withthebottompartderivedfromtetralonewasfoundphoto-switchableinreasonabletimescale.Photoisomerizationofthediastereomericallypure(10R,11R,P)-helicene(7a)at280nmledtovirtuallyexclusiveformationoftheoppositeMform-diastereomer7a′(7a′/7a=99.6/0.4).Thepreferentialreturnof7a′to7acanbeeffecteduponirradiationat254nm(7a′/7a=3G/67)orthermallyat1307a′/7a=0/100).Thephoto-inducedswitchingprocessamountstoa133%differenceind.e.(from99.2%to-34%).TheconcomitantchangeofhelicenechiralitybetweenthesetwodiastereomericphotostationarystatesaugurswellfortheirpotentialapplicationasanopticalswitchinLCmaterials.Toourknowledge,oursystemservesasthebestchirochromicopticalswitchascomparedtotheexamplespossessingsimilarphotochromicproperties.

简介：TheBrenner-LJpotentialisadoptedtodescribetheinteractionbetweenC36clustersanddiamondsurface,andthedepositionmechanismofmulti-C36clustersonthediamondsurfaceisalsostudiedbyusingthemethodofmoleculardynamicssimulation.Thesimulationresultsshowthatthecompetitioneffectsoftwointeractions,i.e.theinteractionbetweenclusterandclusterandtheinteractionbetweenclusterandcrystalplane,arestudied,andthentheinfluenceofthesecompetitioneffectsonC36clusterdepositionisanalysed.Thefindingisthatwhenanincidentenergyisappropriatelychosen,C36clusterscanbechemicallyadsorbedanddepositedsteadilyonthediamondsurfaceintheformofsingle-layer,andinthedepositionprocessthemulti-C36clusterspresentaphenomenonofenergytransmission.Theexperimentalresultshowsthatatatemperatureof300K,inordertodepositC36clustersintoasteadynano-structuredsingle-layeredfilm,theoptimalincidentenergyisbetween10and18eV,iftheincidentenergyislargerthan18eV,theC36clusterswillbedepositedintoanislandnano-structuredfilm.

简介：Linearpolysiloxaneswithpendantbenzo-15-crown-5moietieshavebeensynthesizedfrom3′-or4′-allylbenzo-15-C-5viahydrosilylationofmethyldichlorosilane,followedbypolycondensationwithsilanol-terminatedpolydimethylsiloxane.Itwasfoundthatthepolysiloxanescouldbeusedascarriersinbulkliquidmembranetotransportions.Factorsinfluencingtransportratehavebeeninvestigated.

简介：Ourobjectivesweretodevelopanewchemicalmethodforthepolymerizationofpyrrole.CuCl2dissolvedinC2H5OHsolventisprimarilyusedfortheinitiationpolymerizationofpyrrole.ThepolymerswithdifferentyieldandconductivitywereobtainedbyraringtheinitialconcentrationofCu2+.TheinitialconcentrationsofCu2+variedfrom1.2×10-4moleto6.48×10-3moleCu2+with2.16×10-2molepyrrole.Thepolypyrroleobtainedwascharacterizedwithelementalanalyzer,XPS,IRspectroscopy,Four-pointprobeandSEM.