简介:
简介:Sm3+dopedsodalimesilicateglassesco-dopedwithAs2O3werepreparedandcharacterisedbymeasuringtheirabsorptionspectrainUV-VIS/NIRregionsandluminescencespectrainthevisibleregion.Judd-Ofeltintensityparameters,Ωλ,wereevaluatedfromthemeasuredintensifiesofthevariousabsorptionbands.ΩλparametersoftheseglasseswerecomparedwiththeΩλparametersofotherreportedSm3+glassestostudythebondingenvironmentsurroundingtheSm3+inthepresentglasses.Presenceof[AsO4]3-tetrahedrainthesecondcoordinationspherearoundthecentralSm3+ionmadetheseglasseslesscovalentascomparedtootheroxideglassesbuttheratioΩ4/Ω6ofthe~1.83indicatedthemtobefairlystable.WiththehelpofΩλparametersandluminescencedataforvariousemissionlines,radiativepropertiesfordifferentemissionlineswerecalculated.Thevaluesofradiativepropertiesindicatedthat4G5/2→6H7/2and4G5/2→6H9/2transitionsresponsiblefororangeluminescencemightbeusedinthedevelopmentofmaterialsforLED'sandotheropticaldevicesinthevisibleregion.
简介:分光镜并且在钠fluoroborate(SFB)的Nd3+离子的荧光性质眼镜通过光吸收,排放和腐烂大小被准备并且描绘。精力水平分析用免费离子的Hamiltonian模型被执行。试验性的振荡器力量被测量记录的吸收山峰包含的区域决定因为1.0mol.%Nd3+-做了眼镜。Judd-Ofelt参数(2,4,6)被用来评估象放射的转变那样的激光特征参数概率(AR),放射的腐烂时间(R),荧光分叉比率(R)和刺激排放为4F3/2的剖面图(e)亚稳的状态。为Nd3+离子的不同集中的荧光系列被在514.5nmAr+离子激光使样品激动记录。
简介:AnenhancedadsorptionanddesorptionprocedureofNd(III)ontoD113-IIIresinwerepreparedwithvariouschemicalmethods.BatchstudieswerecarriedoutwithvariouspH,contacttime,temperatureandinitialconcentrations,andthencolumnstudieswereconducted.TheresultsshowedthattheoptimaladsorptionconditionwasatpHvalueof6.90.Theprocesswasfastinitiallyandarrivedequilibriumwithin60h.TheresinexhibitedahighNd(III)uptakeas232.56mg/gat298K.Theadsorptiondatafittedwellwithpseudo-second-orderkineticmodel.Thermodynamicparameterswerestudied,whichindicatedthattheadsorptionprocesswasspontaneousandendothermic.Thomasmodelwasdelineatedheretopredictthebreakthroughcurvesbasedontheexperimentalcolumnstudydata.Intheelutiontest,1mol/LHClsolutioncouldachieveasatisfactoryelutionrate,whichindicatedthatD113-IIIresincouldberegeneratedandreused.Finally,theIRspectroscopictechniquewasundertaken,andanoveladsorptionmechanismwasproposed.
简介:ThemeasurementsoftemperaturedependenceofthemagneticsusceptibilityofLa1-xSrxCoO3perovskiteoxidesatdifferentSrdoping(0≤x≤0.5)andannealingtemperaturewerepresented.Forthesamplewithx=0.1,ashoulderwasobservedaround150K,andapeakwhichisonefeatureofspinglassappearedaround50Kinthecurveofsusceptibilityversustemperature.Thehigh-temperature(250~420K)susceptibilityfitswellwithCurie-Weisslawforallsamples.WeissconstantandeffectivemagneticmomentweredeterminedandtheirvariationswithSrdopingandoxygenannealingconditionwereobtained.TheWeissconstantincreasesmonotonouslywithSrcontentforx>0.2.Thevaluesofeffectivemomentswereinterpretedwiththespinstateofcobaltions.Studiesonthesusceptibilitiesofthesampleswithx=0.2underdifferentpreparationtemperaturesandannealingtemperaturesshowthattherisingofsinteringtemperatureandannealingtemperaturewillincreasethepara-ferromagnetictransitiontemperature,andreducetheeffectivemomenttonormalvalue.OurresultshowsthatbothCo3+andCo4+ionsshouldbeinISstateafterannealingandtheoxygenannealingcausesthetransitionofCo3+spinstatefromHStoIS.
简介:VariousopticalluminescencespectroscopictechniqueswereusedtocharacterizethehighTcsuperconductorYBa2Cu3Ox.TheemissionbandsrevealthatCu3+coexistwithCu2+andCu+inthismaterial.
简介:BondedtypeRE3+dopedluminescentco-polymerwassynthesizedbysolutionfreeradicalcopolymerization.Theinfluenceofchargesequence,monomersandco-polymerizedmethodonpropertiesandstructuresoftheco-polymerswasstudied.Theemissionintensityoftheco-polymersatdifferentRE3+concentrationswastested.Theresultsshowedthattheco-polymersofEu-PStandEu-PMMAbothhadwideabsorptionpeakat200-400nmandthestrongestpeakappearedat235nm.ThefluorescentintensityofEu3+dopedpolystyreneco-polymerwasstrongerthanthatofEu3+dopedPMMAcopolymer.Thecharacteristicemissionofeuropiumionswasobservedintheco-polymers.Thecopolymerdopedwithrareearthelementsshowedthe"sensitizationeffect"forthecentralions.Thebonded-typerareearthcopolymernotonlyenhancedtheenergytransferefficiency,butalsoimprovedthefluorescenceintensitybyiacreasmgtherigidityofmainandsidechain.
简介:YAG:Ce3+(Yttriumaluminumgarnet)fluorescencepowdersweresuccessfullypreparedbyco-precipitationmethodusingaluminumnitrate,yttriumnitrate,cerousnitrateasthestartingmaterialsandammoniumcarbonateasprecipitant.TheproductswerecharacterizedbyX-raypowderdiffraction,luminescencespectrometer,transmissionelectronmicroscope(TEM).TheXRDresultsshowedthattheobtainedYAG:Ce3+fluorescencepowdershadthecrystallinestructuresofYAGatcalcinationstemperatureof900oCandtheTEMresultsshowedthatthegraindiameterswereabout100nm.TheYAG:Ce3+fluorescencepowders,synthesizedbyco-precipitationmethod,hadthebestluminescencepropertywhentheCedopingamountwasx=0.06inthemolecularformulaofY3-xCexAl5O12,thecalcinationstimewas2handthecalcinationstemperaturewas1000°C.