简介:一系列立方的稀土元素sesquioxidesRE2O3的拉曼系列(RE=Eu,Gd,Dy,惊讶,嗯,Tm,Yb,陆,Sc和Y)被拉曼光谱学与532和785根nm激光线调查。丰富的另外的乐队由于激光激动的光被观察。为Eu2O3,Dy2O3,Ho2O3,Er2O3,Tm2O3和Yb2O3,,光主要为Gd2O3,Lu2O3,Sc2O3和Y2O3来自内在的三价的lanthanide离子,他们的光被归因于象Eu3+,Nd3+和Er3+那样的另外的光lanthanide离子的踪迹杂质。这调查为检测踪迹作为一个有用工具证实了拉曼光谱学光lanthanide杂质。
简介:Thesynthesis,compositionoptimization,VUVPhotoluminescence(PL)spectra,andopticalproperties,of(Y,Gd)(V,P)O4∶Eu3+phosphorswereinvestigatedbysynchrotronradiation.TheVUVPLEspectraandthecorrelationamongVUVPLintensity,λem,andEu3+,Gd3+,andP-contentwereestablished.ThePLEspectralstudiesshowedthat(Y,Gd)(V,P)O4∶Eu3+exhibitedsignificantabsorptionintheVUVrange.TheVUVPLintensitywasfoundtoenhancewithPO43-andGd3+-doping.Furthermore,thechromaticitycharacteristicsof(Y,Gd)(V,P)O4∶Eu3+werealsofoundtobe(0.6614,0.3286)andcomparedagainst(Y,Gd)BO3∶Eu3+asareference.Basedonthecharacterizationresults,wearecurrentlyimprovingandevaluatingthepotentialapplicationof(Y,Gd)(V,P)O4∶Eu3+asanewred-emittingPDPphosphor.
简介:Awhitelong-lastingphosphorCa2MgSi2O7:Dy3+waspreparedbythesolid-statereaction.Astrongbandpeakedat260nmwasshownintheexcitationspectrumof578nmemission,whichmightbeattributedtotheoxygendeficiencyofthehost.Afterirradiatedwith254nmfor4min,thewhiteafterglowofthesamplecouldbeseenfor3h.Moreover,thedepthsandfrequencyfactorsoftrapcenterswerecal-culatedfromthethermo-luminescencecurveofthesample,whichindicatedthatthetrapcenterscorrespondingtothe414Kbandweremorehelpfultothelong-lastingphosphorescence.