简介：H+-restackednanosheetsandnanoscrollspeeledfromK4Nb6O17displaydifferentstructuresandsurfacecharacters.Thetworestackedsampleswithincreasedsurfaceareashaveanamazingvisible-lightresponseforthephotodegradationofdyes,whichissuperiortocommercialTiO2(P25)andNb2O5.Bycomparison,H+/nanosheetshavearelativelyfasterphotodegradationrateoriginatedfromlargeandsmoothbasalplane.Theworkrevealsthatdyeadsorbedontheunfoldednanosheetscaneffectivelyharvestsunlight.Duetofacilepreparation,low-costandhighphotocatalyticefficiency,H+/nanosheetsandH+/nanoscrollsmightbeusedforthevisiblelight-drivendegradationoforganicdyesasasubstituteforTiO2inindustry.

简介：Directconversionoffructose-basedcarbohydratesto5-ethoxymethylfurfural(EMF)catalyzedbyLewisacidinethanolwasinvestigated.ItwasfoundthatBF3(Et)2Owasfavorablefor5-hydroxymethylfurfural(HMF)etherificationtoEMF.BF3(Et)2OcombinationwithAlCl36H2Owiththemolarratioof1wasaneffectivecatalystsystemforsynthesisofEMFfromfructose-basedcarbohydrates.55.0%,45.4%and23.9%ofEMFyieldswereobtainedfromfructose,inulinandsucroseunderoptimizedconditions,respectively.

简介：Theresultsonadissociationbehaviorofpropanehydratespreparedfrom'drywater'andcontainedunreactedresidualwaterintheformoficeinclusionsorsupercooledliquidwater(watersolutionofgas)werepresentedfortemperaturesbelow273K.Thetemperaturerampingorpressurereleasemethodwasusedforthedissociationofpropanehydratesamples.Itwasfoundthatthemechanismofgashydratedissociationattemperaturesbelow273Kdependedonthephasestateofunreactedwaterinthehydratesample.Gashydratesdissociatedintoiceandgasiftheiceinclusionswereinthehydratesample.Thesamplesofpropanehydrateswithinclusionsofunreactedsupercooledwateronly(withouticeinclusions)dissociatedintosupercooledwaterandgasbelowthepressureofthesupercooledwater-hydrate-gasmetastableequilibrium.

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简介：物理图像是“不同学科知识与研究方法的联系与渗透的典范，它遍布于物理“科学内容”的各大版块．本文通过对物理电现象中若干典型图像的详析，强调图像教学务必做到有目标、有比较、讲科学、讲效益，促进学生登上具有初步信息收集、信息处理、信息交流能力的平台．

简介：QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.

简介：合成了一维绳梯链状双金属化合物[Ni(en)2]3[Fe(CN)6]2·2H2O,并对其变温穆斯堡尔谱进行了研究,结果表明该分子磁体中铁的电子态为低自旋Fe3+,而大的四极分裂值(QS)表明此化合物的[Fe(CN)6]3-单元对称结构发生了形变,低温时出现的磁弛豫谱,给出了在该温度点附近出现铁磁耦合相互作用的信息。