简介：Theefficiencyofthepoly（3-hexylthiophene）（P3HT）and[6,6]-phenylC61-butyricacidmethylester(PC61BM)basedorganicsolarcellswasenhancedbyusing1,2,4-trichlorobenzene（TCB）asaprocessingadditivetocontroltheblendmorphology.TheadditionofTCBimprovedthearrangementofP3HTwhichresultedingoodphaseseparatedblendfilms.Correspondingly,theoptimizedsolarcellsshowedapowerconversionefficiency（PCE）of4.17%withafillfactor（FF）of0.69,whichwerehigherthanthoseofcommonthermalannealingdevices（PCE3.84%,FF0.67）.Theefficiencywasfurtherimprovedto4.74%bythermalannealingat150°Cfor10minwithahigherFFof0.74.
简介：一个非水的暂停polycondensation方法被建议继续为准备的p-phenylenediamine和terephthaloyl氯化物的反应poly(p苯撑terephthalamide)(PPTA)。系统与NMP-CaCl被操作<潜水艇class=“a-plus-plus”>是的2答案驱散的阶段和是的惰性的液体石蜡连续阶段。每NMP-CaCl<潜水艇class=“a-plus-plus”>在石蜡推迟的2答案microdroplet用作polycondensation发生了的microreactor。根据TGA，XRD，红外，SEM和EA的结果，有好质量的PPTA通过这个新奇方法被获得，并且影响这个过程的很多个主要因素被调查为PPTA的准备决定最佳条件。而且，这个二阶段的polycondensation系统与常规解决方案polycondensation方法相比带给许多唯一的优点，包括使反应物离开氧和水的封上的反应环境，HCl到的容易的移动支持更少的精力花费了工具的反应，控制得好的温度和低粘性。
简介：TheSiO2nanoparticleswerecoatedonthesurfaceofgrapheneoxide(GO)bysol-gelmethodtogettheSiO2-Gcompound.TheSiO2-GwasrestoredandoleophylicallymodifiedtopreparehydrophobicmodifiedSiO2-G(HM-SiO2-G)whichwassubsequentlyaddedtosiliconerubbermatrixtopreparetwo-componentroomtemperaturevulcanized(RTV-2)thermalconductivesiliconerubber.Themorphology,chemicalstructureanddispersityofthemodifiedgraphenewerecharacterizedwithSEM,FTIR,Raman,andXPSmethods.Inaddition,theheat-resistancebehavior,mechanicalproperties,thermalconductivity,andelectricalconductivityoftheRTV-2siliconerubberwerealsostudiedsystematically.TheresultsshowedthattheSiO2nanoparticleswerecoatedongrapheneoxidesuccessfully,andHM-SiO2-GwasuniformlydispersedinRTV-2siliconerubber.TheadditionofHM-SiO2-Gcouldeffectivelyimprovethethermalstability,mechanicalpropertiesandthermalconductivityofRTV-2siliconerubberandhadnogreatinfluenceontheelectricalinsulationperformance.
简介：Asidechainliquidcrystallinecopolysiloxane,whichwouldshowelectro-opticeffectsasknownfromlowmassliquidcrystal,wassynthesizedbyhydrosilylationreaction,andthetwohomologousmonomerswithdifferentlengthspacerscontainingSchiff’sbasemesogenwith—NO2terminatedgroupweregraftedtoapolysiloxanemainchain.Residualmonomerincrudeproductiseffectiveinreinforcingtheresponsetoanelectricfieldoverthatofpurepolymericliquidcrystal.
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