简介：高密度聚乙烯(HDPE)的薄墙样品经由注射塑造，不同注射速度从100mm/s到1200mm/s被准备。在张力的力量和幼仔模量的重要减少与增加注射速度被观察。为了在这后面调查机制，减少，取向，分子的重量，分子的重量分发，融化流动率，crystallinity和水晶HDPE的形态学用二维的宽角度的X光检查衍射(2D-WAXD)被描绘，胶化浸透层析(GPC)，毛状的电流测定和微分扫描热量测定(DSC)分别地。这被表明取向，分子的重量，分子的重量分发，融化流动率和crystallinity没与增加有明显的变化注射速度。不过，扩大的链晶体的内容或大合拢的链晶体被发现与增加注射速度减少。因此，在张力的性质的减少被扩大的链晶体或大合拢的链晶体的减少的内容主要贡献，这被结束。这研究为高速度注射塑造的申请向工业提供珍贵信息。

简介：Newacetylenemonomers,6-{[(1-naphthylethynyl-4-phenyl)carbonyl]oxy}-l-phenyl-l-hexyne(1),2,5-diethynylthiophene(3),and4,4′-diethynylbiphenyl(6)weresynthesized.Homopolymerizationof1andcopolycyclotrimerizationsof3and6with1-heptyneandl-octynehavebeenachievedwithWCI6-andTaC15-Ph4Sncatalysts,respectively,givingsolublelineardisubstitutedpolyacetylene(2)andhyperbranchedpolyarylenes(5and8)withhighmolecularweights(upto1.2×105)inhighyields(upto98%).ThestructuresandpropertiesofthepolymersarecharacterizedandevaluatedbyIR,NMR,TGA,UV,photoluminescence(PL),andelectroluminescence(EL)analyses.Allthepolymerspossesshighthermalstabilityandemitstrongbluelightuponphotoexcitation.Theintensityoftheemittedlightisgreaterthanthatofpoly(1-phenyl-1-octyne),awell-knownhighlyluminescentdisubstitutedpolyacetylene.Littleaggregation-inducedredshiftinthePLwasobservedinthethinfilmsofthepolymers.Byconstructingamulti-layerELdevice,highELquantumyield(0.18%)hasbeenachievedin2,whicharethebestresultsforsubstitutedpolyacetylenesattainablesofar.

简介：Heat-resistantsiliconegelsweresynthesizedbyreplacingthesinglemainchainpolymethylhydrosiloxanewithreactiveladderlikepolyhydrosilsesquioxanecopolymers.Becauseoftheinteractionbetweenpolydimethylsiloxanechainsandtheladderlikepolysilsesquioxaneschains,thecyclizationofthepolydimethylsiloxanechainsishindered.Thehighthermalstabilityoftheladderlikepolymerscanimprovethethermalstabilityofthesiliconegelswithoutsacrificingtheirgoodcomprehensiveproperties.

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简介：Inthisarticle,AHPS(3-allyloxy-2-hydroxy-1-propanesulfonatesalt)wassynthesizedtouseinemulsifier-freeemulsionpolymerizationofBA/BMA/MMAsystemforhighsolidcontentlatexes.Storagestability,flowbehaviorofthelatexes,morphologyoftheobtainedlatexparticles,dynamicviscoelasticbehavior,tensilestrengthandwaterresistancepropertiesoftheresultedcopolymerswereinvestigated.TheexperimentalresultsshowthatwiththeadditionofAHPS,stabilityoftheemulsionisgreatlyimprovedthatthereappearsnoapparentprecipitationduringthepolymerizationandstorageatroomtemperaturefor6monthsandat-10℃forfourmonths.FlowofthelatexesfollowstheBinghambodylaws,diameterofthelatexparticlesisabout0.6μm,ofwhichislargerthanthatofbyconventionalemulsionpolymerization(0.12μm).Inaddition,notonlywaterresistanceofthecopolymersobtainedbyemulsifier-freeemulstionpolymerizationisgreatlyimproved,butalsotensilestrengthisobviouslyenhanced.

简介：Twoseriesofinterpenetratingsulfonicacidresins（ISAR）,10×nandn×10,werepreparedbymeansofthewetmethod,andthephysicochemical,thermodynamicandkineticpropertiesoftheISARweremeasured.Theresultsshow:10×nresinsexhibitbetterpropertiesthann×10ones,mainlyinhigherapparentdegreeofcrosslinkingandlargerconformationalentropyeffect,amongwhich,10×1resinexhibitsthebestthermodynamicandkineticproperties.IntheDTAgraphsofn×10resins,therearetwoTgandtwoTox,butinthoseof10×n,onlyoneTgandoneTox.Thisresultwellsupportstheconclusionthat10×nresinshavemuchbetterinterpenetratingstructuralaspects.

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简介：AnewtypeofSiO_2-MgO-CaO(SMC)whiskerwasusedtomodifyhighdensitypolyethylene(HDPE).Themeltingbehaviorandcrystallinitywereinvestigatedbydifferentialscanningcalorimetry(DSC).ThedispersionofwhiskersandinterfacialadhesioninthepreparedHDPE/SMCwhiskercompositeswereinvestigatedbyscanningelectronmicroscopy(SEM).Themechanicalpropertieswereevaluatedbymechanicaltestsanddynamicmechanicalanalysis(DMA).DSCdataindicatedthatthemeltingtemperatureandthecrystall...

简介：新奇的肼单体，pyridine-2，6二度((4-aminophenyl)thioureido)羰基(PATC)高效地被综合并且有各种各样的芳香的dianhydrides的polymerized。因而，(pyridinethiourea-imide)poly，有好热性质的s(PPTI)和火焰retardancy被制作。PATC和PPTI的结构被FTIR描绘，<啜class=“a-plus-plus”>1H-NMR，<啜class=“a-plus-plus”>13与元素的分析，crystallinity，organosolubility，固有的粘性和胶化浸透一起的C-NMR光谱学色析法的大小。包含C=S，CONH和元的PPTI在聚合物脊梁代替了pyridine一半显示出非结晶的自然并且在高度极的器官的溶剂并且甚至在象tetrahydrofuran(THF)那样的不太极的溶剂是容易地可溶的。聚合物在0.911.16dL/g的范围有固有的粘性，分子的重量在6800077000g/mol之间被发现。PPTI的电的性质以在频率的一个范围上经常的电介质被估计。他们的热稳定性被在范围发现的10%重量损失温度决定519563在组之中未改变。1/1-sGC子单元的蛋白质层次从中年的比较w相?盼?盼在RCC被减少吗？？

简介：Adetailedstudywasperformedonthecrystalstructuresofpan-milledhigh-densitypolyethylene(HDPE)usingdifferentialscanningcalorimetry(DSC)andX-raydiffraction.ThecrystallinityofHDPEfirstdecreasedslightly,followedbyagradualincreasewithincreasingmillingtimes.Monocliniccrystalsappearedafter4cyclesofmilling.Withincreasingtimesofmilling,theproportionofmonocliniccrystalsincreasedsignificantlywhiletheproportionoforthorhombiccrystalsdecreasedgradually.Withincreasingtimesofmilling,thecrystallitesizeoforthorhombicformdecreasedgreatly,whilethesizeofmonocliniccrystalliteskeptalmostconstantduringmilling.

简介：Polymernanoparticleswerepreparedinthemethylmethacrylate(MMA)/butylmethacrylate(BA)emulsioncopolymerizationprocessbyamodifiedmicroemulsioncopolymerizationmethod.2-Hydroxyethylmethacrylate(HEMA),acrylate(AA)andmethylacrylate(MAA)wereusedasreactivecosurfactants.Withthisprocesshighpolymer:surfactantweightratios(40:1orgreater),relativelyconcentrated(～30wt.%)latexesandsmall(～60nm)particlediameterswereobtained.PropertiesofthelatexeswerecharacterizedbyTEM,DSC,dynamiclightscattering,andIRspectroscopy.

简介：Carbazole-basedbi-functionalphotorefractivepolyacrylateswerepreparedviafreeradicalpolymerizationandpost-azo-couplingreaction.ThestructureofpolymerswascharacterizedbyFouriertransforminfraredspectroscopy(FTIR)andprotonnuclearmagneticresonance(1H-NMR)spectroscopy.Thedifferentialscanningcalorimetry(DSC)andthethermalgravimetricanalysis(TGA)wereusedtocharacterizethethermalpropertyofpolymers.Theresultsindicatethatthoughtheglasstransitiontemperature(Tg)ofpolymersincreaseswithincreasingtheratioofNLOgroups,thepolymerswithdifferentratiosofNLOgroupsstillallshowlowglasstransitiontemperaturesaround60°C,andgoodthermalstability,whicharefavorabletothepracticalapplicationofthesepolymers.Thegelpermeationchromatographic(GPC)resultindicatesthatthesepolymersallhavehigh-molecular-weightwhichisfavorabletothelongtermstabilityofthematerial.Further,thesepolymershavegoodsolubilityinchloroformsolvent,andthesolutionscaneasilybefabricatedintoopticallytransparentfilms.Gaincoefficientsof75cm-1,185cm-1and66cm-1canbeobservedatzeroexternalelectricfieldwithoutanyadditionagentorpre-polingforpolymersP-2,P-3andP-4respectively.ThedifferentcontentsofNLOgroupsresultinthedifferentpropertiesofpolymersP-2,P-3andP-4.

简介：Theisotropyoranisotropyinsomephysicalpropertiesoftheammorphouspoly(ethyleneterephthalate)filmsuniaxiallydrawnattemperaturesaboveitsT_gandthenquenchedtoroomtemperaturehavebeenstudied.Experimentalresultsherepresentedshowthatthisamorphousstateofhighglobalchainorientationbutnearlyrandomsegmentalorientation,theGOLRstate,isnearlyisotropicinrefractiveindicesandYoung’smodulusforsmalldeformation,whileitisveryprobablyanisotropicinthermalconductionandmicrowavedielectricproperties.

简介：Thestrategyofsequentiallyspin-coatingaperovskitefilmfromtheperovskiteprecursorandanelectrontransportinglayerof[6,6]-phenyl-C71-butyricacidmethylester(PC71BM)isdevelopedtosimplifythefabricationprocedureofperovskitesolarcells.X-raydiffractionandscanningelectronmicroscopyindicatethatPC71BMfilmonperovskitelayercanretardtheevaporationofdimethylsulfoxide（DMSO）efficiently,thusprolongingthetransformationofintermediatephasetoperovskitecrystals,leadingtoahighqualityperovskitethinfilm.Thesolarcellswiththestructureofindiumtinoxides（ITO）/poly（3,4-ethylenedioxythiophene）:poly（styrenesulfonate）（PEDOT:PSS）/CH3NH3PbI3/PC71BM/bathocuproine（BCP）/Agmadefromthissimplifiedmethodexhibitahigherefficiency（12.68%）thanthosefromtheconventionalone-stepmethod（9.49%）.

简介：有在粒子的核心的高carboxyl内容的没有肥皂的吸水恐水病的核心壳乳胶粒子经由播种乳剂被综合聚合使用甲基methacrylate(MMA)，丁基acrylate(BA)，甲基丙烯酸(MAA)，苯乙烯(圣)和乙烯乙二醇dimethacrylate(EGDMA)作为单体，并且在聚合，粒子尺寸和形态学上在核心准备使用的MMA内容的影响被传播电子显微镜学调查，动态轻散布结果证明播种乳剂聚合能用当在核心准备的MAA内容是时，喂过程的饥饿的单体顺利被执行平等者到或不到24wt%，并且有恐水病的PSt壳的吸水的P(MMA-BA-MAA-EGDMA)核心的包含的效率随MAA内容的增加减少了。当有中等极性的P(MMA-MAA-St)的夹层在P(MMA-BA-MAA-EGDMA)核心和PSt壳之间被插入时，井在核心准备与24wt%MAA内容设计了没有肥皂的吸水恐水病的核心壳乳胶粒子被获得。

简介：Usingsupportedmulti-componentzincdicarboxylatecatalyst,poly(1,2-propylenecarbonate-co-1,2-cyclohexylenecarbonate)(PPCHC)wassuccessfullysynthesizedfromcarbondioxide(CO_2)withpropyleneoxide(PO)andcyclohexeneoxide(CHO).Theconversionofepoxidesdramaticallyincreasedupto89.7%(yield:384.2gofpolymerpergofZn)withincreasingreactiontemperaturefrom60℃to80℃.Theoptimizedreactiontemperatureis80℃.Thechemicalstructure,themolecularweight,aswellasthermalandmechanicalpropertiesoftheresultingterpolymerswereinvestigatedextensively.WhenCHOfeedcontent(mol%)islowerthan10%,thePPCHCterpolymershavenumberaveragemolecularweight(M_n)rangingfrom102×10~3to202×10~3andmolecularweightdistribution(MWD)valuesrangingfrom2.8to3.5.Incontrasttopoly(propylenecarbonate)(PPC),theintroductionofsmallamountofCHOleadstoincreaseintheglasstransitiontemperaturefrom38.0℃to42.6℃.Similarly,themechanicalstrengthofthesynthesizedterpolymerisgreatlyenhancedduetotheincorporationofCHO.TheseimprovementsinmechanicalandthermalpropertiesareofimportanceforthepracticalapplicationofPPC.