简介:BystudyingthespectralpropertiesoftheunderlyingoperatorcorrespondingtotheM/G/1queueingmodelwithoptionalsecondserviceweobtainthatthetime-dependentsolutionofthemodelstronglyconvergestoitssteady-statesolution.Wealsoshowthatthetime-dependentqueueingsizeatthedeparturepointconvergestothecorrespondingsteadystatequeueingsizeatthedeparturepoint.
简介:Graphitedusthasanimportanteffectonthesafetyofhigh-temperaturegas-cooledreactors(HTR).Theflowfieldinthesteamgeneratorwasstudiedbythecomputationalfluiddynamics(CFD)method,withtheresultsindicatingthatthefrictionvelocityinthewindwardandtheleewardoftheheattransfertubesisrelativelylowandishigheratthesides.Furtheranalysisoftheresuspensionofgraphitedustindicatesthattheresuspensionfractionreachesnearlyzeroforparticleswithadiameterlessthan1μm,whereasitwillincreasesastheheliumvelocityinthesteamgeneratorincreasesforparticlesizelargerthan1μm.Moreover,theresuspensionfractionincreasesastheparticlesizeincreases.Theresultsalsoindicatethatresuspensionoftheparticleswithsizeslargerthan1μmexhibitedobviousdifferencesindifferentpartsofthesteamgenerator.
简介:Thecreationandpropagationoflongitudinalacousticphonons(LAPs)inhighqualityhematitethinfilms(α-Fe2O3)epitaxiallygrownondifferentsubstrates(BaTiO3,SrTiO3,andLaAlO3)areinvestigatedusingthefemtosecondpump–probetechnique.Transientreflectionmeasurements(?R/R)indicatethephoto-excitedelectrondynamics,andtheinitialdecaylessthan1psandtheslowdecayof~500psareattributedtotheelectron-LOphononcouplingandelectron–holenonradiativerecombination,respectively.LAPsinα-Fe2O3filmcanbecreatedbyultrafastexcitationoftheligandfieldstate,suchastheligandfieldtransitionsunder800-nmexcitationaswellastheligandtometalcharge-transferwith400-nmexcitation.Thestrainmodulationsofthesoundvelocityandtheout-of-planeelasticpropertiesaredemonstratedinα-Fe2O3filmondifferentsubstrates.
简介:Thesymmetryenergywhichcharacterizestheisospindependenceoftheequationofstateofasymmetricnuclearmatter,playsacrucialroleinunderstandingavarietyofissuesinnuclearphysicsandastrophysics,suchasheavyioncollisions,exoticnuclei,stabilityofsuperheavynuclei,fusioncrosssections,thestructures,compositionandcoolingofneutronstars[1??5].Muchtheoreticalandexperimentalefforthasbeenmadetoconstrainthedensitydependenceofsymmetryenergy.Uptonow,wehavegotsomebasicknowledgeaboutthesymmetryenergyatlowdensities,whileathighdensitiesweevendonotknowitsvariationtendencyasafunctionofdensity.Theproblemremainsunsolvedduetothedifficultyofnucleon-nucleoninteractionsandmany-bodyproblems.
简介:Thehighrepetitionrate10J/10nsYb:YAGlasersystemanditskeytechniquesarereported.Theamplifiersinthissystemhaveamulti-passV-shapestructureandtheheatintheamplifiersisremovedbymeansoflaminarwaterflow.Inthemainamplifier,thelaserisfour-pass,andanapproximately8.5J/1Hz/10nsoutputisachievedintheprimarytest.Thefar-fieldoftheoutputbeamisapproximately10timesthediffractionlimit.Becauseofthehigherlevelsofamplifiedspontaneousemission(ASE)inthemainamplifier,theoutputenergyislowerthanexpected.Attheendwediscusssomemeasuresthatcanimprovethepropertiesofthelasersystem.
简介:Thecopolymerizationsofethylenewith10-undecen-1-olhavebeeninvestigatedusingvanadiumprecatalysts,bis(imino)pyrrolylvanadium(III)complexes1-3,2,5-C4H2N(CH=NR)2VCl2(THF)2[R=C6H5(1),2,6-iPr2C6H3(2),C6F5(3)],andtheiminopyrrolylandβ-diketiminateonesforcomparison.Thepolarmonomerwaspretreatedbydiethylaluminiumchloride(presentalsoasthecocatalyst)beforethecopolymerization.ThemonomerreactivityratioswereevaluatedusingtheFineman-Rossmethod.Theligandstructureconsiderablyinfluencedthecatalyticactivityandtolerancetowardsthepolarmonomer,thepolarmonomerincorporationandthemolecularweightsoftheresultantcopolymers.Thebis(imino)pyrrolylvanadiumcomplexesexhibitedpromisingcatalyticperformanceforthecopolymerization,andahighcatalyticactivityupto3.84kg/mmolv·hwithahighcomonomerincorporationof14.0mol%wasachievedbycomplex3undermildconditions.
简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.