简介:TheeffectsofSO2,SO3ondenovosynthesisofpolychlorinateddibenzo-p-dioxins(PCDDs)anddibenzofurans(PCDFs)werestudiedusingmodelflyashesincorporatingcopperoxideandactivatedcarbon.ItwasfoundthattheinhibitiveeffectofSO2onPCDD/FsformationissimilartothatofSO3.Toinvestigatetheinhibitionmechanism,CuSO4formationsfrombothCuOandCuCl2wereexamined.TheabilityofSO3toconvertCuCl2andCuOonasilicasupportintosulfateismuchstrongerthanthatofSO2.However,replacingsilicabyactivatedcarbonleadstoamuchhighconversionofCuCl2toCuSO4inthepresenceofSO2.ThepromotionbyactivatedcarbonisexplainedbythereductionofCuCl2toCu2Cl2andtheeventualconversionofCu2Cl2intoCuSO4isthemaininhibitionmechanismofSO2ondenovosynthesisofPCDD/Fs.
简介:WereportonN-dopedp-typeZnOfilmswiththec-axisparalleltothesubstrate.ZnOfilmswerepreparedonana-Al2O3(0001)substratebysolid-sourcechemicalvapourdeposition(CVD),Zn(CH3COO)2.2H2OwasusedastheprecursorandCH3COONH4asthenitrogensource.Thegrowthtemperaturewasvariedfrom300℃to600℃,theas-grownZnOfilmdepositedat500℃showedp-typeconductionwithitsresistivityof42Ωcm,carrierdensity3.7×10^17cm^-3andHallmobility1.26cm^2V^-1.s^-1atroomtemperature,whicharethebestpropertiesforp-typeZnOdepositedbyCVD.Thep-typeZnOfilmpossessesatransmittanceofabout85%inthevisibleregionandabandgapof3.21eVatroomtemperature.
简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.
简介:S^p(1≤p≤∞)空间为导数属于Hardy空间H^p的复平面单位圆盘D上所有解析函数组成的空间.令函数φ和φ是D上的解析函数且φ(D)D,则将算子W(φ,φ):f→φfoφ称为加权复合算子.文章给出了当1≤q≤p≤∞,φ∈S^∞时,加权复合算子W(φ,φ)从空间S^p到S^q上的有界性的充要条件.然后通过推广经典的Fejer-Riesz不等式证明了当1〈p≤∞时,S^p到圆盘代数A上的嵌入映射是紧的.
简介:研究p-致凸Banach空间中渐近半压缩映象的修正的Mann迭代过程和修正的Ishikawa迭代过程的强收敛性.本文始终假设X是P-致凸Banach空间.最近,r-渐近半压缩映象的概念被引入,并给出了X中该映象(此时,r=P)的修正的Mann迭代过程和修正的Ishikawa迭代过程的强收敛性定理,文章所得结果改进、推广和统一了近期相关结果.
简介:ThecompressionbehaviourofPd39Ni10Cu30P21bulkmetallicglassisivestigatedatroomtemperatureupto23.5GPausinginsituhighpressureenergydispersivex-raydiffractionwithasynchrotronradiationsource.Pressureinducedstrucuralrelaxationofthebulkmetallicglassisexhibitedwithinthepressurerange.Itisfoundthatbelowabout5GPa,theexistenceofexcessfreevolumecontributestorapidstructuralrelaxation,whichgivesrisetorapidvolumeticchange.Underhigherpressure,furtherrelaxationresultsinstructuralstiffness.
简介:目前,国内没有关于半钢发热剂的国家标准检测方法,只能根据组分范围分别检测各个组分,不仅耗时而且使用的大量化学试剂对环境造成污染。故研究了X-射线荧光光谱法快速测定半钢发热剂中Si,P,S的方法。采用粉末压片制样,研究其制样条件,包括磨样时间、压样时间和压力对测定结果的影响。采用其它方法定值提供的检测样品,作为x-射线荧光光谱法内控标准样品,采用经验系数法进行基体校正,通过解谱拟合建立校准曲线,校准曲线建立后仪器建立漂移校正程序。实验结果精密度好,各元素的相对标准偏差在0.15%-1.3%。准确度满足生产需求,实验方法可用于快速检测半钢发热剂化学组分。
简介:<正>Foranyintegersa1,a2,a3,a4andcwitha1a2a3a40(modp),thispapershowsthatthereexistsasolutionX=(x1,x2,x3,x4)∈Z4ofthecongruencea1x12+a2x22+a3x32+a4x42≡c(modp)suchthat‖X‖=max{|x1|,|x2|,|x3|,|x4|}《p1/2logp.
简介:Theefficiencyofthepoly(3-hexylthiophene)(P3HT)and[6,6]-phenylC61-butyricacidmethylester(PC61BM)basedorganicsolarcellswasenhancedbyusing1,2,4-trichlorobenzene(TCB)asaprocessingadditivetocontroltheblendmorphology.TheadditionofTCBimprovedthearrangementofP3HTwhichresultedingoodphaseseparatedblendfilms.Correspondingly,theoptimizedsolarcellsshowedapowerconversionefficiency(PCE)of4.17%withafillfactor(FF)of0.69,whichwerehigherthanthoseofcommonthermalannealingdevices(PCE3.84%,FF0.67).Theefficiencywasfurtherimprovedto4.74%bythermalannealingat150°Cfor10minwithahigherFFof0.74.
简介:Themonomericcobalt-phosphite-thiolatocomplex[Co(mpt)2{P(OCH3)3}2]BF4(Hmpt=2-mercaptothiazoline)hasbeenpreparedandcharacterizedbyX-raycrystallography.ThecomplexcrystallizesinthemonoclinicspacegroupC2/cwitha=0.8078(5),b=2.6020(18),c=1.2191(7)nm,β=99.38(1)°,V=2.528(3)nm3,andZ=4.Thestructurecomprisesdiscretecations[Co(mpt)2{P(OCH3)3}2.]+andanionsBF4-,inwhichthecobalt(Ⅲ)atomiscoordinatedtotwochelatempt-andtwoas-orientedmonodentateP(OCH3)3ligandsinahighlydistortedoctahedralgeometry.ThemostdistortedanglesareS(2)-Co(1)-S(2a)of162.23(10)°andN(1)-Co(1)-S(2)of71.47(13)°,thelatteriscausedbythegeometricconstraintofthebidentateligandmpt-.CyclicvoltammetryhasbeenusedtostudytheelectrochemicalbehaviorofthetitlecomplexontheRelectrodeinMeCNsolutionwith0.1mol·L-1ofBun4NBF4aselectrolyte.TheresultsindicatethatthetitlecomplexisunstableinMeCN.
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简介:一个非水的暂停polycondensation方法被建议继续为准备的p-phenylenediamine和terephthaloyl氯化物的反应poly(p苯撑terephthalamide)(PPTA)。系统与NMP-CaCl被操作<潜水艇class=“a-plus-plus”>是的2答案驱散的阶段和是的惰性的液体石蜡连续阶段。每NMP-CaCl<潜水艇class=“a-plus-plus”>在石蜡推迟的2答案microdroplet用作polycondensation发生了的microreactor。根据TGA,XRD,红外,SEM和EA的结果,有好质量的PPTA通过这个新奇方法被获得,并且影响这个过程的很多个主要因素被调查为PPTA的准备决定最佳条件。而且,这个二阶段的polycondensation系统与常规解决方案polycondensation方法相比带给许多唯一的优点,包括使反应物离开氧和水的封上的反应环境,HCl到的容易的移动支持更少的精力花费了工具的反应,控制得好的温度和低粘性。
简介:基于密度泛函理论(DFT)的第一性原理平面波超软赝势方法,计算了纯MgF2晶体、Co掺杂MgF2晶体、P掺杂MgF2晶体和(Co,P)双掺杂MgF2晶体的电子结构和光学特性.结果表明,掺杂后的MgF2晶体发生了畸变,原子之间的键长也有所变化.(Co,P)双掺杂后,由于非金属原子P态和金属原子d态之间的轨道杂化,在MgF:的导带与价带之间形成了新的杂质能级,这些杂质能级一方面减小了MgF2的带隙宽度,使光吸收曲线红移到可见光区,另一方面有利于光生电子一空穴对的分离,提高了MgF2光催化效率.(Co,P)双掺杂使位于禁带中的杂质能级的态密度明显增加,导致电子从价带跃迁到杂质能级和从杂质能级跃迁到导带的概率增加,从而使其对太阳能的利用率提高.并揭示了(Co,P)双掺杂MgF2在光学元器件方面的潜在应用.