学科分类
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12 个结果
  • 简介:Anumberofnaphthalenedonorcompoundsthatpossessanadamantanaminebindingmoietyandan(OCH2CH2)n(nn1,2,3,4,6,8)spacerweresynthesized.Thefluorescencequenchingbetweenthesedonorsubstratesandmono-6-O-p-nitrobenzoyl-β-cyclodextrin(pNBCD)andmono-6-O-m-nitrobenzoyl-β-cyclodextrin(mNBCD)wasstudiedindetail.Itwasfoundthatveryefficientfluorescencequenchingcouldoccurinthesesupramolecularsystems.Thisquenchingwasattributedtothephotoinducedelectrontransferinsidethesupramolecularassemblybetweenthenaphthalenedonorsandcyclodextrinacceptors.DetailedStern-VolmerconstantsweremeasuredandtheywerepartitionedintodynamicStern-Volmerquenchingconstantsandstaticbindingconstants.Itwasdemonstratedthatthebindingconstantsbetweenallthenaphthalenecompoundsandcyclodextrinsarethesameastheypossessthesamebindingsite,i.e.,adamantanamine.

  • 标签: 光致电子转移 Host-Guest化合物 2-萘基-(乙烯氧基)n-金钢石 单-6-O-p-硝基苯甲酰基-β-环式糊精 单-6-O-m-硝基苯甲酰基-β-环式糊精
  • 简介:ToraisetheroomtemperatureionicconductivityandimprovethemechanicalstrengthofaPEO-basedpolymerelectrolyte,anoncrystallinetwo-componentepoxyelectrolytesystemhasbeenprepared.Thediglycidyletherofpolyethyleneglycolsasprecursorsofthesystemweresynthesizedbyatwo-stepprocess.Thepresumedstructureoftheproductwascharacterized,by13C,1HNMRandIRspectroscopy.Itwasfoundthataside-reactionoccurredbetweenthesecondaryhydroxylgroupofPEG-chlorohydrinandepichlorohydrininsomedegree,resultinginaby-productcontaining—CH2Clsidegroup.Byselectingacharacteristicsignal,whichisundistortedbytheincreaseinthelengthofCH2CH2—Osegment,a1HNMRapproachofdeterminingtheequivalentepoxyweight(EEW)wasproposed.ThemethodisvalidtospecimenseventhoughtheEEWisashighas2,000.TheexaminationofthespecimensbyDSCshowedthatepoxidationgreatlydepressedthecrystallinityofthePEG’s,whereastheTgwasraised.

  • 标签: POLYMER solid ELECTROLYTE Polyethylene GLYCOL EPOXY
  • 简介:一荧光灯分核derivate,N-allyl-1-pyrenemethylammoniumhydrochloride(APA+),被报导与葫芦形成稳定的hostguest建筑群[8]uril(CB[8]),并且这个性质能被利用到确定CB的纯净[8]经由排放滴定。而且,APA+和CB的1:1建筑群[8]能进一步绑甲基viologen(MV2+),它是广泛地使用的除草剂的主要成分,提供一个好方法检测MV2+,特别在低集中。

  • 标签: 有效成分含量 甲基紫精 CB 荧光测定 检测 顾客
  • 简介:密度功能的理论(DFT)学习被执行了为[Znn?1Al(OH2)n+6(哦)2n?2]3+(n=36)并且[Znn?1Al(OH2)2n?2(哦)2n?2]3+(n=7)簇,它包括象brucite一样格子的基本结构的信息在范围与Zn/Al臼齿的比率(R)Zn/Al分层的双氢氧化物(LDH)组织26,以便在二进制Zn/AlLDH的结构和稳定性上理解Zn/Al比率的效果。基于几何参数的系统的计算和簇模型的形成精力,Zn2+和Al3+阳离子用不同R价值在象brucite一样结构同态地代替Mg2+是可能的,这被发现,在簇和单位房间参数的微观结构导致差别一ofZn/AlLDH。几何学的分析并且在三价的Al3+或二价的Zn2+阳离子附近结合表明Al3+在当时,决定微观结构性质,形成和相应ZnRAl簇的结合的稳定性比Zn2+起一个更重要的作用R<5,当Zn2+的影响在R5的情况中成为主导的因素时。这些调查结果在对实验的好同意。这个工作提供阳离子的作文怎么影响包含Zn二进制LDH层的微观结构和稳定性的详细电子水平的理解。

  • 标签: 二价锌离子 密度泛函理论 层结构 金属氢氧化物 离子对 密度比
  • 简介:Lithium-sulfur(Li-S)batteriesbelongtooneofthepromisingtechnologiesforhigh-energy-densityrechargeablebatteries.However,sulfurcathodessufferfrominherentproblemsofitspoorelectronicconductivityandtheshuttlingofhighlydissolublelithiumpolysulfidesgeneratedduringthecycles.Loadingsulfurintoporouscarbonshasbeenprovedtobeaneffectiveapproachtoalleviatetheseissues.Mesoporousandmicroporouscarbonshavebeenwidelyusedforsulfuraccommodation,butmesoporouscarbonshavepoorsulfurconfinement,whereasmicroporouscarbonsareimpededbylowsulfurloadingrates.Here,acore-shellcarbon,combiningboththemeritsofmesoporouscarbonwithlargeporevolumeandmicroporouscarbonwitheffectivesulfurconfinement,waspreparedbycoatingthemesoporousCMK-3withamicroporouscarbon(MPC)shellandservedasthecarbonhost(CMK-3@MPC)toaccommodatesulfur.Aftersulfurinfusion,theas-obtainedS/(CMK-3@MPC)cathodedeliveredahighinitialcapacityofupto1422mAh·g-1andsustained654mAh·g-1reversiblespecificcapacityafter36cyclesat0.1C.Thegoodperformanceisascribedtotheuniquecore-shellstructureoftheCMK-3@MPCmatrix,inwhichsulfurcanbeeffectivelyconfinedwithinthemeso/microporouscarbonhost,thusachievingsimultaneouslyhighelectrochemicalutilization.

  • 标签: 可溶性硫化物 可再充电电池 多孔碳 微孔 主机 中孔炭材料
  • 简介:Afacilegreenlow-costcontrollablehydrothermal-thermalconversion(HTC)processfortheuniformhighaspectratioCaSiO3nanowireshasbeendevelopedusingabundantCaCl2·2H2OandNa2SiO3·9H2Oasrawmaterialswithoutanyorganicadditive.Thenanowiresexhibitedatransparentcharacteristicfromtheultraviolettovisibleregion,andtheCaSiO3:1.2%Tb3+nanophosphorswithwellpreserved1DmorphologydemonstratedstronggreenluminescencewithCIEcoordinatesof(x=0.3144,y=0.5912).Thepresentworkdefinitelyrevealsthenanowiresasapromisingstructureandfunctionintegratedhostcandidateforgreen-emittingluminescentmaterialsinlightdisplaysystemsandoptoelectronicdevices.

  • 标签: Calcium SILICATE NANOWIRES Green hydrothermal-thermal conversion
  • 简介:Inthisstudy,weinvestigatetheinfluenceofdopingonthechargetransferanddevicecharacteristicsparametersinthebulkheterojunctionsolarcellsbasedonpoly(3-hexylthiophene)(P3HT)andamethanofuUerenederivative(PCBM).Organicsemiconductorsarealsoknowntobenotpureandtheyhavedefectsandimpurities,someofthemarebeingchargedandactasp-typeorn-typedopants.Calculationsofthesolarcellcharacteristicsparametersversusthep-dopinglevelhavebeendoneatthreedifferentn-dopings(N_d)thatconsistof5×10~(17)cm~(-3),10~(18)cm~(-3),and5×10~(18)cm~(-3).Weperformtheanalysisofthedopingconcentrationthroughthedrift-diffusionmodel,andcalculatethecurrentandvoltagedopingdependency.Wefindthatatthreedifferentn-dopantlevels,optimump-typedopingisaboutN_p=6×10~(18)cm~(-3).Simulationresultshaveshownthatbyincreasingdopinglevel,V_(oc)monotonicallyincreasesbydoping.CellefficiencyreachesitsmaximumatsomewhathigherdopingasFFhasitspeakatN_p=3×10~(18)cm~(-3).Moreover,thispaperdemonstratesthattheoptimumvalueforthep-dopingisaboutN_p=6×10~(18)cm~(-3)andoptimumvalueforn-dopantisN_d=10~(18)cm~(-3),respectively.Thesimulatedresultsconfirmthatdopingconsiderablyaffectstheperformanceoforganicsolarcells.

  • 标签: 有机太阳能电池 掺杂剂 异质结 聚合物 基质材料 模拟
  • 简介:Wereportanovelapproachtoobtainingaclassicalblue-greenexcitableCaS:Eu2+phosphorwithdesiredredemissionbymicrowave(MW)firingprocedureintheabsenceofaddingelementalsulphur.ThedisturbingeffectofMWelectromagneticfieldondecompositionofCaSO4intoCaSactivatedbyeuropiumisdistinctlyobservedtogivepurehostphasewithoutaddinganyelementalsulphurandcarbon.ThehostphaseevolutionisobservedtobehighlydependentonthevariationofappliedMWpowerfromX-raydiffraction(XRD)patternsandthecorrespondingphotoluminescence(PL),andamaximumPLintensityat1100WofMWpowerisacquiredfortheobtainedpurerhostphase.Thenon-thermalandnon-equilibriumeffectsbyMWarerevealedtocorrelatewiththeinteractionbetweenpolarstructureofthehostandappliedelectromagneticfield.Theresultsdemonstrateanoptionalproceduretopreparethisred-emittingphosphorinaneffective,environment-friendlyandscalableapproachforphosphorproductionintheapplicationofbio-illuminationforplantcultivationandartificialphotosynthesis.

  • 标签: 光致发光性质 红光发射 微波促进 荧光粉 硫酸钙 CAS