简介: 一位聪明天真的小朋友问妈妈:"为什么2加2等于4?"妈妈答:"傻孩子,连这么简单的算术都不懂!"于是这位母亲伸出左手的2个指头,又伸出右手的2个指头,左右的2个指头往一起一并,说:"这就叫2加2,你数一数,看是不是4?"孩子勉强点头,接着又问:"可是4是什么玩意儿呢?"妈妈欲言而无语.是呀,如果母亲说这些指头的数目就叫做4,孩子再追问什么叫做999999999,那可就不好用指头之类的东西来比划着解释了!……
简介: 一位聪明天真的小朋友问妈妈:'为什么2加2等于4?'妈妈答:'傻孩子,连这么简单的算术都不懂!'于是这位母亲伸出左手的2个指头,又伸出右手的2个指头,左右的2个指头往一起一并,说:'这就叫2加2,你数一数,看是不是4?'孩子勉强点头,接着又问:'可是4是什么玩意儿呢?'妈妈欲言而无语.是呀,如果母亲说这些指头的数目就叫做4,孩子再追问什么叫做999999999,那可就不好用指头之类的东西来比划着解释了!……
简介:Emissionquenchingof[Ru(bpy)2(4,4’-dcbpy)](PF6)2(1)bybenzenamine,4-[2-[5-[4-[4-dimethylamino]phenyl]-4,5-di-hydro-1-phenyl-1H-pyrazol-3-yl]-ethenyl]-N,N-dimetyl(2)or1,5-diphenyl-3-(2-phenothiazine)-2-pyrazoline(3)wasobserved.Measurementsoftheemissiondecayof1beforeandafteradditionof2or3bysinglephotoncountingtechniquecon-finnedtheobservations.Theemissionquenchingof1by2or3wassubmittedtoStern-Volmerequation.Itwascalculatedthatthequenchingrateconstants(kq)are5.5×109(mol/L)-1s-1for2and4.0×109(mol/L)-1s-1for3,respectively.Theseresultsindicatedacharacterofdynamicquenchingprocess.Thesinglet-stateof2or3wasalsoquenchedby1.ThequenchingbehaviorsdidnotconformtotheStern-Volmerequationandinvolvedbothstaticanddynamicquenchingprocesses.Theapparentquenchingrateconstant(kapp)wascalculatedtobe3×109(mol/L)-1fortheinteractionofexcited2with1,and1.2×109(mol/L)-1forthatofexcited3wit
简介:Thecombinationofboth4,4′-bipyridine(4,4′-bipy)anddihydrogenphosphateanionligandswithcopper(Ⅱ)resultsintheformationofanovellayeredcompoundCu(4,4′-bipy)2(H2PO4)2(H2O)2.ThecrystalstructurecomprisesdiscreteneutralCu(4,4′-bipy)2(H2PO4)2(H2O)2units.Thecopperatom,locatedonthecrystallographictwofoldaxis,iscoordinatedwithtwonitrogenatomsofterminal4,4′-bipyligandsandtwowatermoleculesattheequatorialpositions,andtwodihydrogenphosphateoxygenatomsattheaxialpositions,forminganelongatedoctahedron.Thecomplexisatwo-dimensionaldistortedrhomboidalnetworkpossessingtwokindsofrhomboidswithdimensionsofca.1.6792nm×0.3203nmand1.2778nm×0.3198nm,respectively.Thetwo-dimensionalnetworksarestackedparallellyoneachotheralongc-axistogiveanextendedthree-dimensionalchannelnetworkwithaninterlayerdistanceofca.0.5030nm.Crystaldata:triclinic,spacegroupP-1,a=1.0253(2)nm,b=1.4501(3)nm,c=0.79715(16)nm,α=97.91(3)°,β=90.99(3)°,γ=85.54(3)°,V=1.1703(4)nm3,Z=2,R=0.0892,wR=0.2451.
简介:一、学习指南。1.达成目标:通过观看教学视频和完成“自主学习任务单”给出的任务,会读、会认、会写、会用“科目”的核心词汇,会用“Wehave...Ican...”句型描述学习的科目。设计意图:核心单词及句型的初步学习属于机械操练,学生可通过微视频模仿练习即可习得;2.课堂学习形式预告:(1)课堂组织“QuickResponse”核心单词小组竞赛;(2)小组展示“Mytimetable”,介绍一天的课程安排;(3)小组采访“Myfavouritesubjects”,角色扮演提问并回答喜欢的科目及原因。学生从微视频中可习得本单元核心单词和句型的发音和基本用法。
简介:Ca8Mg(SiO4)4Cl2:Eu2+phosphordopedwithSr2+cationforCa2+partially,wassynthesizedbysolid-statereactionathightemperatureunderreducingatmosphere,anditsluminescentpropertieswereinvestigated.TheexperimentalresultsindicatethattheemissionintensityofthephosphorincreasesafterbeingdopedwithafewamountofSr2+ion.Theemissionpeakofthephosphorblueshifttoabout464nmwhenthephosphorisdopedwithlargequantityofSr2+ions.TheexcitationspectrumindicatesthatthephosphorcanbewellexcitedbyUVandbluelightfrom300to460nm,andthephosphorwasfittedwellfortheexcitationbyUVorblue-LED.