简介:ZnOfilmscontainingErandGenanocrystals(nc-Ge)weresynthesizedandtheirphotoluminescence(PL)propertieswerestudied.Visibleandnear-infraredPLintensitiesarefoundtobegreatlyincreasedinnc-Ge-containingfilm.Er-related1.54μmemissionhasbeeninvestigatedunderseveralexcitationconditionsupondifferentkindsofGe,ErcodopedZnOthinfilms.1.54μmPLenhancementaccompaniedbytheappearanceofnc-Geimpliesasignificantcorrelationbetweennc-GeandPLemissionofEr3+.Theincreasedintensityof1.54μminGe:Er:ZnOfilmisconsideredtocomefromthejointeffectofthelocalpotentialdistortionaroundEr3+andthepossibleenergytransferfromnc-GetoEr3+.
简介:Theoptimalconditionsforthecomplexationreactionofmeso-tetra(3-methoxy-4-hy-droxyphenyl)porphineT(3-M-4HP)Pwithplatinumandrhodiumarepresented.Beer’sLawisobeyedwhentheconcentrationofrhodiumisintherangeof0.45-1.15μg/25mL.Themolarabsorptivityofrhodiumwasfoundtobe1.99×106L·mol-1·cm-1at460nm.ThevalueofεPtwasfoundtobe6.28×105L·mol-1·cm-1bylinearregressionmethod.TheKcoefficientmethodandcompensatingcoefficientwereusedtodetermineplatinumandrhodiumsimultaneoulywithoutremovalormaskingoftheinterferentsinthesample.Theresultsforthedeterminationofplatinumandrhodiuminthemixedsolutionofplatinumandrhodiumaresatisfactory.
简介:孟加拉帕德玛大桥为公铁两用全焊接整体节点钢桁梁桥,桥跨布置共分7联:6×(6×150m)+1×(5×150m)。上层公路桥面采用混凝土板块预制结构,现场整体浇筑;下层铁路桥面为横、纵梁板梁结构,横梁与钢桁梁下弦整体节点全熔透对接焊接,采用“整跨一体运架”方案施工。150m跨3D拼装与焊接施工场地选择在桥址陆地,杆件运输至拼装场后,首先在胎架上进行弦杆与节点的组拼与焊接(二拼),之后进行桁片的组拼与焊接(桁拼),桁片拼装结束后,在150m跨整孔大节段立体拼装前,采用起重设备完成由平位到立位的转换,最后完成150m跨3D拼装与焊接(立拼)。该拼装技术首次应用于此类大型全焊接钢桁梁桥,实践证明,该施工技术可行。