简介：TheNdCl3/MgCl2bisupportedcatalystwaspreparedbyusingNdCl3,MgCl2,（CH3）2（CH2）2OHandTiCl4.ItisshownthatthestructureofbisupportedcatalystwasdifferentfromthoseofeitherNdCl3orMgCl2singlesupportedcatalyst.Apeculiartypeofkineticcurveforethylenepolymerizationwasfound.

简介：为综合的一条non-isocyanate线路有优秀热、机械的性质的热塑的聚氨酯被描述。与四个聚乙烯乙二醇木钉融化1,6-bishydroxyethyloxy羰基aminohexane的transurethanepolycondensation，即PEG400，PEG600，PEG1000，或PEG1500，在不同臼齿的比率被进行。有长木钉序列的一系列热塑的polyetherurethanesTPEU被准备。TPEU经由胶化浸透层析被描绘，FTIR，<啜class=“a-plus-plus”>1H-NMR，微分扫描热量测定，thermogravimetric分析，散布的宽角度的X光检查，和张力的测试。TPEU展览T<潜水艇class=“a-plus-plus”>在12.4汦灡之间的g？

简介：Polyolefinsthatbearachiralsidechain(typicallyanisobutylgroup)experienceaso-calledmacromolecularamplificationofchirality:thechiralside-chaininducesaslightpreferenceforeithertgortg-mainchainconformation.Thisslightconformationalbiasisamplifiedcooperativelyalongthechain,andresultsinpreferredchiralityofthemainchainhelicalconformations.Asaresult,thesepolymersdisplayaliquid-crystal(LC)phasebothinsolutionand,inthemeltasatransientphaseonthewaytocrystallization.Theexistenceoftwoprocesses(melt-LCandLC-crystaltransitions)resultsinunconventionalbehaviorsthatwerefirstanalyzedbyPinoandcollaboratorsbackin1975.Thesepolymersalsoofferameanstotestthestructuralconsequencesofrecentlyintroducedcrystallizationschemes.Theseschemespostulatetheformationofatransientliquid-crystalphaseasageneralschemeforpolymercrystallization.

简介：Conventionalchloromethylation,paraformaldehyde/hydrogenchlorideinaceticacidmedium,wasappliedto1,2-dimethoxybenzene.Chloroform-solublepoly(3,4-dimethoxy-o-tolylene)wasobtainedwithanintrinsicviscosityof0.034dLg~(-1).ThepolymerwasevaluatedasacondensationredoxpolymerprecursorformedbyaFriedel-Craftsreaction.Cleavageofthemethoxygroupspresentinthispolymerresultedinpoly(3,4-dihydroxy-o-tolylene)whichmanifestedagreatair-oxidationresistance.Theredoxpropertyofthelatterpolymerwasfoundtobe1017mVbypotentiometrictitrationwith0.05Ncericammoniumnitrateat25℃.Thismidpotentialwascomparedtothatofcatechol,amonomericanalogue,underthesametitrationconditions.

简介：TheconductivitybehaviorofAl(OH)3-acrylamidehybridpolyacrylamide(hybridPAAm)indistilledwaterwasstudied.Adiscontinuityphenomenonoftheconductivity(k)versusconcentration(c)curveofthehybridPAAminacertainconcentrationregimeisfound.ThisphenomenonisdependentonthemolecularweightofthehybridPAAmandontheparticlesizeandcontentoftheAl(OH)3colloidinthehybridPAAm.ThisphenomenonwasaccountedforassumingionizationofthehybridPAAm.

简介：TheeffectsofHDPEmatrixtoughnessonthebrittle-ductiletransitionofHDPE/CaCO3blendsareinvestigated.NotallHDPEcanbetoughenedbyCaCO3particles.TheabilityofthematrixtoyieldplaysafundamentalroleindetermingwhetherHDPEcanbetoughenedornot.Thereexistsacriticalmatrixtoughness(Isc≈45J/m)belowwhichHDPEcannotbetoughenedobservablybyCaCO3particleatgivenaveragesize,andabovewhichthecriticalmatrixligamentthickness（τ?）isproportionaltomatriximpactstrength.

简介：Thechemicalgraftingofthiolterminatedpoly（sodiumstyrenesulfonate）（HS-PSSS）chainsfromsodiumnitrate（NaNO3）saltsolutiontoagoldsurfacewasinvestigatedwithaquartzcrystalmicrobalancewithdissipationmonitoring（QCM-D）indifferentsaltconcentrations.ItwasfoundthatatlowsaltconcentrationgraftingdensityofHS-PSSSwaslowandthegraftedchainsadoptedamushroomconformation.Withtheincreaseofsaltconcentrationpolyelectrolytechainsunderwentatransitiontowardcoiledstateduetoreductionofelectrostaticrepulsionandasaresultmorechainsweregraftedonthesurface.WhenthegraftingdensityreachedacertainlimitafterwhichfurthergraftingcausedrepulsionbetweenalreadygraftedHS-PSSSchainsandasaresultgraftedchainsadoptedabrushconformation.

简介：OrganicchelatingreagentinfluencesupontheredoxadsorptionofactivatedcarbonfibertowardsAu3-weresystematicallyinvestigated.TheexperimentalresultsindicatedthatthepresenceoforganicchelatingreagentonactivatedcarbonfiberstronglyaffectsadsorptioncapacityofactivatedcarbonfibertowardsAu3+.Thereduction-adsorptionamountofAu3+increasedthreetimesbythepresenceof8-quinolinol.Furthermore,Thereduction-adsorptionamountofAu3+dependedonthepHvalueofadsorptionandtemperature.

简介：Solublepoly(3-hexyl-2,5-thienylenevinylene)(PHTV)wasreadilysynthesizedfromthiopheneinayieldbetterthanthatoftheprecursormethodtopreparepoly(thienylenevinylene)(PTV).Thebandgapofthepolymerisabout1.8eV,whichiscomparablewiththatofPTV.Owingtotheintroductionofalkylsidegroupsontothebackboneofthepolymer,itcanbedissolvedincommonorganicsolventssuchaschloroform,THFandtoluene.ThesynthesisofsolublePHTVisaveryimportantapproachtopreventingoxidationandtoimprovingthepropertiesandtheprocessbilityofthePTV.TheexistenceofalkylsidegroupsinPHTVdoesnotaffectits,bandgapandthermalpropertiesascomparedwithPTV.AfterdopingwithFeCl3,theconductivityofPHTVisashighas1.1×10-2S/cm.ThesolublePHTVcanbeeasilytransformedintothinfilmwithmuchbetterqualitythanthatofthePTVfilmpreparedbythetraditionalprecursormethod,whichisveryimportantforfabricatingdeviceswithgoodproperties.

简介：CuO/γ-Al2O3catalystswerepreparedbyplasmatreatmentandconventionalimpregnationmethods.Thecatalyticcombustionoftwokindsofvolatileorganiccompounds(VOCs),tolueneandbenzene,werecarriedoutovertheseCuO/γ-Al2O3catalysts.ThesurfacepropertiesofthesecatalystswerecharacterizedbyX-rayDiffraction(XRD)andScanningElectronMicroscopy(SEM).TheexperimentalresultsshowedthatincatalyticcombustiontheactivityoftheCuO/γ-Al2O3catalystpreparedviaplasmawasmuchhigherthanthatoftheCuO/γ-Al2O3catalystpreparedbyconventionalimpregnationmethod.XRDresultsshowedthatanenhanceddispersionhadbeenachievedwiththeplasmatreatment.SEMresultsindicatedthatthesizebecamemuchsmallerandthesurfacebecamemoreuniformwiththeplasmatreatment.

简介：包含1,3,4-oxadiazole单位的热地稳定的聚合物作为溶剂在pyridine与芳香/脂肪族的二度酸氯化物通过芳香/脂肪族的bis-tetrazole混合物的Huisgen反应被综合了。获得的聚合物甚至在象DMSO和DMF那样的极的aprotic溶剂不可溶解或稍微可溶。相对高的固有的粘性价值(0.611.33dL/g，在在25点的0.125%H2SO4????????????????????????倠？？

简介：Acylationreactionofanthracenewithoxalylchlorideinthepresenceof[Emim]C1-A1C13ionicliquidhasbeeninvestigated.Pure1,2-aceanthryenedione,whichisusedasintermediateoffunctionalaromaticpolymermaterial,wasobtainedbyrecrystallingthereactionmixturewithaetherandwasdeterminedbyGC/MS,1HNMRandFTIRanalysis.Theinfluencesofvariousparameters,suchasthecontentsofAlCl3in[Emim]C1-A1C13,theamountofacylationagent,amountof[Emim]C1-A1C13,reactiontemperatureandreactiontimewereinvestigated.Theoptimumconditionswereasfollows:themolarfractionofA1C13inionicliquid[x(AlCl3)]being0.67,molarratioofionicliquidtoanthracenebeing2:1,molarratioofoxalylchloridetoanthracenebeing2:1,reactiontemperaturebeing40℃andreactiontimebeing6h.Underaboveconditions,theyieldandselectivityof1,2-aceanthrylenedionecanreach91.5%and98.3%respectively.Furthermore,[Emim]C1-A1C13ionicliquid,comparedwithmetalhalidessuchasAlCl3,wasfoundtocatalyzethereactionasanovelenvironmentalfriendlycatalystandsolventandcanbereused.

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简介：Immobilizedtriazinedyeaffinitychromatographyhasbeenwidelyusedforproteinpurification.Inthispaper,CibacronBlueF3G-4wasimmobilized,throughaspacerarm,ontoarigidhydroplhilicporouspolymerbyreactinganepoxy-group-containingpoly(vinylalcohol)with6-aminohexyl-N'-CibacronBlueF3G-A,whichwasobtainedbyreactingCibacronBlueF3G-4withexcessof1,6-diaminohexane,inapH8.6buffer,Theepoxy-group-containingpoly(vinylalcohol)waspreparedbytreatingmacroporouspoly(vinylalcohol)withexcessepichlorohydrininthepresenceofNaOHindimethylsulfoxide.Themacroporouspoly(vinylalcohol)waspreparedbyhydrolysisofmacroporouscrosslinkedpoly(vinylacetate),whichwassynthesizedbysuspensioncopolymerizationofvinylacetateandtriallylisocyanurateinthepresenceofbutylacetateandn-heptaneasdiluents.TheCibacronBlueF3G-A-immobilizedpoly(vinylalcohol)waspackedinastainlesssteelcolumn(250×5mmI.D.)andthechromatographicbehaviorsofseveralproteins(cytochromec,lysozyme,bovineserumalbumin,insulin,andlactatedehydrogenase)weredetermined.

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简介：Amovingboundarymodelunderconsideringthevolumechangeofsphericalresinbeadsduringionexchangeprocesseswasemployedtorecognizethemechanismsofreecoveringuraniumfromcarbonatesolutionsusingstronglybasicanionexchanger.Twoimportantfactors,swellingandionexchange,whichdirectlyaffecttheviolumeofionexchangersweretakenintoaccount.AnionexchangemechanismhasbeenfoundfortheforwardreactionPCl/[UO2(CO3)3]^4-,andisparticaldiffusiongoverningathighconcentrationofthecomplexanion.ThemechanismofRCl/U(VI)atpH5.5-7.5isachemicalreactiontakingplaceatthemovingboundaryoftheunreactednucleus.ForthereversereactionRnU/NaCl,theuranyltricarbonatecomplexanionintheresinphaseisreplacedbyCl^-ionswithanionexchangemechanismalwaydeterminedbyparticlediffusion.TheotherformsofuraniuminthesolidphaseloadedontheresinatpH5.5-7.5shouldbelongtonon-exchangeableuranium.ThemechanismofthereversereactionRnU/HClisalwayschemicalreactionwhichisnotrestrictedtothemovingboundaryoftheunreactedcore.

简介：Asidechainliquidcrystallinecopolysiloxane,whichwouldshowelectro-opticeffectsasknownfromlowmassliquidcrystal,wassynthesizedbyhydrosilylationreaction,andthetwohomologousmonomerswithdifferentlengthspacerscontainingSchiff’sbasemesogenwith—NO2terminatedgroupweregraftedtoapolysiloxanemainchain.Residualmonomerincrudeproductiseffectiveinreinforcingtheresponsetoanelectricfieldoverthatofpurepolymericliquidcrystal.

简介：Kineticsofchloride/sulfate,chloride/nitrateandnitrate/sulfateforwardexchangesandreverseexchangesatsolutionconcentrationsof1N,0.2Nand0.02Non201×7strongbaseanionexchangeresin,respectively,havebeenexaminedat25℃.Itisfoundthattheforwardandthereverseexchangeratesofthetwogivenionsatlowsolutionconcentration,respectively,underidenticalconditionscanbecontrolledbydifferentmechanisms,whilethoseathighsolutionconcentrationareallcontrolledbyparticlediffusion.Theternaryexchangeratesofsulfate/(chloride+nitrate)andnitrate/(chloride+sulfate)havealsobeenexamined.

简介：Theadsorptionbehaviorofionicgoldontochelatingfibercontainingamidoximegroupswasinvestigated.ThechelatingfiberpresentshighadsorptioncapacityforionicgoldAu^3+（upto626mg/g,whenthecontentofamidoximegroupreaches7.59mmol/g),andpossessestheabilitytoreducetheAu^3+intometallicgold,Intheredoxprocess,theamidoximegroupisoxidizedintocarboxylgroup.