学科分类
/ 6
118 个结果
  • 简介:Thelayer-by-layercomplexationtechniqueofpolymerandmetalionwassuccessfullyutilizedtofabricatetheuhrathinmuhilayerfilmofpoly(3-thiopheneaceticacid(PTAA)andTb^3+ionbydippingthesubstratesalternativelyinpolymerandTb^3+ionaqueoussolutions.UV-vismeasurementrevealedthattheabsorbancehaslinearitywiththebilayernumberfromlayertolayerandtheX-rayphotoelectronspectrum(XPS)confirmedtheexistenceofTb^3+ion.ThepHofboththepolymerandTbCl3solutionsinfluencethethicknessdramaticallywhiletheconcentrationofthesolutionsisnotsosensitive.TheluminescentspectrumofthecomplexfilmshowsthecharacteristicemissionofTb^3+ionaswellastheligandindicatingtheformationofthecomplex.

  • 标签: 光致发光 稀土 自组装薄膜 多层膜 UV-VIS
  • 简介:太钢1350m3高炉在炉体破损严重的情况下,对高炉进行了大检修,并采取一系列强化冶炼的措施,收到良好效果.

  • 标签: 高炉 强化冶炼 炼铁
  • 简介:本文通过对原燃料条件、高炉操作制度、富氧、风温以及日常操作调剂等方面进行剖析,提出1080m3高炉增产降耗的潜力所在。

  • 标签: 原燃料 操作制度 富氧 风温 增产 降耗
  • 简介:分析了3S技术的特点,考虑矿区的具体情况和要求,探讨了3S技术应用于矿区工程的可行性和应用目标.

  • 标签: 3S技术 矿山 应用目标
  • 简介:Thesinglecrystalofthecomplex[Sc(NO33(H2O)2]·(15C5)hasbeenpreparedinacetonitrile.Thenewcomplexhasbeencharacterizedbyelementalanalysis,IRspectra,solubilityandmolarconductancemeasurements.ThestructureofthecomplexisdeterminedbysinglecrystalX-raydiffractionanalysis.

  • 标签: solubility acetonitrile Crown molar H2O NO3
  • 简介:(Ba0.66Sr0.33)Mg0.8Al11.47O19:Tm0.013+(BSMA:Tm3+)phosphorwassynthesizedbysolid-statereactions.ThesamplewascharacterizedbyX-raydiffraction(XRD),scanningelectronicmicroscope(SEM),vacuumultraviolet(VUV)spectra,ultraviolet(UV)spectraandFT-IRspectrum.XRDpatternrevealsthatBSMA:Tm3+hasthesamestructureasBaAl12O19phase.SEMimageillustratesthatthephosphorhasthehexagonalshapeanddeepslicestructure.VUVandUVemissionspectraat20,50and100Kshowthatthelowtemperatureluminescenceintensitiesbecomeweakgraduallywiththeincreasingofthetemperatureunder147and254nmexcitation.Thestrongbroadbandpeaksataround357and397nmandthepeakat516nmunder147nmexcitationallcorrespondtothecharacteristictransitionsofTm3+ions.However,underUV(254nm)excitation,themainpeakbecomes530nmwhichhasveryhighlineintensity,andthepeaksatabout362and403nmareveryweak.Theexcitationspectrumat20Kshowsthattherearethreeabsorptionpeaksataround153,186and193nmwhen516nmemissionismonitored.Theabsorptionpeaksof[AlO4],[AlO6]andAl-OcanbeobservedinFT-IRspectrum.

  • 标签: VACUUM ULTRAVIOLET low temperature LUMINESCENCE Tm3+
  • 简介:近年来通过提高操作技术,380m3高炉生产技术经济指标进步明显,利用系数由2.85t/m3·d上升到3.2t/m3·d左右,焦比由原来410kg/tFe降到360kg/tFe,经济效益显著。

  • 标签: 380m3高炉 生产技术 进步
  • 简介:通过对攀钢冷轧厂酸洗3号纠偏装置跑偏原因的分析和对纠偏角度的计算,提出了可行的改进方案,完全消除了跑偏现象,取得了圆满成功。

  • 标签: 纠偏 跑偏 机构
  • 简介:SphericalYAG:Ce3+phosphorparticleswithnarrowsizedistributionwerepreparedbyspraypyrolysis.Theeffectsoftheconcentrationofsolution,theflowrateofcarriergasandtheannealingtemperatureonthephosphormorphologywerestudied.Theproductivityofprecursorparticlesshowsatrendofdropafterrisingwiththeincreaseofconcentration.Raisingtheflowrateofnitrogencanimprovetheproductivityoftheprecursorparticles.Phosphorpreparedbyspraypyrolysishasobviouslyhigheremissionintensitythanthatsynthesizedbysolidstatereaction,spraypyrolysismakesCe3+ionswelldistributedinthecrystallatticeastheluminescentcenters,andphosphorparticleshaveregularsphericityandnarrowsizedistribution.

  • 标签: 钇铝石榴石 稀土 热解 制备 发光二极管 荧光性质
  • 简介:中铝山西分公司氧化铝3号因转窑窑前鼓风机因轴承失效、机壳移位等原因造成风机振动大,虽更换了轴承恢复了机壳位置,但振动未消除:后采用因素排除的方法,在检修过程中实行过程工序确认制度,最终找出了风机振动大的原因,和对缺陷处理的方法.

  • 标签: 氧化铝 回转窑 鼓风机 振动 动平衡 裂缝
  • 简介:Differentfluxeswereusedtosynthesizelongpersistencephosphors,calciumsulfidesactivatedbyEu2+andTm3+,byconvenientsolid-statemethod.ThephosphorusingNH4Fasafluxhasgoodcrystallinityandlargeparticlesize,itsstabilityagainstwaterandotheratmosphericcomponentsisenhanced,anditsafterglowislongerandfluorescentintensityismoreintensethanthoseofthephosphorusingNH4Clasflux.TheirPLintensitiesvariedwithtimeinmoistairweremeasured,noremarkablechangewasfoundforthosepreparedwithNH4FfluxincontrastwithNH4Clasflux.SousingNH4Fasfluxisagoodmethodtoenhancethestabilityofalkalineearthsulfides.

  • 标签: 磷光体 CaS:Eu^2+/Tm^3+ 化学稳定性 稀土 硫化钙 铕二价
  • 简介:Basedonthethermodynamicallyself-consistentanalysisandoptimizationofthreesub-binarysystemsoftheternarysystemPrCl3-CaCl2-MgCl2,thethermodynamicsofthisternarysystemhasbeenstudied.UsingHillertmodelandtakingMgCl2asanasymmetriccomponent,thePrCl3-CaCl2-MgCl2phasediagramhasbeencalculated.Theagreementbetweencalculatedandmeasuredcompositionsandtemperaturesatdeflectingpointsonliquidusisgood.Thesystemisasimpleeutecticonewithaeutecticpointat26.0mol%PrCl3,41.5mol%CaCl2,32.5mol%MgCl2;560℃(calculated)and26.0mol%PrCl3,39.4mol%CaCl2,34.6mol%MgCl2;546℃(measured),respectively.

  • 标签: TERNARY system Phase DIAGRAM Rare earth
  • 简介:NominalcompositionofCa1-xZnxTiO3:0.002Pr3+(x=0.000~0.200)phosphorswerepreparedbyconventionalsolidreactionroute.XRDandPLmeasurementswereusedtoinvestigatethesolid-solutionstructureandluminescencepropertiesofZn-dopedCa1-xZnxTiO3:0.002Pr3+phosphors.Theeffectofsolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionsontheluminescentpropertieswasanalyzed.Theresultsrevealthat,withtheincreaseofZnsubstitutioncontentbelow0.010,latticeparametersandtheintensityofexcitationpeakatboth260and330nmaswellasthecorresponding610nmemissionintensityaremonotonouslydecreasedquicklyinasimilartendency.Also,theevolutionofluminescenceintensityandcrystalcellparametersagainstZndopingconcentrationareingoodagreement.AboveresultsarecloselyrelatedwiththestructurechangewithinCa1-xZnxTiO3:0.002Pr3+solid-solutionphaseformedbytheZnionssubstitutionfortheCasites.Presentstudyrevealsthatthesolid-solutionstructureformedbysubstitutionbetweenCa2+andZn2+ionshassignificanteffectontheluminescencepropertiesofsinglephaseCa1-xZnxTiO3:0.002Pr3+phosphors.

  • 标签: Ca1-xZnxTiO3 固溶体 发光性能 稀土 掺杂 荧光材料
  • 简介:美国宇航局在加州帕萨迪纳的喷气推进实验室研究成功了一种制造YBa2Cu3O7-α高温超导电缆(封装在金属套管内)的新方法。据称,这种方法成本较低,过程易于控制,且对各种前体材料有很强的适应能力。该法分4个步骤:生产具有化学(配)比的前体(Precursor)粉;将前体粉包封在金属套管内;用轧制的方法使前体粉固结;在液态锂金属浴槽内进行处理,使之转变成超导组

  • 标签: 粉末冶金 金属套管 高温超导电缆 锂金属 实验室研究 喷气推进
  • 简介:针对3~#皮带的产尘特点,分别在尾轮和首轮采用独立的防尘系统,加大收尘风量、定向气流排尘、活动刚性密闭、空气幕隔离、扁平罩收尘及低速文丘里除尘器除尘等综合防尘措施,防尘效果良好:3~#皮带工作场所粉尘浓度最高时才1.5mg/m~3,低于粉尘卫生标准2mg/m~3的允许值,尾气排放粉尘浓度最高时达47.0mg/m~3,在卫生标准100mg/m~3的允许范围之内.

  • 标签: 皮带防尘 加大风量 定向排尘