简介：１ＩｎｔｒｏｄｕｃｔｉｏｎＩｔｈａｓｂｅｅｎｄｅｍｏｎｓｔｒａｔｅｄｔｈａｔｓｐｉｎｅｌｓｔｒｕｃｔｕｒｅｌｉｔｈｉｕｍｍａｎｇａｎｅｓｅｏｘｉｄｅｉｓｔｈｅｍｏｓｔｐｒｏｍｉｓｉｎｇｃａｔｈｏｄｅｆｏｒ“ｌｉｔｈｉｕｍｉｏｎ”ｂａｔｅｒｉｅｓｂｅ...

简介：Fe(OH)3precursorsolwaspreparedbyasol-gelmethod.Theprecursorsolwasdippedontotheabsorbentcotton,andgelwasformedontheabsorbentcottontemplateafterthevolatilizationofmoisture.Fe2O3microtubulesweresynthesizedaftertheprocessofself-propagationorcalcination.Thephase,morphology,andparticlediameterofthesampleswereexaminedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM),andthemagneticpropertiesofthesamplesweremeasuredusingavibratingsamplemagnetometer(VSM).TheexternaldiametersofFe2O3microtubulesrangedbetween8and13μm,andthewallthicknessesrangedbetween0.5and2μm.ThetypeofthecalcinationmethodplaysasignificantroleindevelopingtheFe2O3phaseandthevariationinthemagneticpropertiesinthesol-geltemplatecomplexingmethod.γ-Fe2O3wassynthesizedbyaself-propagationmethod.However,α-Fe2O3wassynthesizedaftercalcinationat400°Cfor2h.Thecoercivityofthesamplessynthesizedbycalcinationat400°Cfor2hafterself-propagationwasfoundtoincreasesignificantly,therebypresentinghardmagneticproperties.

简介：在这份报纸，纺纱冰上的无磁性的Y离子的冲淡效果加重Dy2Ti2O7由红外线并且拉曼系列和磁化大小被调查。与温度弄软减少的异常声子在父母被发现并且冲淡除了之外，做的混合物，和Y能放松弄软声子233附近的红外模式?厘米<啜class=“a-plus-plus”>显示在纺纱冰材料联合的强壮的phononphonon的1,。当冲淡的水平不很高时，磁化大小表明无磁性的杂质严重地不处于扎根的状态影响纺纱冰规则。然而，大量冲淡提高混乱并且因为集体旋转扭动簇不再是可得到的，打破纺纱冰状态。

简介：采用化学平衡模拟软件GEMS预测了锌湿法冶金过程中涉及的锌在Zn（Ⅱ）-NH3-H2O和Zn（Ⅱ）-NH3-Cl--H2O体系中的溶解度,并构建了其含锌物种分布图和优势区图。采用平衡实验方法测定了相同条件下锌的溶解度,其结果与预测结果相吻合。含锌物种的分布图和优势区图表明,在弱碱性条件下,2个体系均为以锌氨和羟基锌氨配合物为溶液的主要物种,其中Zn（NH3）24-为主要优势物种;在Zn（Ⅱ）-NH3-Cl--H2O体系中,锌氨氯三元配合物的形成能有效增大锌在中性条件下的溶解度,在该体系中存在Zn（OH）2、Zn（OH）1.6Cl0.4和Zn（NH3）2Cl23种固相,固相产物的形成取决于体系中总锌、总氨和总氯浓度。这些热力学平衡图表明了体系中各种物种之间的相互影响作用,并预测了总氨和总氯浓度的变化对锌溶解度的影响,为锌湿法冶金提供了热力学数据。

简介：TheprocesstoobtainhighT（110K）phasequickly,themicrostructureandpropertiesofAg-sheathedBi（Pb）-Sr-Ca-Cu-Osuperconductortapeshavebeenstudied.ItwasfoundthattheformationtimeofthehighTcphasewasgreatlyshortenedbytheadditionofmoreCaandCutothenominalcompositionofBi（Pb）:Sr:Ca:Cu=2:2:2:3andtheadoptionofappropriatesinteringtemperatureandcoolingrate.SuperconductorpowderwithpredominanthighT,phasewaspreparedaftera840C/50htreatment.TheJoftheAg-sheathedtapesandthemagneticfielddependenceofJwereobviouslyimprovedbyrepeatedlypres-singandsintering.Themaximumtransportcurrentdensityat77Kinazeromagneticfieldwas12,200A/cm2.ThemagneticdependenceofJwassummarizedasfollows:6.450A/cm2（B⊥1.B∥S.0.1T）1,810A/cm2（B⊥1.B∥S,1T）,390A/cm2（B⊥1.B∥S,2T）（B:magneticfield.1:electriccurrent.S:surfaceoftapes）.TheimprovementofJwasattributedtotheformationoftheplate-likestructurewithhomogeneouscompositiondistributionandthestrongc-axistexture.

简介：TheelectronicstructuresofspinelMgAl2O4andMgOtunnelbarriermaterialswereinvestigatedusingfirst-principlesdensityfunctionaltheorycalculations.OurresultsshowthatsimilarelectronicstructuresarefoundfortheMgAl2O4andMgOtunnelingbarriers.ThecalculateddirectenergygapsattheΓ-pointareabout5.10eVforMgAl2O4and4.81eVforMgO,respectively.BecauseofthesimilarfeatureinbandstructuresfromΓhigh-symmetrypointtoFpoint(△band),thecoherenttunnelingeffectmightbeexpectedtoappearinMgAl2O4-basedMTJslikeinMgO-basedMTJs.ThesmalldifferenceofthesurfacefreeenergiesofFe(2.9J.m-2)andMgAl2O4(2.27J·m-2)onthe{100}orientation,andthesmallerlatticemismatchbetweenMgAl2O4andferromagneticelectrodesthanthatbetweenMgOandferromagneticelectrodes,thespinelMgAl2O4cansubstituteMgOtofabricatethecoherenttunnelingandchemicallystablemagnetictunneljunctionstructures,whichwillbeappliedinthenextgenerationreadheadsorspintronicdevices.

简介：

简介：Anewenvironmentalfriendlycatalyst,H4SiW12O40/PAnwaspreparedandidentifiedbymeansofFT-IR,XRDandTG/DTA.Cyclohexanone1,2-propanediolketalwassynthesizedfromcyclohexanoneand1,2-propanediolinthepresenceofH4SiW12O40/PAn.Thefactorsinfluencingthesynthesiswerediscussedandthebestconditionswerefoundout.Theoptimumconditionsare:molarratioofcyclohexanoneto1,2-propanediolis1:1.4,thequantityofcatalystisequalto1.0%offeedstocks,andthereactiontimeis40min.H4SiW12O40/PAnisanexcellentcatalystforsynthesizingcyclohexanone1,2-propanediolketalanditsyieldcanreachover96.5%.

简介：采用平面和曲面两种压边圈来研究压边圈类型对5182-O铝合金板材室温拉深性能的影响。通过光学显微镜（OM）来研究铝合金板材的显微组织。结果表明：使用平面压边圈的极限拉深比为1.7,而且拉深杯出现了严重的制耳。相比之下,使用曲面压边圈,板材的极限拉深比提高到2.0。曲面压边圈提供的压边力能弱化制耳,阻止板材法兰起皱,这是因为板材在曲面压边圈作用下,在不同方向的流动更均匀。

简介：Au/-Al2O3催化剂被免职降水方法为低集中白酒溪流(甲醇，乙醇，iso-propanol和n-propanol)的催化燃烧作好准备。催化剂被X光检查光电子描绘光谱学(XPS)，X光检查diffractometry(XRD)和精力散X光检查微分析(版本)技术。XPS结果证明仅仅催化剂的表面上有Au0。XRD模式证明Au高度大概在-Al2O3上被驱散。为有2.0g/m3的集中的甲醇，乙醇，iso-propanol和n-propanol的完全的变换的温度是60，155，170和137?，分别地但是他们完全在60，220，260和217点被使矿物化进CO2和H2O吗？分别地在优化催化剂上。催化剂的活动在130h是稳定的。为催化甲醇消除的动力学跟随了伪--首先订表示为r=0.6528c0+0.084的反应2。明显的激活精力的价值是在反应温度的范围的54.7kJ/mol。

简介：ThedistributionsoftheaxialstressandshearstressinAl2O3-TiC/Q235diffusionbondedjointswerestudiedusingfiniteelementmethod(FEM).Theeffectofinterlayerthicknessontheaxialstressandshearstresswasalsoinvestigated.Theresultsindicatethatthegradientsoftheaxialstressandshearstressaregreatnearthejointedge.ThemaximalshearstressproducesattheinterfaceoftheAl2O3-TiCandTiinterlayer.WiththeincreaseofCuinterlayerthickness,themagnitudesoftheaxialstressandshearstressfirstdecreaseandthenincrease.Thedistributionoftheaxialstresschangesgreatlywithalittlechangeintheshearstress.TheshearfractureinitiatesattheinterfaceoftheAl2O3-TiC/TiinterlayerwithhighshearstressandthenpropagatestotheAl2O3-TiCside,whichisconsistentwiththestressFEMcalculatingresults.

简介：TheeffectofyttriaonthesolidreactionmechanismofaCaHPO4·2H2O+CaCO3systematdifferenttemperatureswasexperimentallystud-ied.Thesampleswithandwithoutyttriaweresubjectedtothermogravimetric/differentialscanningcalorimetrymeasurement.ThesampleswereheattreatedatthetemperaturescorrespondingtothepeaksontheDSCspectra,andtheresultedphasecompositionswereidentifiedbyX-raydiffraction.Thetransformationmechanismwasdeducedbycomparingthephasesobtainedatdifferenttemperatures.Theresultsshowthatthetransformationsatbelow1073Karenotaffectedbyyttria,butallthoseatabove1073Karecompletelyaltered.Theformationtem-peratureofhydroxyapatitedecreasesby134K,andthedecompositiontemperatureincreasesby38K.ThepolymorphoustransformationofCa3(PO4)2fromβphasetoαphaseincreasesby47K.Thethermodynamicpropertiesofthetransformationsatabove1073Karealsomodi-fiedbytheadditionofyttria;thatis,theendothermalpeaksaresubstitutedbyexothermalpeaks.

简介：反的尖晶石类型金属氧化物，magnesium-manganese-titanium氧化物(Mg2Mn0.5Ti0.5O4)，用coprecipitation/thermal结晶化方法被准备。有这材料的抽取/插入反应被X光检查，交换的浸透能力，pH滴定，和分发系数(Kd)测量调查。Mg2Mn0.5Ti0.5O4的酸处理引起了Mg2+超过81%的抽取，而Mn4+和Ti4+的溶解是不到10%。试验性的结果证明酸处理的样品有交换56mg的一个能力

简介：微米大小的Sr2(P2O7):Ce，Tb绿黄磷被与它的先锋在不同温度被退火准备综合了由一同沉淀(NH4)在周围的温度的2HPO4。黄磷的阶段结构，谷物尺寸，表面形态学，和光性质被X光检查衍射调查，扫描电子显微镜，传播电子显微镜，和荧光光谱。先锋的产品在1,100点退火了的结果表演??‰浮???匠??伲?????畅？？

简介：在氩气气氛下,将Ag2O与石墨通过机械活化或热还原反应生成Ag,对其等温还原过程的动力学进行研究。结果表明,采用Johnson-Mehl-Avrami模型能合理地解释Ag2O与石墨经机械活化和热还原合成Ag的过程。采用相同的模型来研究机械活化和热还原反应合成Ag的动力学时,机械活化还原过程中的Avrami指数比热还原的要高;热还原和机械活化过程中的晶核长大机制分别是扩散控制和界面控制。

简介：利用高频辅助激光熔覆技术在镍基合金上制备Al2O3-13%TiO2（质量分数）陶瓷涂层。采用SEM、XRD和EDS等方法分析陶瓷涂层的微观结构和陶瓷层与粘结层之间的结合界面。结果表明：陶瓷层出现了完全熔化区和液相烧结区双层结构,其中,完全熔化区颗粒充分烧结长大,而液相烧结区则出现了三维网状结构,该三维网状结构由熔化的TiO2相包裹Al2O3颗粒形成。通过激光熔覆作用下的粉末熔化和扁平化行为解释双层结构形成机理。同时,在陶瓷层与粘结层的结合界面上发现具有尖晶石结构的NiAl2O4和针状结构的Cr2O3,证明在激光熔覆过程中发生的化学反应可以有效增加陶瓷层与粘结层的结合强度。

简介：2014年6月2日，中国模具工业协会七届第四次常务理事（扩大）会议在上海召开，中国模具工业协会名誉会长、副会长、常务理事、理事和重点骨干企业的代表140余人出席了大会。中国模具工业协会常务副会长兼秘书长武兵书主持了会议。本次工作会议主要议程有六项：

简介：Anewseriesofrareearthcompounds,Y2-xErxMo4O15(x=0.0-2.0),weresynthesizedandtheirstructuresweredeterminedbypowderX-raydiffraction(XRD).RietveldanalysisofXRDpatternsrevealsthatthecompoundsofthisseriescrystallizeinmonoclinicsystemwithspacegroupP21/c.Thelatticeparametersa,b,c,βandtheunitcellvolumeVde-creaselinearlywithincreasingErcontent.Thethermalexpansionpropertiesofthesecompoundswerestudiedunderhigh-temperatureXRD.PositivethermalexpansionsofcompoundsY2-xErxMo4O15arefoundtobeanisotropicalongthethreecrystallographicdirectionswhereaandcaxesexpandwhilebaxiscontractsinthewholetemperaturerange.Byanalysisofdata,theexpansionofweakbandMo2-O14withrisingtemperatureshouldberesponsibleforpositivethermalexpansion.

简介：ThelongafterglowSrAl2O4:Dy,Euphosphorisliabletohydrolyzeinwaterwithdeteriorationoftheluminescentproperty.SrAl2O4:Dy,Euphosphorswerethereforeheatedat60-90℃inTEOSsoltoformasurfacegelandthenheat-treatedat400℃toobtainSiO2coatedphosphors.ObservationbyTransmissionElectronMicroscope(TEM)andX-rayphotoelectronspectroscopy(XPS)showsthatathinsilicafilmformsonthesurfaceofthephosphors.Thecoatingprocedurecanbeillustratedbyafour-stepprocessandthetransparentsilicafilmcansuppressthehydrolysisprocess,sothattheluminescentpropertiesofthephosphorsareunimpairedorevenbetter.

简介：TiO2nanoparticleswithdifferentphasesarepreparedbyhydrolysisoftitaniumtetrabutoxideinthepresenceofHCl.ThecompositionandmicrostructureoftheresultingsamplesarestudiedbyXRDandTEM.TheseresultsshowthattherangeofparticlesizeofTiO2isfrom20to30nm.ThemechanismofTiO2photocatalysisreactionhasbeendiscussedextensively.PhotocatalyticactivitiesofnanometerTiO2arealsoevaluatedbydegradationofthecrystalvioletsolution.ExperimentalresultsindicatethatthesynergisticactionofH2O2andultrasonicwavegreatlyenhancesphoto-catalyticreactionofTiO2.